A constrained least-squares approach to combine bottom-up and top-down CO2 flux estimates

Terrestrial CO₂ flux estimates are obtained from two fundamentally different methods generally termed bottom-up and top-down approaches. Inventory methods are one type of bottom-up approach which uses various sources of information such as crop production surveys and forest monitoring data to estimate the annual CO₂ flux at locations covering a study region. Top-down approaches are various types of atmospheric inversion methods which use CO₂ concentration measurements from monitoring towers and atmospheric transport models to estimate CO₂ flux over a study region. Both methods can also quantify the uncertainty associated with their estimates. Historically, these two approaches have produced estimates that differ considerably. The goal of this work is to construct a statistical model which sensibly combines estimates from the two approaches to produce a new estimate of CO₂ flux for our study region. The two approaches have complementary strengths and weaknesses, and our results show that certain aspects of the uncertainty associated with each of the approaches are greatly reduced by combining the methods. Our model is purposefully simple and designed to take the two approaches’ estimates and measures of uncertainty at ‘face value’. Specifically, we use a constrained least-squares approach to appropriately weigh the estimates by the inverse of their variance, and the constraint imposes agreement between the two sources. Our application involves nearly 18,000 flux estimates for the upper midwest United States. The constrained dependencies result in a non-sparse covariance matrix, but computation requires only minutes due to the structure of the model.     

Flooding,resettlement, and change in livelihoods: evidence from rural Mozambique

Post‐disaster development policies, such as resettlement, can have major impacts on communities. This paper examines how and why people's livelihoods change as a result of resettlement, and relocated people's views of such changes, in the context of natural disasters. It presents two historically‐grounded, comparative case studies of post‐flood resettlement in rural Mozambique. The studies demonstrate a movement away from rain‐fed subsistence agriculture towards commercial agriculture and non‐agricultural activities. The ability to secure a viable livelihood was a key determinant of whether resettlers remained in their new locations or returned to the river valleys despite the risks posed by floods. The findings suggest that more research is required to understand i) why resettlers choose to stay in or abandon designated resettlement areas, ii) what is meant by ‘voluntary’ and ‘involuntary’ resettlement in the realm of post‐disaster reconstruction, and iii) the policy drivers of resettlement in developing countries.     

How well do predators adjust to climate-mediated shifts in prey distribution? A study on Australian water pythons

Climate change can move the spatial location of resources critical for population viability, and a species' resilience to such changes will depend upon its ability to flexibly shift its activities away from no-longer-suitable sites to exploit new opportunities. Intuition suggests that vagile predators should be able to track spatial shifts in prey availability, but our data on water pythons (Liasisfuscus) in tropical Australia suggest a less encouraging scenario. These pythons undergo regular long-range (to >10 kmin) seasonal migrations to follow flooding-induced migrations by their prey (native dusky rats, Rattus colletti). However, when an extreme flooding event virtually eliminated rats for a three-year period, the local pythons did not disperse despite the presence of abundant rats only 8 km away; instead, many pythons starved to death. This inflexibility suggests that some vagile species that track seasonally migrating prey may do so by responding to habitat attributes that have consistently predicted prey availability over evolutionary time, rather than reacting to proximate cues that signal the presence of prey per se. A species' vulnerability to climate change will be increased by an inability to shift its activities away from historical sites toward newly favorable areas.     

Glass recycling in cement production--an innovative approach

An innovative approach of using waste glass in cement production was proposed and tested in a laboratory and cement production plant. The laboratory characterization of 32 types of glass show that the chemical composition of glass does not vary significantly with its color or origin but depends on its application. The alkali content of glass, a major concern for cement production varies from 0 to 22%. For the glass bottles mainly found in Hong Kong waste glasses, the alkali content (Na2O) ranges from 10 to 19% with an average around 15%. There is no significant change of the SO2 content in the gas exhaust of the rotary kiln when about 1.8 t/h of glass bottles were loaded along with the 280-290 t/h raw materials. The content of NOx, mainly depends on the temperature of the kiln, does not show significant change either. The SO3 content of the clinker is comparable with that obtained without the loading of glass. The alkaline content shows a slight increase but still within three times the standard deviation obtained from the statistical data of the past year. The detailed analysis of the quality of the cement product shows that there is not any significant impact of glass for the feeding rate tested.     

Quantification of mass fluxes and natural attenuation rates at an industrial site with a limited monitoring network: a case study

At many "real world" field sites, the number of available monitoring wells is limited due to economic or geological reasons. Under such restricted conditions, it is difficult to perform a reliable field investigation and to quantify primary lines of evidence for natural attenuation (NA), like the documentation of a decrease of contaminant mass flux in flow direction. This study reports the results of a groundwater investigation at a former manufactured gas plant situated in a Quaternary river valley in southwest Germany. The location, infrastructure and aquifer setting are typical of many industrial sites in Germany. Due to difficult drilling conditions (coarse glaciofluvial gravel deposits and an anthropogenic fill above the aquifer), only 12 monitoring wells were available for the investigation and localisation of the contaminant plume. These wells were situated along three control planes (CP) downgradient from the contaminant source, with four wells along each plane. Based on the sparse set of monitoring wells, field scale mass fluxes and first-order natural attenuation rate constants of benzene, toluene, ethylbenzene, and o-xylene and p-xylene (BTEX) and low molecular weight polycyclic aromatic hydrocarbons (PAH) were estimated utilizing different point scale and also a new integral investigation method. The results show that even at a heterogeneous site with a sparse monitoring network point scale investigation methods can provide reliable information on field scale natural attenuation rates, if a dependable flow model or tracer test data is available. If this information is not available, only the new integral investigation method presented can yield adequate results for the quantification of contaminant mass fluxes under sparse monitoring conditions.     

Assessment of the efficacy of slow-release formulations of the tribenuron-methyl herbicide in field-grown spring wheat

Environmental Science and Pollution Research - The efficacy of slow-release formulations of tribenuron-methyl (TBM) embedded in the matrix of degradable poly(3-hydroxybutyrate) blended with birch...     

Effectiveness of potassium ferrate (VI) as a green agent in the treatment and disinfection of carwash wastewater

Environmental Science and Pollution Research - Carwash wastewater treatment with potassium ferrate (VI) (K2FeO4) was optimized by response surface methodology. The optimum conditions for chemical...     

A workflow to investigate the impacts of weathered multi-walled carbon nanotubes to the mud snail Lymnaea stagnalis

Environmental Science and Pollution Research - Although the development and application of nanomaterials is a growing industry, little data is available on the ecotoxicological effects on aquatic...     

USING CLIMATE FORECASTS FOR WATER MANAGEMENT: ARIZONA AND THE 1997–1998 EL NIÑO1

ABSTRACT: Unrelenting pressure on limited surface water supplies requires increasingly sophisticated water management approaches. Climate forecasts of seasonal precipitation and temperature are potentially useful, but the operational water management community currently underutilizes them. However, some agencies in Arizona took unprecedented advantage of forecasts for a potentially wet winter during the 1997–1998 El Niño event. This study investigates use of this information through a series of semi‐structured in‐depth interviews with key personnel from agencies responsible for emergency management and water supply; their jurisdictions ranged from urban to rural and local to regional. Interviews investigated information acquisition, interpretation, and incorporation into specific decisions and actions. While unprecedented actions were taken by some water management agencies and no agencies implemented inappropriate measures, some missed opportunities for more effective response, primarily through inaction. This study reveals a variety of technical factors and institutional characteristics affecting forecast use. Study findings emphasize the need for: (a) closer ongoing relationships between forecast producers and users, (b) increased institutional flexibility to exploit the increasing skill of seasonal climate forecasts, (c) demonstration projects of effective forecast use, and (d) a regional forum to facilitate information transfer between the hydro‐climatic research community and operational water managers.     

A Case Study of the Beneficial Reuse of Treated Groundwater

The future disposal of treated groundwater at the former Nebraska Ordnance Plant (NOP) Superfund site has been a topic of interest to the local property owners, the U.S. Army Corps of Engineers, and the local regulatory agencies. The Record of Decision for the site includes the extraction, treatment, and disposal of almost 3,000 gpm of groundwater with an estimated restoration time period exceeding 100 years. Interest from property owners and the Nebraska agency charged with regulating groundwater supply prompted the Corps of Engineers to consider several strategies for beneficially reusing the treated water. Alternatives included the establishment of a rural water district or local distribution system; delivery of the water to the municipal supply system of Lincoln, Nebraska, andsol;or other nearby municipalities; and consideration of innovative remedial technologies to reduce the quantity of treated water requiring disposal. The selected disposal plan consists of providing treated groundwater to interested parties for agricultural use with excess treated groundwater discharged to two streams. Multiple feasibility studies were generated, public input was solicited, and interagency agreements were executed during the course of the project. The remediation project is currently being constructed, and at least one property owner has constructed a new center‐pivot irrigation system to use the treated groundwater. © 2001 John Wiley & Sons.