In this work, biochar (BC), activated carbon (AC), and graphene oxide (GO) were thiol-functionalized using 3-mercaptopropyltrimethoxysilane (3-MPTS) (named as BCS, ACS, and GOS, respectively). BCS, ACS, and GOS were synthesized mainly via the interaction between hydrolyzed 3-MPTS and surface oxygen-containing functional groups (e.g., –OH, O–C=O, and C=O) and π-π interaction. The materials before and after modification were characterized and tested for mercury removal, including sorption kinetics and isotherms, the effects of adsorbent dosage, initial pH, and ionic strength. Pseudo-second-order sorption kinetic model (R2 = 0.992~1.000) and Langmuir sorption isotherm model (R2 = 0.964~0.998) fitted well with the sorption data of mercury. GOS had the most –SH groups with the largest adsorption capacity for Hg2+ and CH3Hg+ (449.6 and 127.5 mg/g), followed by ACS (235.7 and 86.7 mg/g) and BCS (175.6 and 30.3 mg/g), which were much larger than GO (96.7 and 4.9 mg/g), AC (81.1 and 24.6 mg/g), and BC (95.6 and 9.4 mg/g). GOS and ACS showed stable mercury adsorption properties at a wide pH range (2~9) and ionic strength (0.01~0.1 mol/L). Mercury maybe removed by ligand exchange, surface complexation, and electrostatic attraction.
Journal of Polymers and the Environment - Diclofenac sodium, as a typical deputation of non-steroidal anti-inflammatory drugs, is widely used in clinical treatment. Due to the heavy use, diclofenac... 相似文献
Hexane, a representative VOC, is used as a solvent for extraction and as an ingredient in gasoline. The degradation of hexane
by bacteria is relatively slow due to its low solubility. Moreover, the biodegradation pathway of hexane under aerobic conditions
remains to be investigated; therefore, a study relating to aerobic biodegradation mechanisms is required. Consequently, in
this study, an effective hexane degrader was isolated and the biodegradation pathway examined for the first time. In addition,
the degradation characteristics of a variety of recalcitrant hydrocarbons were qualitatively and quantitatively investigated
using the isolate. 相似文献
Environmental Chemistry Letters - The discharge of various pollutant-rich wastewater in large volumes without adequate treatment seriously endangers the environment. Catalytic and photocatalytic... 相似文献
Environmental Geochemistry and Health - The purpose of this study was to investigate the associations between levels of lead (Pb), cadmium (Cd), chromium (Cr), and manganese (Mn) in the PM2.5 and... 相似文献