Characterization of hydrocarbon pollutant burdens in petrochemical and refinery process streams

This paper describes techniques which provide for both qualitative and quantitative identification of major components in a process stream. The techniques and instrumentation have been deliberately chosen so as to be within the technical and financial reach of all but the smallecompany laboratory. The sample preparation steps consist of an initial series of extractions which isolate compounds into organic acid, base, and neutral compounds and a totally water soluble phase. Each fraction is then concentrated and subjected to thin-layer chromatography, gas chromatography, infrared spectroscopy or ultraviolet spectroscopy as appropriate. Results are given for laboratory samples, one a mixture of aniline, phenol, benzoic acid, m-nitrobenzaldehyde, 1-butanol, 2-hexanone, nonane, and cyclohexane, and the other a mixture of benzene, ethylbenzene, and styrene. Also, a qualitative analysis of a petroleum refinery desalter water is presented.     

The Grimsel (Switzerland) migration experiment: integrating field experiments, laboratory investigations and modelling

For several years tracer migration experiments are performed at Nagra's Grimsel Test Site in the Swiss Alps as a joint undertaking of Nagra, PNC and PSI. The aim is to develop methods for field experiments at possible sites for nuclear waste repositories and to test radionuclide transport models.A hydraulic dipole field is generated in a well-defined fracture zone in granite. The tracers used are non-sorbing (uranine, ³He, ⁴He, ⁸²Br⁻, ¹²³I⁻), mildly sorbing (²²Na⁺, ²⁴Na⁺), and more strongly sorbing (⁸⁵Sr²⁺, ⁸⁶Rb⁺, ¹³⁴Cs⁺, ¹³⁷Cs⁺). These experiments have been complemented by extensive laboratory investigations on petrography, on water-rock and nuclide-rock interaction as well as by migration experiments with bore cores.The main questions addressed are: What are the relevant geometric factors and mechanisms for transport, how well can breakthrough curves be extrapolated from one dipole arrangement to another, which parameters are scale dependent, is there a difference in sorption values between laboratory and field experiments or between static and dynamic experiments. Evaluating the experimental results for the non-sorbing uranine and the mildly sorbing tracers sorption, Strontium, we show that a consistent picture of tracer transport, and specifically of tracer sorption, is obtained when exploiting all available experimental information and using not too simplistic models.     

EFFECT OF pH ON PHOSPHORUS RELEASE DURING MACROPHYTE (ELEOCHARIS sp.) DECOMPOSITION1

ABSTRACT: Laboratory microcosms were used to evaluate the effect of pH on release of soluble reactive phosphorus (SRP) during aerobic decomposition of the aquatic macrophyte Eleocharis sp., which is common in oligotrophic Florida lakes. The total amount of SRP released during a 227-day incubation in the dark was independent of pH over the range 3.7 to 5.5, but initial rates of release were faster at the lowest pH. The results indicate that the low total phosphorus concentrations observed in many acidic lakes are not necessarily attributable to reduced rates of decomposition and nutrient mineralization at low pH, as some researchers have suggested.     

THE DEVELOPMENT OF A PLAN OF STUDY – AN INTERAGENCY APPROACH TO MULTIOBJECTIVE PLANNING AND EVALUATION OF WATER AND LAND RESOURCE USE1

ABSTRACT The paper presents a systems approach for planning and evaluating alternative plans for resource use incorporating the concepts of multiobjective planning and evaluation (MOPE). The need for multidisciplinary input and strong interagency cooperation in planning for resource use is related to the logical and orderly completion of the planning steps. The paper briefly describes MOPE, emphasizing two important concepts: (1) the relationship of the study problems and objectives to national social objectives, and (2) the display of alternative solutions showing tradeoffs. Several important characteristics of a plan of study which implements MOPE are presented and discussed. A proposed MOPE analytical system is discussed in detail. The MOPE analytical system is divided into eight interdependent subsystems that describe data collection, use, analysis, and results. A linear program (L.P.) model is proposed to analyze the present and future demand relationships for natural resources. The model will also evaluate the interaction of agriculture, forestry, and recreation with the resource base of the basin, considering National Economic Development, Environmental Quality, and Regional Development.     

MODERNIZATION OF NATIONAL WEATHER SERVICE RIVER FORECASTING TECHNIQUES1

The National Weather Service is nearing the conclusion of a five year period of transition from index type catchment modelling to the use of conceptual hydrologic models. The decision to make this technological change was based on an extensive research project in which various catchment models were tested in a wide variety of basins and their strong and weak points ascertained. This project is described. Some of the problems involved in the changeover, which are discussed, are practical parameter optimization methods, computer requirements for the more complex technology, data requirements, fitting of the catchment model to major river systems, training of personnel and staffing problems.     

Application of SMR to Modeling Watersheds in the Catskill Mountains

Very few hydrological models commonly used in watershed management are appropriate for simulating the saturation excess runoff. The Soil Moisture Routing model (SMR) was developed specifically to predict saturation excess runoff from variable source areas, especially for areas where shallow interflow controls saturation. A recent version of SMR was applied to two rural catchments in the Catskill Mountains to evaluate its ability to simulate the hydrology of these systems. Only readily available meteorological, topographical, and landuse information from published literature and governmental agencies was used. Measured and predicted streamflows showed relatively good agreement; the average Nash–Sutcliffe efficiency for the two watersheds were R ²=72% and R ²=63%. Distributed soil moisture contents and the locations of hydrologically sensitive areas were also predicted well.