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551.
Determination of hydrocarbons in old creosote contaminated soil using headspace solid phase microextraction and GC-MS. 总被引:3,自引:0,他引:3
Headspace solid phase microextraction (HS-SPME) has been used together with GC-MS to analyze organic substances directly in a soil, heavily contaminated with PAHs/creosote (approximately 300 mg/kg soil), from an old gaswork site in Stockholm, Sweden. The HS-SPME results, both qualitative and quantitative, were compared with traditional liquid extraction using ethyl acetate/hexane (20:80). It was shown that the concentrations determined with HS-SPME at 60 degrees C correlated well, for compounds containing up to two and three aromatic rings (naphthalenes, acenaphthene, acenaphthylene and fluorenes, while a lower concentration was obtained for phenanthrene, anthracene, fluoranthene and pyrene. The total concentrations for each compound determined with HS-SPME ranged from 2 to 25 microg/g soil. Quantification was done using standard addition of compounds directly to the soil samples. The bioavailable fraction of the compounds in the contaminated soil at 20 degrees C was analyzed using external calibration by spiking sterile uncontaminated sand (same texture and particle size as the contaminated soil but without a heavily sorbed organic fraction) with hydrocarbon standards in different concentrations. Storage of exposed fibers at 20 degrees C showed that analysis should be done within two days to make qualitative measurements and earlier (as soon as possible) for quantitative determinations. 相似文献
552.
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554.
J T Smith O V Voitsekhovitch L H?kanson J Hilton 《Journal of environmental radioactivity》2001,56(1-2):11-32
Following a radioactive fallout event, there are a number of possible intervention measures to reduce radioactive doses to the public via the surface water pathway. We have critically reviewed the options available to decision-makers in the event of radioactive contamination of surface waters. We believe that the most effective and viable measures to reduce radioactivity in drinking water are those which operate at the water treatment and distribution stage. Intervention measures to reduce concentrations of radioactivity in rivers and reservoirs are expected to be much less viable and efficient at reducing doses via the drinking water pathway. Bans on consumption of freshwater fish can be effective, but there are few viable measures to reduce radioactivity in fish prior to the preparation stage. Lake liming and biomanipulation have been found to be ineffective for radiocaesium, although the addition of potassium to lakewaters appears promising in some situations. Lake liming may be effective in reducing radiostrontium in fish, though this has not, to our knowledge, been tested. De-boning fish contaminated by strontium is probably the most effective food preparation measure, but salting and freezing can also reduce radiocaesium concentrations in fish. The provision of accurate information to the public is highlighted as a key element of countermeasure implementation. 相似文献
555.
H Vandenhove Y Thiry A Gommers F Goor J M Jossart E Holm T G?fvert J Roed A Grebenkov S Timofeyev T G?ufert 《Journal of environmental radioactivity》2001,56(1-2):157-184
When dealing with large-scale environmental contamination, as following the Chernobyl accident, changed land use such that the products of the land are radiologically acceptable and sustain an economic return from the land is a potentially sustainable remediation option. In this paper, willow short rotation coppice (SRC) is evaluated on radiological, technical and economic grounds for W. European and Belarus site conditions. Radiocaesium uptake was studied in a newly established and existing SRC. Only for light-texture soils with low soil potassium should cultivation be restricted to soils with contamination levels below 100-370 kBq m-2 given the TFs on these soils (5 x 10(-4) and 2 x 10(-3) m2 kg-1) and considering the Belarus exemption limit for firewood (740 Bq kg-1). In the case of high wood contamination levels (> 1000 Bq kg-1), power plant personnel working in the vicinity of ash conveyers should be subjected to radiation protection measures. For appropriate soil conditions, potential SRC yields are high. In Belarus, most soils are sandy with a low water retention, for which yield estimates are too low to make production profitable without irrigation. The economic viability should be thoroughly calculated for the prevailing conditions. In W. Europe, SRC production or conversion is not profitable without price incentives. For Belarus, the profitability of SRC on the production side largely depends on crop yield and price of the delivered bio-fuel. Large-scale heat conversion systems seem the most profitable and revenue may be considerable. Electricity routes are usually unprofitable. It could be concluded that energy production from SRC is potentially a radiologically and economically sustainable land use option for contaminated agricultural land. 相似文献
556.
Female and male reproductive interests often differ. In species in which matings are accompanied by a transfer of resources
valuable for both participants, such as nuptial prey gifts, conflicts may readily occur. Scorpionflies may use alternative
mating tactics. One is to offer a prey item (dead arthropod) to females in exchange for mating. This prey gift tactic includes
a conflict because a male must decide on whether to offer the gift rather than to fight the female and consume the gift. The
outcome may depend on the nutritional status of both males and females. Males may be more willing to give if they themselves
are satiated and the condition of the females may influence the payoff from the males’ investment. Similarly, females may
be more willing to accept food gifts if they are in poor nutritional condition. In this study of the scorpionfly Panorpa cognata, I experimentally manipulated the feeding history of both males and females. I observed the outcome of the direct interactions
that followed when males that were holding prey were approached by females. I found that well-fed males offered the food gift
sooner than males in poor nutritional condition that fed extensively on the food item before offering. Female condition had
no significant influence on whether prey items were offered by males or accepted by females. I also found that well-fed males
rarely searched for prey to pursue the prey gift tactic in courtship. Thus, the prey tactic does not seem to be the males’
first option. 相似文献
557.
Th. Knacker und J. R?mbke 《Umweltwissenschaften und Schadstoff-Forschung》2008,20(4):301-302
Ohne Zusammenfassung 相似文献
558.
Ohne Zusammenfassung
Original erschienen in UWSF – Z Umweltchem ?kotox 20(2):133–144 (2008) DOI:
Herausgeber: Martin Pehnt und Eckard Helmers 相似文献
559.
This work examines the performance of a hydrous ferric oxide (HFO) reactive filtration (RF) process with coupled chemically enhanced secondary treatment (RECYCLE) for phosphorus removal from municipal wastewater (HFO-RF-RECYCLE). A 3-month, 0.95-ML/d (0.25-mgd) demonstration of HFO-RF-RECYCLE was performed at a municipal wastewater treatment plant equipped with oxidation ditches and secondary clarifiers. Influent to the plant averaged 6.0 mg/L phosphorus, with a tertiary effluent average of 0.011 mg/L phosphorus. Iron doses to the plant were low, at 5 mg/L. Inline recycling of HFO solution rejects to the plant influent resulted in a maximum 90.3%, dose-dependent reduction of phosphorus in the secondary effluent at 4.5 ML/d (1.2 mgd). Other results included reduction of total suspended solids and turbidity. A mass balance analysis was performed. We conclude that HFO-RF-RECYCLE may allow very low levels of phosphorus discharge from municipal wastewater treatment plants with a ferric-iron-based tertiary filtration process and residual recycling. 相似文献
560.
Asbj?rn Haaning Nielsen Jes Vollertsen Henriette Stokbro Jensen Heidi Ina Madsen Thorkild Hvitved-Jacobsen 《Water environment research》2008,80(1):16-25
The formation and fate of sulfide in a force main and a downstream-located gravity sewer were investigated in an extensive field study. Sulfide formation in the force main was significant. However, during 14 minutes of transport in the gravity sewer, the sulfide concentration decreased 30%, on average. An application of a conceptual sewer process model for simulating the formation and fate of sulfide was demonstrated. Overall, the model predicted that approximately 90% of the decrease of the sulfide concentration in the gravity sewer was the result of sulfide oxidation and that only a small fraction entered the sewer atmosphere, causing odor and corrosion. Even so, the model predicted concrete corrosion rates of up to 1.2 mm/y in the gravity sewer section. 相似文献