Movement of pertechnetate through soils: Hydrodynamic dispersion

Measurement of the hydrodynamic dispersion of pertechnetate (⁹⁹TcO^?₄) migrating towards the water-table complements other investigations of the partition of pertechnetate between soil solution and soil colloids. This study was performed on soil columns equilibrated with distilled water and through which a solution of ⁹⁹TcO₄NH₄ or ³⁶ClNa was percolated at constant rate. A theoretical elution curve was adjusted to the experimental points obtained from a sand column. An estimate could thus be made of the parameters characterizing the migration of pertechnetate. The model used here considered the presence of a ‘dead water’ zone in the column into which the solute penetrates by molecular diffusion only at a given rate. The elution curves obtained experimentally and theoretically have been compared with those for a non-reactive anion, ³⁶Cl^?. A simulationof the change of pertechnetate concentration in the eluate has been made for increasing values of the retention factor. The calculated curves confirm the very low mobility of this anion in soil.     

Effects of Lime and Ash Treatments on DOC Fractions and Low Molecular Weight Organic Acids in Soil Solutions of Acidified Podzolic Soils

Dissolved organic carbon (DOC) fractions and different low molecular weight organic acids (LMWOAs) were determined in soil solutions from two lime or ash treated Norway spruce sites in the south of Sweden. At Hasslöv, 3.45 t ha^-1 or 8.75 t ha^-1 dolomite were applied 15 years before sampling. Horröd was treated with 4.28 t ha^-1 ash and 3.25 t ha^-1 dolomite and sampled four years later. Propionate (7–268 M) and malonate (2–34 M) were the LMWOAsfound in the highest concentrations at Hasslöv. Two other LMWOAs dominated at Horröd, namely citrate (18–64 M)and fumarate (5–31 M). The differences in concentration of most of the determined LMWOAs at Hasslöv were significantly increased due to treatment. The LMWOAs comprised between 1.1–6.3% of the DOC at Hasslöv and 4.5–17.6% at Horröd. At Hasslöv normally 3–10% of the total acidity (TA) was due to LMWOAs and the average specific buffer capacity was 74 ± 22 mmol mol^-1C.The total DOC concentration in the mor layer solution was 16 mM for the dolomite treated plots compared to 10 mM at the untreated plot. A major part of the increase in DOC at the treated plots apparently had a hydrophobic character and was of high molecular weight corresponding to 3–10 kDa. The concentration of DOC < 1 kDa in the control and treated plots was similar.     

Influence of arsenic co-contamination on DDT breakdown and microbial activity

The impacts of arsenic co-contamination on the natural breakdown of 1,1,l1-trichloro-2,2-bis(4-chlorophenyl)ethane (DDT) in soil are investigated in a study of 12 former cattle dip sites located in northeastern NSW, Australia. This study examines the relationship between the intrinsic breakdown of DDT to 1,1 -dichloro-2,2-bis(4-chlorophenyl)ethane (DDD) and 1,l-dichloro-2,2-bis(4-chlorophenyl)ethylene (DDE), and the impacts of arsenic co-contamination on this breakdown. Between-site analysis demonstrated that arsenic at 2000 mg/kg gave a 50% reduction in the concentration of DDD compared to background arsenic of 5 mg/kg.Within-site analysis also showed the ratio of DDT:DDD increased in soils as arsenic concentrations increased. This within-site trend was also apparent with the DDT:DDE ratio, suggesting inhibition of DDT breakdown by arsenic co-contamination. Microbial activity was inhibited as residues of total DDTs and arsenic increased. Hence arsenic co-contamination and high concentrations of DDT in soil may result in an increased persistence of DDT in the environment studied.     

Technology,managerial, and policy initiatives for improving environmental performance in small-scale gold mining industry

This paper reviews a series of strategies for improving environmental performance in the small-scale gold mining industry. Although conditions vary regionally, few regulations and policies exist specifically for small-scale gold mining activity. Furthermore, because environmental awareness is low in most developing countries, sites typically feature rudimentary technologies and poor management practices. A combination of policy-, managerial- and technology-related initiatives is needed to facilitate environmental improvement in the industry. Following a broad overview of these initiatives, a recommended strategy is put forth for governments keen on improving the environmental conditions of resident small-scale gold mines.     

A Comparative Analysis of the Vegetation and Topsoil Cover Nutrient Status between Two Similarly Rehabilitated Ash Disposal Sites

The aim of this paper is to compare the rehabilitation result between two ash disposal sites with regard to its vegetation establishment and soil nutrient status. The study areas were situated in close proximity, in the Mpumalanga coalfield, South Africa. Although both areas received a similar amelioration treatment and were seeded with similar seed mixture the vegetation composition were significantly different. Both areas were poor in essential nutrients, this probably being one of the most limiting factors for vegetation establishment. No serious phytotoxic conditions, as is frequently experience with coal ash, could be identified. A regular monitoring and low level maintenance program is therefore proposed to improve the sustainability of the vegetation. The study proposed that results form such evaluations be used to identify performance standards for rehabilitated derelict land.     

Accumulation of Heavy Metals by in vitro cultures of plants

The aim of the project is to study heavy metals accumulation by the selected plants in both laboratory and field conditions. Within the experiments the aspen (Populus tremula × tremuloides), sunflower (Helianthus annuus) and corn (Zea mays) plants were studied. The reasons for this selection were: a fast growth of these plants, an accumulation capacity and an ability to survive in different types of soils. The study was carried out on the aspen plantlets grown in vitro. The plants were exposed to the aqueous solutions having concentrations 0.1 mM, 0.5 mM of Pb²⁺ or Ni²⁺, respectively. The accumulation capacityfor aspen, was about 70% of Pb²⁺ originally present in the solution. The starting concentration of Pb²⁺ (0.5 mM) exhibited no negative impact on the growth. Besides in vitro expositions, a pilot-scale phytoremediation experiment was carried out at the polluted industrial area (Zn – 75000 mg/kg), (Pb – 16000 mg/kg), (Cr – 590 mg/kg), (Cd – 90 mg/kg) and (Cu – 1700 mg/kg).     

USE OF HEMISPHERIC IMAGERY FOR ESTIMATING STREAM SOLAR EXPOSURE1

ABSTRACT: Solar exposure profoundly affects stream processes and species composition. Despite this, prominent stream monitoring protocols focus on canopy closure (obstruction of the sky as a whole) rather than on measures of solar exposure or shading. We identify a candidate set of solar exposure metrics that can be derived from hemispheric images. These metrics enable a more mechanistic evaluation of solar exposure than can be achieved with canopy closure metrics. Data collected from 31 stream reaches in eastern Oregon enable us to quantify and compare metrics of solar exposure from hemispheric images and a metric of canopy closure with a concave densiometer. Repeatability of hemispheric metrics is generally as good as or better than the densiometer closure metric, and variation in the analysis of hemispheric images attributable to differences between analysts is negligibly small. Metrics from the hemispheric images and the densiometer are typically strongly correlated, at the scale of an individual observation and for 150 m stream reaches, but not always in a linear fashion. We quantify the character of the uncertainty in the relationship between the densiometer and the hemispheric metrics. Hemispheric imagery produces repeatable metrics representing an important ecological attribute; thus those researching the effects of solar exposure on stream ecosystems should consider the use of hemispheric imagery.     

Differential effects of strain on two forms of work performance: individual employee sales and creativity

In this research, we develop and test a model of the links between psychological strain (subjective experiences of feeling conflict and tension) and work performance. Our model includes two types of strain (work strain and home strain) and two forms of work performance (quantity of individual sales performance and creativity). Thus we acknowledge the importance of work and non‐work sources of strain as well as the multidimensional nature of work performance. We test the proposed relationships with data collected over six months from a field sample of 195 hair salon stylists (personal service workers who interact directly with customers and provide services directly to individuals and not to other firms). Results demonstrate a positive relation between work strain and individual employee sales performance and a negative relation between home strain and employee creativity at work. Leader–member exchange moderated the effects of work strain and home strain on creativity. We discuss findings and implications, emphasizing multiple roles, the importance of differentiating types of strain, and the multidimensionality of work performance. We conclude by suggesting that strain may be particularly relevant to work performance of employees in jobs like those in our sample which are characterized by high social interdependence and low task interdependence. Copyright © 2001 John Wiley & Sons, Ltd.     

Planning behavior and perceived control of time at work

This study investigated two mediation models of time management. The first model consisted of parts of Macan's ( 1994 ) model. The second model combined this model with Karasek's ( 1998 ) Job Demand–Control model. Two sets of self‐report questionnaires were collected and were analyzed using structural equation modeling. The first model, in which perceived control of time was hypothesized to fully mediate the relation between planning behavior and work strain, job satisfaction, and job performance, was found to be less adequate than the second model, which added workload and job autonomy as independent variables. Results also indicated that partial, rather than full, mediation of perceived control of time fitted the data best. The study demonstrated the importance of studying both planning behavior and job characteristics, which was not part of past research. Copyright © 2004 John Wiley & Sons, Ltd.