首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1741篇
  免费   238篇
  国内免费   750篇
安全科学   215篇
废物处理   112篇
环保管理   132篇
综合类   1350篇
基础理论   254篇
污染及防治   375篇
评价与监测   108篇
社会与环境   92篇
灾害及防治   91篇
  2024年   17篇
  2023年   42篇
  2022年   146篇
  2021年   145篇
  2020年   156篇
  2019年   100篇
  2018年   127篇
  2017年   134篇
  2016年   101篇
  2015年   122篇
  2014年   136篇
  2013年   154篇
  2012年   141篇
  2011年   173篇
  2010年   145篇
  2009年   128篇
  2008年   129篇
  2007年   94篇
  2006年   102篇
  2005年   88篇
  2004年   68篇
  2003年   32篇
  2002年   24篇
  2001年   26篇
  2000年   39篇
  1999年   30篇
  1998年   25篇
  1997年   28篇
  1996年   18篇
  1995年   13篇
  1994年   13篇
  1993年   6篇
  1992年   6篇
  1991年   3篇
  1990年   8篇
  1989年   2篇
  1988年   2篇
  1986年   5篇
  1985年   1篇
排序方式: 共有2729条查询结果,搜索用时 437 毫秒
411.
目的 掌握CAF失效机理MTTF分析方法,以便于在实际案例中实施工程优化决策,从而降低故障危害风险和寿命周期总费用。方法 以某航电电源母板CAF失效为例,基于CAF失效机理的物理化学变化时间特性模型算法,建立电压、介质间距和MTTF变化关系,以辅助工程优化决策。结果 基于仿真计算数据,形成对特定范围产品的改进和处置决策,从而限制失效危害风险的进一步扩散,降低了产品生命周期维护费用,并提升了客户满意度。结论 掌握装备常见失效机理和采取适宜的应对措施,是持续改进装备可用性、可靠性和环境适应性的必要条件。  相似文献   
412.
本文综述了碳链延长技术在处理有机废料及碳资源回收领域的优势,梳理了其发展历程为后续研究提供方向指导,阐释了其生化代谢途径中物质转变、能量传递和信号传输等机理,验证了其延长为丁酸、己酸等产物的热力和动力学可行性,总结归纳了其已优化的关键反应参数和已运行的工程试验案例等方面内容.本文为揭示细胞碳链延长机制和应用碳链延长技术于实际废料治理提供理论基础和建议展望.  相似文献   
413.
对北京市通州区H再生水厂采用的A2/O+MBR工艺运行效果与不同环节碳排放特征进行研究.结果表明:2018年该再生水厂对BOD5,CODcr,NH4+-N,TN和TP的平均去除率分别为97.3%,94.1%,98.6%,77.0%,96.2%;全厂碳排放总量和吨水碳排放量呈春夏季节逐渐降低,秋冬季节缓慢升高的特征,全厂综合吨水碳排放量约为2.26kgCO2e/t.碳排放总量中能耗碳排放量占主要地位,CH4,N2O和物耗碳排放量占比较小;统计分析显示CH4,能耗和物耗吨水碳排放量与BOD5,TN进水浓度及BOD5去除率显著相关;N2O吨水碳排放量与TN与BOD5进水浓度显著相关;直接,间接吨水碳排放量与水量无显著相关性.  相似文献   
414.
Environment-friendly nano-catalysts capable of activating peroxymonosulfate (PMS) have received increasing attention recently. Nevertheless, traditional nano-catalysts are generally well dispersed and difficult to be separated from reaction system, so it is particularly important to develop nano-catalysts with both good catalytic activity and excellent recycling efficiency. In this work, magnetically recoverable Fe3O4-modified ternary CoFeCu-layered double hydroxides (Fe3O4/CoFeCu-LDHs) was prepared by a simple co-precipitation method and initially applied to activate PMS for the degradation of Rhodamine B (RhB). X-ray diffraction (XRD), fourier transform infrared spectrometer (FT-IR), scanning electron microscope (SEM), transmission electron microscopy (TEM), Brunauer-Emmett-Teller method (BET), and vibrating sample magnetometer (VSM) were applied to characterize morphology, structure, specific surface area and magnetism. In addition, the effects of several key parameters were evaluated. The Fe3O4/CoFeCu-LDHs exhibited high catalytic activity, and RhB degradation efficiency could reach 100% within 20 min by adding 0.2 g/L of catalyst and 1 mmol/L of PMS into 50 mg/L of RhB solution under a wide pH condition (3.0-7.0). Notably, the Fe3O4/CoFeCu-LDHs showed good super-paramagnetism and excellent stability, which could be effectively and quickly recovered under magnetic condition, and the degradation efficiency after ten cycles could still maintain 98.95%. Both radicals quenching tests and electron spin resonance (ESR) identified both HO? and SO4?? were involved and SO4?? played a dominant role on the RhB degradation. Finally, the chemical states of the sample's surface elements were measured by X-ray photoelectron spectroscopy (XPS), and the possible activation mechanism in Fe3O4/CoFeCu-LDHs/PMS system was proposed according to comprehensive analysis.  相似文献   
415.
Using a bottom-up estimation method, a comprehensive, high-resolution emission inventory of gaseous and particulate atmospheric pollutants for multiple anthropogenic sectors with typical local sources has been developed for the Harbin-Changchun city agglomeration (HCA). The annual emissions for CO, NOx, SO2, NH3, VOCS, PM2.5, PM10, BC and OC during 2017 in the HCA were estimated to be 5.82 Tg, 0.70 Tg, 0.34 Tg, 0.75 Tg, 0.81Tg, 0.67 Tg, 1.59 Tg, 0.12 Tg and 0.26 Tg, respectively. For PM10 and SO2, the emissions from industry processes were the dominant contributors representing 54.7% and 49.5%, respectively, of the total emissions, while 95.3% and 44.5% of the total NH3 and NOx emissions, respectively, were from or associated with agricultural activities and transportation. Spatiotemporal distributions showed that most emissions (except NH3) occurred in November to March and were concentrated in the central cities of Changchun and Harbin and the surrounding cities. Open burning of straw made an important contribution to PM2.5 in the central regions of the northeastern plain during autumn and spring, while domestic coal combustion for heating purposes was significant with respect to SO2 and PM2.5 emissions during autumn and winter. Furthermore, based on Principal Component Analysis and Multivariable Linear Regression model, air temperature, relative humidity, electricity and energy consumption, and the urban and rural population were optimized to be representative indicators for rapidly assessing the magnitude of regional atmospheric pollutants in the HCA. Such indicators and equations were demonstrated to be useful for local atmospheric environment management.  相似文献   
416.
Understanding the formation mechanisms of secondary air pollution is very important for the formulation of air pollution control countermeasures in China. Thus, a large-scale outdoor atmospheric simulation smog chamber was constructed at Chinese Research Academy of Environmental Sciences (the CRAES Chamber), which was designed for simulating the atmospheric photochemical processes under the conditions close to the real atmospheric environment. The chamber consisted of a 56-m3 fluorinated ethylene propylene (FEP) Teflon film reactor, an electrically-driven stainless steel alloy shield, an auxiliary system, and multiple detection instrumentations. By performing a series of characterization experiments, we obtained basic parameters of the CRAES chamber, such as the mixing ability, the background reactivity, and the wall loss rates of gaseous compounds (propene, NO, NO2, ozone) and aerosols (ammonium sulfate). Oxidation experiments were also performed to study the formation of ozone and secondary organic aerosol (SOA), including α-pinene ozonolysis, propene and 1,3,5-trimethylbenzene photooxidation. Temperature and seed effects on the vapor wall loss and SOA yields were obtained in this work: higher temperature and the presence of seed could reduce the vapor wall loss; SOA yield was found to depend inversely on temperature, and the presence of seed could increase SOA yield. The seed was suggested to be used in the chamber to reduce the interaction between the gas phase and chamber walls. The results above showed that the CRAES chamber was reliable and could meet the demands for investigating tropospheric chemistry.  相似文献   
417.
Environmental Science and Pollution Research - Cadmium (Cd) pollution has led to a serious deterioration in soil quality, plant growth, and human health. Therefore, restoration of soil quality is...  相似文献   
418.
Environmental Science and Pollution Research - The demand of wet wipes and masks has been rising worldwide since the outbreak of global COVID-19; however, with more reports about improper handling...  相似文献   
419.
Feng  Yanlu  Liu  Tong  Xu  Siyi  Ren  Yiyi  Ge  Yiling  Yin  Lihong  Pu  Yuepu  Liang  Geyu 《Environmental science and pollution research international》2022,29(46):69153-69175
Environmental Science and Pollution Research - The health risks caused by environmental pollution have long been of substantial concern. With the development of epigenetics, a large number of...  相似文献   
420.
Environmental Science and Pollution Research - Cardiovascular diseases (CVD) caused by household air pollution (HAP) have sparked widespread concern globally in the recent decade. Meanwhile,...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号