Adsorption selectivity of salicylic acid and 5-sulfosalicylic acid onto hypercrosslinked polymeric adsorbents

Both bottle-point and column-feeding experiments involving different solutes and sorbents were carried out to investigate the adsorption selectivity and separation performance of salicylic acid and 5-sulfosalicylic acid. Their adsorption isotherms onto such hypercrosslinked polymeric adsorbents as NDA-100 and NDA-99 could be well described by the Freundlich equations whose characteristics describe extrathermic and favorable adsorption processes. The adsorption towards NDA-100 mainly depended on the π-π interaction, while that towards NDA-99 was extremely influenced by the static-electric interaction. Additionally, the adsorptive capacity of salicylic acid on NDA-99 decreased while it increased on NDA-100 with the presence of 5-sulfosalicylic acid in the adsorptive environment as the competitive component. Comparatively, the adsorption capacity of 5-sulfosalicylic acid decreased on both resins with salicylic acid as the competitive component. In fact, the difference in the interaction between adsorbent and adsorbate resulted in the straight antagonism on the effective adsorption sites on the adsorbent. In conclusion, the adsorption selectivity of salicylic acid onto NDA-100 was obviously larger than that onto NDA-99 with the existence of 5-sulfosalicylic acid in the adsorptive environment. A satisfactory separation and recovery of tested solutes in aqueous phase could be foreseeably achieved by the sequencing adsorption technique involving NDA-100 as well as NDA-99. Translated from Environmental Pollution & Control, 2005, 27(8): 570–574 [译自: 环境污染与防治]     

Total nitrogen and community turnover determine phosphorus use efficiency of phytoplankton along nutrient gradients in plateau lakes

Numerous studies support that biodiversity predict most to ecosystem functioning, but whether other factors display a more significant direct impact on ecosystem functioning than biodiversity remains to be studied. We investigated 398 samples of the phytoplankton phosphorus resource use efficiency (RUE_P = chlorophyll-a concentration/dissolved phosphate) across two seasons in nine plateau lakes in Yunnan Province, China. We identified the main contributors to phytoplankton RUE_P and analyzed their potential influences on RUE_P at different lake trophic states. The results showed that total nitrogen (TN) contributed the most to RUE_P among the nine lakes, whereas community turnover (measured as community dissimilarity) explained the most to RUE_P variation across the two seasons. Moreover, TN also influenced RUE_P by affecting biodiversity. Species richness (SR), functional attribute diversity (FAD2), and dendrogram-based functional diversity (FDc) were positively correlated with RUE_P in both seasons, while evenness was negatively correlated with RUE_P at the end of the rainy season. We also found that the effects of biodiversity and turnover on RUE_P depended on the lake trophic states. SR and FAD2 were positively correlated with RUE_P in all three trophic states. Evenness showed a negative correlation with RUE_P at the eutrophic and oligotrophic levels, but a positive correlation at the mesotrophic level. Turnover had a negative influence on RUE_P at the eutrophic level, but a positive influence at the mesotrophic and oligotrophic levels. Overall, our results suggested that multiple factors and nutrient states need to be considered when the ecosystem functioning predictors and the biodiversity-ecosystem functioning relationships are investigated.     

煤矸石制非烧结砖的可行性研究

从实验室试验和工业性试验出发， 煤矸石制非烧结砖的可行性。研究结果表明，用煤矸石和适量固化剂制成的非绕结砖经过２８ｄ自然养护后，其质量和放射性均符合国家有关标准。利用煤矸石非烧砖无 技术上还是经济上都是可行和有利的。     

农村平原地区生态保护与发展绿色产业

江苏省姜堰市通过建设生态求救区这一综合措施，遵循生态经济原理，积极推广应用清洁生产工艺和生态技术，注重环境保护，推进绿色产业，落实了国家的可持续发展战略，为自然生态系统相似，经济发展水平相近的农村平原地区探索出一条可持续发展的道路，。     

污水海洋（江河）处置工程喷口的冲淤规律

结合上海市合流污水治理二期工程排放管稀释扩散规律及泥沙冲淤规律的研究，利用少运动相似理论，通过模型试验，从环境泥沙积在上管喷口上的最不利条件出发，分析喷口对泥沙的冲液规律，提出喷口冲淤临界速的概念，并据此提出适宜的上升管高度及喷口射流角度。     

磺酰脲类除草剂的残留分析

磺酰脲类除草剂是一类新型超高效除草剂，大约包括２Ｖ化合物，已被广泛用于禾谷作物防除阔叶杂草以及某些禾本科杂草，该类除草剂在环境中的残留浓度〈１μｇ．ｋｇ＾－１水平。常规的分析方法包括生物鉴定，酶免疫分析，气相色谱法和高效液相色谱法（ＨＰＬＣ）、ＨＰＬＣ／ＭＳ联用后，可以准确测定复杂环境样中磺酰脲类除草剂的痕量残留。     

水胺硫磷降解优势菌的筛选及其降解条件的研究

本文从已驯化好的活性污泥菌是悬液中分离筛选出水胺硫磷的降解优势菌，并对其降解条件进行了实验研究，当温度为２５℃，ＰＨ为６．５～７．５，水胺硫磷进水浓度１３５ｍｇ／Ｌ，停留时间为１２ｈ，在供氧条件下，水胺硫磷降解率可达７２．３％，而混合菌在最佳条件下，其水胺硫磷降解率为５５．８％，本文还要菌种进行了鉴定。     

锅炉烟气脱硫技术发展综述

在调查研究的基础上，论述国内外烟道气脱硫技术的发展与前景，提出开发生产适合我国国情的烟气脱硫技术势在必行。还简要介绍了最为普遍的石灰／石灰石法脱硫基本原理。     

昆明空气污染物等级与天气背景的关系

通过样本分析得出：昆明空气污染物主要为SO2,为轻度污染;秋冬季出现污染日较多,可分为高压脊控制型和偏西气流型天气背景。夏季出现污染日较少,主要为高压脊控制型天气背景;污染物浓度在一天中的分布特征呈“W”型;污染物预报方程。     

新疆阿尔泰地槽成矿元素分布特征

新疆阿尔泰地槽内成矿元素 ,自北东向南西分为四个带 ,每个带内分布有元素区和矿床 :①阿尔泰山北缘元素带 (阿克萨拉等区 ) ;②阿尔泰山中脊元素带 (冲呼等五个区和可可托海 3号脉稀有金属矿等矿床 ) ;③阿尔泰山南缘元素带 (阿舍勒等四个区和阿舍勒铜矿等矿床 ) ;④额尔齐斯元素带 (喀拉通克等区和喀拉通克铜镍矿等矿床 )。成矿元素区带是寻找新矿床的有利地段