油田采出液乳化程度的影响因素试验研究

通过模拟油田采出液,考察了油水比、聚合物、表面活性剂及天然固体颗粒物对油田采出液乳化程度的影响。试验表明:随着油水比下降,模拟水样含油量降低,油珠Zeta电位升高,平均粒径变大,水样乳化稳定性减弱;HPAM会吸附于油珠表面从而增强其负电性,降低油珠间的有效碰撞,使油珠的平均粒径较小,导致油水分离较困难;表面活性剂会直接降低水样的表面张力,增强油水亲和性,导致水样含油量增大,同时增强了油珠的负电性,不利于油珠的集结聚并;天然固体颗粒物本身有一定的电负性,降低了油珠的Zeta电位,增加油珠的静电排斥,妨碍油珠的聚并,同时使水样的含油量升高,最终导致乳状液稳定。     

富水区隧道渗漏病害虹吸排水处置方法模型试验研究

针对隧道渗漏水病害问题,提出了一种新型隧道虹吸排水处置方法。通过室内物理模型试验,分析了虹吸排水作用对隧道围岩地下水的影响。结果表明:虹吸排水系统对地下水位的分布影响较大,虹吸管处地下水位变化尤为明显。降雨强度是影响虹吸排水流量的重要因素,降雨强度增大,虹吸排水流量先增大后维持最大流量不变,降雨所需疏干时间增长。围岩渗透系数与虹吸管径是影响地下水位分布与虹吸排水效果的重要因素,围岩渗透系数与虹吸管径越大,地下水位整体降深越大,虹吸排水流量维持在最大流量的稳定时间越短,地下水疏干时间越短,虹吸排水效果越好。     

Managing the adverse thermal effects of urban development in a densely populated Chinese city

Guangzhou city in South China has experienced an accelerated urban development since the 1980s. This paper examines the impact of the urban development on urban heat islands through a historical analysis of urban-rural air temperature differences. Remote sensing techniques were applied to derive information on land use/cover and land surface temperatures and to assess the thermal response patterns of land cover types. The results revealed an overriding importance of urban land cover expansion in the changes in heat island intensity and surface temperature patterns. Urban development was also related to a continual air temperature increase in the 1980s and 1990s. The combined use of satellite-derived vegetation and land cover distributions with land surface temperature maps provides a potential useful tool for many planning applications. The city's greening campaigns and landscaping designs should consider the different cooling effects of forest, shrubs and grassy lawns for temperature control and should plant more tall trees.     

动态臭氧/紫外线法处理磺基水杨酸废水

研究了在有或无紫外线 (UV)照射的条件下臭氧 (O3 )对磺基水杨酸废水的处理效果。用O3 与UV协同处理磺基水杨酸废水比仅用O3 和仅用UV的处理效果好得多 ,其COD去除率大于后二者的COD去除率之和。试验选用的动态O3 /UV法处理磺基水杨酸废水的工艺条件为 :O3 发生器放电功率 90 %× 180W ,UV功率 14W ,废水循环流速 10 0mL/min ,处理时间 90min。在此条件下 ,废水COD去除率可达 80 %左右。在上述的O3 发生器放电功率、UV功率、废水循环流速条件下 ,处理 1min时废水变澄清     

汕头市地震灾害评估方案

本文根据汕头市城市现状,提出了汕头市地震灾害评估方案。包括利用GIS建立地区小区划数据库,房屋基本数据库,生命线系统基本数据库,基本图形数据库,地震灾害评估知识库和地震灾害评估决策系统。     

苏南典型城区河网地区沉积物重金属调查研究

本研究对太湖上游集水区重要城市常州城区河网的12条主要河流开展了城市主要河道沉积物中的重金属分布状况及特征调查,采用Hakanson生态风险指数法对沉积物中的主要重金属对所在水域的污染程度及对水域和周围环境造成的潜在风险影响进行了评价。结果显示,常州河道沉积物已受到严重污染,不同类型河道的沉积物污染程度趋势为:城区>郊区>城市外围河道,其中以Hg的污染最重。     

福建省山仔水库水质现状及演变趋势分析

依据1996年-2010年监测数据及实际观测情况,分析了山仔水库水质现状和长期变化趋势。水库建库初期,水质状况比较好,但随着外源污染输入和内源污染释放,水体中的各项污染物指标水平升高,特别是氮磷营养物质。控制外源污染近10年之后,水库水质有了明显好转,蓝藻水华现象亦呈减少趋势,但水体中的氮磷营养物质仍维持在一定水平,高于富营养化临界浓度,水库的生态治理仍不容忽视。     

Preparation methods and thermal stability of Ba-Mn-Ce oxide catalyst for NOx-assisted soot oxidation

Manganese oxide-loaded and -doped ceria as well as the corresponding barium-modified oxide catalysts were prepared for soot oxidation in the presence of NOx, and were characterized by using X-ray diffraction, Brunauer-Emmett-Teller and NO temperatureprogrammed oxidation measurements. The activity of catalyst depended strongly on the NO2 production capacity, and the importance of surface nitrates was weakened without heat transfer limitations. The formation of perovskite-type oxides after the high-temperature calcination caused the loss of NOx storage capacity for the Ba-modified catalysts, but did not seem to affect the NO oxidation activity obviously. The addition of barium did not prevent the phase separation of MnOx-CeO2 solid solutions, whereas it inhibited the sintering of oxide crystallites effectively. This, as well as the relatively high surface area, resulted in a small increase in soot oxidation temperature for the thermally aged Ba/Mn-Ce catalyst.     

环保督政约谈机制分析:以安阳市为例

环保督政约谈制度是环保新常态下的一项制度尝试。本文以安阳市作为案例点,从约谈的法律依据、整改措施等方面对环保督政约谈制度进行了研究。研究发现环保督政约谈制度有一定的法律基础,在国外和国内许多行业也有类似的实践,实施该制度以来已取得一定成效,但也存在部分措施行政色彩较重、长效机制缺乏、环境问题责任界定不清等问题。文章提出了要明确政府部门职责,提高环保执法能力并建立“尽责免责”机制,要创新约谈模式,试行“党政同责”和“部门问责”,强化整改措施落实,加大信息公开并加强监督和跟踪评估,逐步建立环保“阳光”约谈的长效机制等建议。     

Effect of water vapor on NH3-NO/NO2 SCR performance of fresh and aged MnOx-NbOx-CeO2 catalysts

A MnOx–NbOx–CeO2 catalyst for low temperature selective catalytic reduction(SCR) of NOx with NH3 was prepared by a sol–gel method, and characterized by NH3–NO/NO2 SCR catalytic activity, NO/NH3 oxidation activity, NOx/NH3 TPD, XRD, BET, H2-TPR and in-situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy(DRIFTS). The results indicate that the Mn Ox–Nb Ox–CeO2 catalyst shows excellent low temperature NH3-SCR activity in the temperature range of 150–300℃. Water vapor inhibits the low temperature activity of the catalyst in standard SCR due to the inhibition of NOx adsorption. As the NO2 content increases in the feed, water vapor does not affect the activity in NO2 SCR. Meanwhile, water vapor significantly enhances the N2 selectivity of the fresh and the aged catalysts due to its inhibition of the decomposition of NH4NO3 into N2O.