全文获取类型
收费全文 | 1926篇 |
免费 | 145篇 |
国内免费 | 463篇 |
专业分类
安全科学 | 176篇 |
废物处理 | 66篇 |
环保管理 | 167篇 |
综合类 | 1070篇 |
基础理论 | 276篇 |
污染及防治 | 489篇 |
评价与监测 | 137篇 |
社会与环境 | 94篇 |
灾害及防治 | 59篇 |
出版年
2024年 | 8篇 |
2023年 | 30篇 |
2022年 | 92篇 |
2021年 | 86篇 |
2020年 | 73篇 |
2019年 | 47篇 |
2018年 | 56篇 |
2017年 | 63篇 |
2016年 | 72篇 |
2015年 | 80篇 |
2014年 | 110篇 |
2013年 | 158篇 |
2012年 | 166篇 |
2011年 | 170篇 |
2010年 | 135篇 |
2009年 | 148篇 |
2008年 | 126篇 |
2007年 | 151篇 |
2006年 | 123篇 |
2005年 | 72篇 |
2004年 | 85篇 |
2003年 | 96篇 |
2002年 | 63篇 |
2001年 | 68篇 |
2000年 | 46篇 |
1999年 | 36篇 |
1998年 | 24篇 |
1997年 | 37篇 |
1996年 | 17篇 |
1995年 | 4篇 |
1994年 | 15篇 |
1993年 | 11篇 |
1992年 | 12篇 |
1991年 | 15篇 |
1990年 | 3篇 |
1989年 | 3篇 |
1988年 | 6篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1979年 | 4篇 |
1978年 | 1篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1973年 | 1篇 |
1971年 | 3篇 |
排序方式: 共有2534条查询结果,搜索用时 890 毫秒
421.
王玲 《环境污染治理技术与设备》2006,7(1):129-131
以磷钨酸为光催化刺,在紫外灯照射下。对模拟染料废水甲基橙溶液进行光催化降解,并研究了催化剂加入量、pH值、甲基橙初始浓度和外加氧化剂H2O2对光催化降解效果的影响。结果表明,磷钨酸光催化剂加入量为300mg/100mL,pH=2.5时,甲基橙溶液的降解率明显高于其他pH值的降解率;在较低浓度下,甲基橙溶液的光催化降解反应符合一级动力学方程;外加氧化剂H2O2可提高光催化反应速率。 相似文献
422.
Rapid degradation of butachlor in wheat rhizosphere soil 总被引:16,自引:0,他引:16
The degradative characteristics of butachlor in non-rhizosphere, wheat rhizosphere, and inoculated rhizosphere soils were measured. The rate constants for the degradation of butachlor in non-rhizosphere, rhizosphere, and inoculated rhizosphere soils were measured to be 0.0385, 0.0902, 0.1091 at 1 mg/kg, 0.0348, 0.0629, 0.2355 at 10 mg/kg, and 0.0299, 0.0386, 0.0642 at 100 mg/kg, respectively. The corresponding half-lives for butachlor in the soils were calculated to be 18.0, 7.7, 6.3 days at 1 mg/kg, 19.9, 11.0, 2.9 days at 10 mg/kg, and 23.2, 18.0, 10.8 days at 100 mg/kg, respectively. The experimental results show that the degradation of butachlor can be enhanced greatly in wheat rhizosphere, and especially in the rhizosphere inoculated with the bacterial community designated HD which is capable of degrading butachlor. It could be concluded that rhizosphere soil inoculated with microorganisms-degrading target herbicides is a useful pathway to achieve rapid degradation of the herbicides in soil. 相似文献
423.
Accumulation of lead, zinc, copper and cadmium by 12 wetland plant species thriving in metal-contaminated sites in China 总被引:32,自引:0,他引:32
The concentrations of lead, zinc, copper and cadmium accumulated by 12 emergent-rooted wetland plant species including different populations of Leersia hexandra, Juncus effusus and Equisetum ramosisti were investigated in field conditions of China. The results showed that metal accumulation by wetland plants differed among species, populations and tissues. Populations grown in substrata with elevated metals contained significantly higher metals in plants. Metals accumulated by wetland plants were mostly distributed in root tissues, suggesting that an exclusion strategy for metal tolerance widely exists in them. That some species/populations could accumulate relatively high metal concentrations (far above the toxic concentration to plants) in their shoots indicates that internal detoxification metal tolerance mechanism(s) are also included. The factors affecting metal accumulation by wetland plants include metal concentrations, pH, and nutrient status in substrata. Mostly concentrations of Pb and Cu in both aboveground and underground tissues of the plants were significantly positively related to their total and/or DTPA-extractable fractions in substrata while negatively to soil N and P, respectively. The potential use of these wetland plants in phytoremediation is also discussed. 相似文献
424.
Occurrence, sources, and inventory of hexabromocyclododecanes (HBCDs) in soils from Chongming Island, the Yangtze River Delta (YRD) 总被引:6,自引:0,他引:6
Hexabromocyclododecanes (HBCDs) is a concern due to their large usage combining with physico-chemical properties and toxicity to wildlife and human. However, very limited data were reported on HBCDs in soils, especially from rural area. In this study, 22 soil samples were collected from Chongming Island at estuary of the Yangtze River Delta, to investigate the level, diasteroisomer profile, potential sources, and mass inventory of HBCDs. The total concentrations ranged from not detected to 93.8 pg g−1 dry weight (dw) with a mean of 23.3 pg g−1 dw, which was at the low end of the global levels. The wide distribution of HBCDs in soils suggested that the local emissions of HBCD-containing materials and/or the inputs via atmospheric transport from other regions were two possible sources. Variation of HBCDs levels was observed in different types of soils. Woodland, tideland and road soils contained slightly higher HBCDs than those of farmland and grassland. Overall, γ-HBCD was the dominant diasteroisomer in soils, followed by α-HBCD and β-HBCD. Significant but weak correlations were only found between α-HBCD and β-HBCD versus TOC content in soils. Currently, the mass inventory of HBCDs in soils of Chongming Island was 5.3 kg. Based on these data, we gave perspective on human intake of HBCDs via soil ingestion by age. Local resident’s intakes ranged from 15.5 to 97.8 fg kg body weight−1 d−1, in which children are exposed more than adults. 相似文献
425.
426.
利用生物操纵与人工湿地技术改善新建大房郢水库水质的实践 总被引:1,自引:0,他引:1
2005~2006年,在蓄水初期的大房郢水库采用投放滤食性鱼类鱼种、移殖螺、蚌、浅水区移植沉水植物、上游湿地扩大香蒲生长面积、消落区以上范围栽培杨树林和防护带等生物操纵与人工湿地技术相结合的方法改善水质的研究,结果表明:自2005年以来,该水库未再出现过蓝藻水华,水体富营养化得到了有效控制,水质已基本稳定在中-富营养型水平。由此认为,利用生物操纵与人工湿地技术结合为改善大房郢水库水质发挥了重要作用。 相似文献
427.
研究了利用NaClO在酸性条件下生成的HClO代替Fenton试剂中的氧化剂H2O2,在Fe^2+的作用下对乐果模拟废水进行处理。结果表明此方法处理乐果废水的效果比较明显。使用Fe^2+/NaClO氧化处理乐果模拟废水,在pH值等于2,NaClO与FeSO4·7H2O的投加量分别为10mL/L,2.5g/L,振荡时间为30min,乐果初始质量浓度小于53mg/L时,乐果的处理率大于88.90%。 相似文献
428.
采用快速液相色谱-三重四级杆串联质谱仪对吸烟、吸二手烟和不吸烟的居民的尿样进行抽检,分析了10种多环芳烃羟基代谢物(OH-PAHs)的组成和含量,评估了吸烟及吸二手烟对人体OH-PAHs内暴露水平的影响.结果表明,吸烟及吸二手烟对居民尿液中OH-PAHs的浓度水平和组成特征均有影响,对萘和芴的代谢产物影响最为显著.OH-PAHs的浓度水平按照吸烟组>吸二手烟组>不吸烟组的顺序递减,吸烟组和吸二手烟组人群尿液中萘的代谢产物2-羟基萘和1-羟基萘所占的比例分别是不吸烟组人群的1.5、1.2倍和1.7、1.9倍;吸烟、吸二手烟和不吸烟人群体内各OH-PAHs之间的相关性分析表明,吸二手烟人群体内OH-PAHs来源最为复杂,受环境空气和香烟烟雾的双重影响.与同类研究结果相比,本研究吸二手烟人群体内OH-PAHs明显偏低,这可能与吸二手烟人群受到烟气的暴露时间和暴露量有关. 相似文献
429.
不同温度下微生物和纤维素酶对发酵猪粪理化特性的影响 总被引:3,自引:0,他引:3
采用恒温发酵培养试验,研究了5℃和25℃时分别接种纤维素酶(X)、枯草芽孢杆菌(K)和EM菌(E)及其组合对新鲜猪粪发酵中的全氮、铵态氮、有机质、p H及微生物数量的影响.结果表明,5℃条件下,猪粪中微生物生长受抑制,细菌、真菌、放线菌数量均明显低于25℃,发酵终期猪粪有机质含量为70%~83%,p H值为7.16~7.36;25℃条件时,发酵终期猪粪有机质含量降至61%~72%,p H值升至8.09~8.94.与对照相比较,25℃下添加微生物和纤维素酶的处理有机质含量降低了2.95%~7.70%(除了K和XE处理),C/N值降低了4.04%~37.59%(除了XK处理),p H值增加了1.7%~26.8%.在总的添加量一致的条件下,发酵剂组合KE、XE、XK、XKE对猪粪发酵的效果优于单一发酵剂的X、K、E处理. 相似文献
430.