Use of extant kinetic parameters to predict effluent concentrations of specific organic compounds at full-scale facilities.

To use the results of kinetic tests to predict effluent concentrations of specific contaminants in activated sludge systems, the fraction of the biomass that has an ability to degrade the test compound (i.e., competent biomass) must be estimated. A calibration procedure was developed to assess the competent biomass concentration because the chemical oxygen demand (COD) fraction tended to underestimate the degrading fraction for three of the four test compounds. Acetone, for instance, had a measured influent COD fraction of 0.08%, and the actual competent fraction was estimated to be 2.3%, based on the model calibration. Once the competent biomass fraction in the mixed liquor was determined, the extant kinetic parameters were subsequently used to predict activated sludge system performance. Predicted effluent concentrations were within 2, 5, and 16% of the average measured concentrations for acetone, linear alkylbenzene sulfonate, and furfural, respectively. Day-to-day predictions for these compounds were less accurate, possibly because of the non-steady-state nature of the activated sludge systems studied. The difference between the fraction of the influent COD contributed by the target compounds and the competent biomass fraction in the mixed liquor was found to be more significant when the target compound contributed less than 1% of the influent organic matter. The chemical structure of the target compound and chemical composition of the influent likely had an effect on the resulting competent biomass concentration. The total maximum growth rate, microX, was observed to be independent of the influent concentration of acetone and furfural, thus suggesting that the competent biomass concentration for these compounds was not affected by the changes in their influent concentrations. Consequently, a majority of competent biomass growth resulted from the degradation of other substrates, resulting in a competent biomass concentration significantly higher than predicted based on the influent COD fraction contributed by the test compound.     

The relationship between environmental management strategies and environmental compliance at Marine Corps installations

Environmental compliance requirements periodically impact the military's ability to use all installation resources. In response, environmental management strategies have been developed to ensure compliance and allow site closure. This study examines the relationship between environmental management strategies and environmental compliance at U.S. Marine Corps (USMC) installations via analysis of environmental compliance audit scores. Five environmental scores of interest from 1998 to 2004 audits—which include total compliance, total management, audit management, policy management, and training management—were subjected to statistical analysis. Results showed the USMC met environmental compliance and management standards, despite limited resources. High management strategy scores were moderately correlated with high total compliance scores. Total management scores improved over time, and noncompliance was most often associated with a lack of resources and plans. © 2006 Wiley Periodicals, Inc.     

Influence tactics and work outcomes: a meta‐analysis

Recent research on influence tactics has focused on the benefits that accrue as a result of using such tactics. The current study utilizes meta‐analytic techniques to estimate the true population correlations between various influence tactics and work‐related outcomes. Results indicate that ingratiation and rationality have positive effects on work outcomes. Additional analyses suggest that these and other influence tactics have significant effects in certain situations and on specific work outcomes. Copyright © 2003 John Wiley & Sons, Ltd.     

RELATIONSHIP OF NITRATE CONCENTRATIONS TO DISTANCE OF WELL SCREEN OPENINGS BELOW CASING WATER LEVELS1

ABSTRACT: Data from 54 well in central and eastern Kansas developed in unconsolidated deposits of Quaternary age indicate that nitrate concentrations are inversely related to the depth of the well screen opening below the water level in the well casing because this relationship was found to exist in an area of Nebraska and in a large area of Kansas, the relationship is generally valid over a wide geo- graphical area. In addition, the data indicate that the incidence of nitrate concentrations exceeding 45 milligrams per liter and nitrate concentrations, in general, are significantly lower in water from wells with screens deeper than 25 feet below the water table in unconfined aquifers or where screens are placed in deep confined aquifers. No concentrations of nitrate greater than 45 milligrams per liter were in obseved wells where screens were deeper than 60 feet below the casing water level. These findings suggest that general placement of well screens as far below the water table as possible in unconfined unconsolidated aquifers in Kansas. and possibly other areas of the Midwest, may be an effective measure in preventing undesirable nitrate concentrations in ground water supplies. particularly in areas where nitrate is a problem.     

Comparative Toxicities of Polar and Non-Polar Organic Fractions From Sediments Affected By the Exxon Valdez Oil Spill in Prince William Sound, Alaska

Standardized tests were applied to aromatic and polar fractions of sediment extracts to determine whether polar constituents or oxidative degradation products contributed significantly to the toxicity of sediments oiled by the Exxon Valdez spill. Intertidal sediment and pore-water samples were collected in September 1990 from two heavily oiled sites and an unoiled site in Prince William Sound (PWS). Methylene chloride extracts from these samples were fractionated by liquid chromatography into aliphatic, aromatic and polar fractions, and the aromatic and polar fractions were tested for toxicity using the Microtox^R test, bivalve larval mortality and development (Mytilus); several measures of genotoxicity in Mytilus, including SOS Chromotest^R, anaphase aberrations and sister chromatid exchange; and survival, anaphase aberrations and teratogenicity in coho salmon (Onchorhynchus kisutch). Microtox^R and SOS Chromotest^R protocols were applied in a screening mode to all samples, whereas other tests were applied only to selected fractions from two sites. Samples from Bay of Isles (oiled) were consistently more toxic (usually only 2 to 5-fold) than the Mooselips Bay (unoiled) samples, which gave very low responses in all tests. for both sites, however, responses to polar and aromatic fractions were about the same in most tests, suggesting that while the overall toxicity of the oil was low in these samples, at least part of that toxicity was derived from polar constituents. Compared to the parent hydrocarbons, polar oxidation products partition preferentially into pore-water and are more rapidly diluted and dispersed in the water column. These results suggest that polar oxidation products of petroleum hydrocarbons pose little risk to marine organisms, except possibly for infauna continuously exposed to pore-water in heavily oiled sediments. Independent surveys showed that sediment toxicity in PWS declined during 1989-1991 to near background levels, in accord with previous understanding of oil weathering and toxicity.     

The Seventh Kew Environmental Lecture: Our global future: climate change

The Kew lecture provides a major contribution to contemporary environmental views. The Hon. Timothy E. Wirth is US Under Secretary of State for Global Affairs and he is responsible within the US State Department for overseeing environment, population, human rights, refugee, narcotics and related programmes. He was elected to the US Senate from Colorado in 1986 and served until 1993 when he chose not to run for re-election. He was, previously, a Congressman for 12 years and was voted one of the 25 most effective Members of Congress. In 1992, he served as national co-chair of the Clinton – Gore presidential campaign. The lecture was delivered at the Royal Botanic Gardens, Kew, London, on 15 September 1997.     

The mental health of expatriate and Kosovar Albanian humanitarian aid workers

The mental health consequences of exposure to traumatic events and the risk factors for psychological morbidity among expatriate and Kosovar Albanian humanitarian aid workers have not been well studied. In June 2000, we used standardised screening tools to survey 285 (69.5%) of 410 expatriate aid workers and 325 (75.8%) of 429 Kosovar Albanian aid workers from 22 humanitarian organizations that were implementing health programmes in Kosovo. The mean number of trauma events experienced by expatriates was 2.8 (standard deviation: 2.7) and by Kosovar staff 3.2 (standard deviation: 2.8). Although only 1.1% of expatriate and 6.2% of Kosovar aid workers reported symptoms consistent with the diagnosis for post-traumatic stress disorder, 17.2% and 16.9%, respectively, reported symptoms satisfying the definition of depression. Regression analysis demonstrated that the number of trauma events experienced was significantly associated with depression for the two sets of workers. Organisational support services may be an important mediating factor and should be targeted at both groups.     

The implosion of the Calgary General Hospital: ambient air quality issues

This paper discusses the implosion of a large inner-city hospital in Calgary, Alberta, Canada, on October 4, 1998. Stationary and mobile air monitoring conducted after the implosion indicated there were several short-term air quality issues, including significant temporal increases in total suspended particles, particulate matter (PM) with aerodynamic diameter less than or equal to 10 microm (PM10), PM with aerodynamic diameter less than or equal to 2.5 microm (PM2.5), asbestos, and airborne and settled lead. In addition, the implosion created a dust cloud that traveled much further than expected, out to 20 km. The ability of an implosion to effectively aerosolize building materials requires the removal of all friable and nonfriable forms of asbestos and all Pb-containing painted surfaces during pre-implosion preparatory work. Public advisories to mitigate personal exposure and indoor migration of the implosion dust cloud constituents should extend to 10 or 20 km around an implosion site. These findings point to a number of complex and problematic issues regarding implosions and safeguarding human health and suggest that implosions in metropolitan areas should be prohibited. Further work to characterize the public health risks of conventional versus implosion demolition is recommended.