The herbicides MCPA, butylate, atrazine and cyanazine are extensively used in Canadian agriculture and information regarding their effects on indigenous biota is scarce. Phytotoxicity assessments were conducted in the laboratory on the common green alga Selenastrum capricornutum using both the active ingredient of the herbicides and their formulated products (for MCPA and butylate). Endpoints determined after the 96 h exposure included algal population growth inhibition (IC50-cell counts), percent lethality (LC50-flow cytometry derived) and photosynthetic electron transport inhibition (EC50-fluorescence induction). Pesticide formulations had greater toxic effects than the active ingredient alone. The 96 h IC50 (50% Inhibition Concentration) and LOEC (Lowest Observable Effects Concentration) using cell counts of S. capricornutum were 18.4 and 8.9 mg l(-1) respectively for MCPA-active ingredient and for MCPA-formulated, these were 0.62 and 0.0062 mg l(-1) respectively. Those for butylateactive ingredient were 61.0 and 8.3 mg l(-1) and for butylate-formulated 1.46 and 0.17 mg l(-1), respectively. The triazines active ingredient, which are photosynthetic inhibitors, had greater effects than either the MCPA or butylate. The IC50 for cyanazine and atrazine were 0.059 and 0.026 mg l(-1), respectively. By comparing the IC50 and LC50 values for the tested active ingredients, it was found that the effects of atrazine were algicidal, whereas those of cyanazine, butylate and MCPA were algistatic. 相似文献
Many developed countries have targeted landfill methane recovery among greenhouse gas mitigation strategies, since methane is the second most important greenhouse gas after carbon dioxide. Major questions remain with respect to actual methane production rates in field settings and the relative mass of methane that is recovered, emitted, oxidized by methanotrophic bacteria, laterally migrated, or temporarily stored within the landfill volume. This paper presents the results of extensive field campaigns at three landfill sites to elucidate the total methane balance and provide field measurements to quantify these pathways. We assessed the overall methane mass balance in field cells with a variety of designs, cover materials, and gas management strategies. Sites included different cell configurations, including temporary clay cover, final clay cover, geosynthetic clay liners, and geomembrane composite covers, and cells with and without gas collection systems. Methane emission rates ranged from -2.2 to >10,000 mg CH(4) m(-2) d(-1). Total methane oxidation rates ranged from 4% to 50% of the methane flux through the cover at sites with positive emissions. Oxidation of atmospheric methane was occurring in vegetated soils above a geomembrane. The results of these studies were used as the basis for guidelines by the French environment agency (ADEME) for default values for percent recovery: 35% for an operating cell with an active landfill gas (LFG) recovery system, 65% for a temporary covered cell with an active LFG recovery system, 85% for a cell with clay final cover and active LFG recovery, and 90% for a cell with a geomembrane final cover and active LFG recovery. 相似文献
The objective of this study was to determine how structure, stratigraphy, and weathering influence fate and transport of contaminants (particularly U) in the ground water and geologic material at the Department of Energy (DOE) Environmental Remediation Sciences Department (ERSD) Field Research Center (FRC). Several cores were collected near four former unlined adjoining waste disposal ponds. The cores were collected, described, analyzed for U, and compared with ground water geochemistry from surrounding multilevel wells. At some locations, acidic U-contaminated ground water was found to preferentially flow in small remnant fractures weathering the surrounding shale (nitric acid extractable U [U(NA)] usually < 50 mg kg(-1)) into thin (<25 cm) Fe oxide-rich clayey seams that retain U (U(NA) 239 to 375 mg kg(-1)). However, greatest contaminant transport occurs in a 2 to 3 m thick more permeable stratigraphic transition zone located between two less permeable, and generally less contaminated zones consisting of (i) overlying unconsolidated saprolite (U(NA) < 0.01 to 200 mg kg(-1)) and (ii) underlying less-weathered bedrock (U(NA) generally < 0.01 to 7 mg kg(-1)). In this transition zone, acidic (pH < 4) U-enriched ground water (U of 38 mg L(-1)) has weathered away calcite veins resulting in greater porosity, higher hydraulic conductivity, and higher U contamination (U(NA) 106 to 745 mg kg(-1)) of the weathered interbedded shale and sandstone. These characteristics of the transition zone produce an interval with a high flux of contaminants that could be targeted for remediation. 相似文献
In this case study of a degraded tropical landscape, we examine how the protected area system in Hong Kong, China, should be modified to improve its efficiency in protecting the surprisingly rich biota. The challenge lies in the fine scale of site selection, and the absence of a core area with high species richness and rarity. Site selection was first conducted in 1 km grid units by selecting hotspots and irreplaceable sites using field records for eight groups of species (amphibians, reptiles, mammals, breeding birds, ants, butterflies, dragonflies and rare vascular plants). The habitats of conservation value within the selected grid units were then delineated on the basis of expert knowledge. Recommendations for increasing the total existing protected area by 6% (i.e. an additional 2% of Hong Kong's total land area) were submitted to the Government in August 2000. To test the robustness of the results, site selection was repeated in 2001 using updated data and different selection methods. The numbers of squares selected by complementarity-based algorithms were similar to those by the hotspots and irreplaceable site method. Sites selected for rare species were very sensitive to data completeness, implying that the application of complementarity-based algorithms at fine scales might be limited. 相似文献
The effectiveness of sewage purification by aquatic plants, such as water hyacinth (Eichhornia crassipes) and water lettuce (Pistia stratiotes), was tested on laboratory and pilot scales. Cascade and semi-continuous pilot experiments verified that the plants are capable of decreasing all tested indicators of water quality to levels that permit the use of the purified water for irrigation of tree crops. This applies to biochemical oxygen demand (BOD), chemical oxygen demand (COD), total suspended solids (TSS), and turbidity. The laboratory-scale tests confirm the capacity of the plants to reach and hold reasonably low levels of BOD (5-7 mg L(-1)) and COD (40-50 mg L(-1)) and very low levels of TSS (3-5 mg L(-1)) and turbidity (1-2 NTU). In the experimental pilot setup, with circulation, COD decreased from 460 to 100 mg L(-1) after 2.5-4 days of treatment, while 6-7 days were required to this end without circulation. This doubled the active pond area and provided a two-level hydraulic loading (8 and 12 L min(-1)) with circulation that proved to be effective during the summer as well as the winter season. The outflow concentrations were 50-85 mg L(-1) of COD and 4-6 mg L(-1) of BOD. The results show that the use of this free water surface flow system (FWS) and its low maintenance system for treatment of urban and agricultural sewage is a viable option. 相似文献
Fast economic and social changes in recent years in China have brought massive expansion, redevelopment, and restructuring
of cities. These changes offer cities the opportunity to improve environmental quality through urban green spaces (UGSs) and
to address the challenges of meeting community aspirations. This study explored peoples’ minds concerning UGSs in Guangzhou
city in south China in relation to the following: (1) knowledge and perception of 25 ecosystem services and 8 negative impacts;
(2) attitude toward site condition and management; (3) expectation of landscape design; and (4) preference ranking of venues.
A questionnaire was designed to solicit opinions from 340 respondents randomly chosen from residents living in the study area.
The results indicated widespread recognition of ecosystem services and strong support of UGS programs. Negative responses
were weakly expressed. Amelioration of urban microclimate and environmental quality were emphasized. Environmental functions
stressed in publicity programs, together with aggravating environmental problems in the city, tended to focus respondents’
attention on UGS benefits. Wildlife habitat, species conservation and other natural ecosystem services drew limited concerns.
Awareness of economic benefits was very low. Visual-landscape contributions with strong preference for naturalistic design
and recreational benefits were highlighted. Compared with other countries, Guangzhou residents were characterized by visual–scenic–recreation
orientation and pragmatic–utilitarian perception of UGSs, reflecting underlying differences in the understanding of inherent
ecosystem services of green spaces. Relevant UGS policies and practices could adopt the approaches of market survey, citizen
participation, and precision planning in order to meet increasingly mature and refined demands. Citizens’ understanding of
high-order ecosystem services could be enhanced to encourage appreciation of nature and their associated benefits. 相似文献
Environment, Development and Sustainability - Application of advanced techniques to ensure the environment sustainability and freshwater ecosystem conservation is a paramount importance. Industrial... 相似文献
An experimental study has been conducted to obtain the adsorption isotherms of four typical pollutants from quaternary aqueous systems onto decolourizing activated carbon. The four materials investigated are: Phenol, 1,4-dihydroxybenzene, 4-amino-l-naphthalene sulfonic acid-sodium salt and Benzoic acid. The study has concentrated on the dilute region of concentrations which range from 10 to 165 ppm (mg/L) at an operating temperature of 30 °C.
The quaternary adsorption equilibria have been modeled using the extended Langmuir predictive model and the ideal adsorbed solution (IAS) theory. In employing these models for the prediction of multicomponent adsorption equilibria, the single-solute isotherms are needed. These isotherms have been fitted to Langmuir, Freundlich, and Dubinin models and the resulting model parameters, which are needed for the prediction of multicomponent adsorption equilibria, are reported. Predictions obtained from the extended Langmuir predictive model and the ideal adsorbed solution (IAS) model are in agreement, however, they deviate to an appreciable extent from experimental observations. 相似文献
A study of the area, including Rosetta city and the estuary of the river Nile (Rosetta branch), has been carried out for assessment of the impact of sea level rise (slr). A geographic information system (GIS) has been built including layers of land use, topography, archeological sites, land cover and population. Analysis of data has been carried out to assess vulnerability of various land use and land cover classes to the impact of sea level rise.Because the area under study has geomorphic relief profiles just over the sea level, inundation of total land could reach 26% of total study area due to only half a meter rise in sea level. This lost area includes 32% of urban clusters mainly used for human shelter and contains 52% of present monuments, 25% of valuable high quality dense palm trees cultivation, 75% of beaches and 19% of lands suitable, 25% of valuable high quality dense palm trees cultivation, 75% of beaches and 19% of lands suitable for agricultural reclamation (although suffering from salt water intrusion and soil salinization). This is expected to cause a significant impact on the present population, economic activities, total regional revenue, and also on tourism. At 1.1 m sea level rise, 72% to total study area could be inundated. This area contains all beaches, half of the palm cultivation, 43% of total urban clusters, which includes 81% of the monumental sites and historic buildings.Other environmental problems such as solid waste management, sanitary disposal network, deteriorating conditions of some monumental structures, in addition to the sea level rise act negatively on the environmental quality of the urban community. Future plans for urban expansion in the area must be studied carefully in order to preserve valuable palm lands and maintain and protect monuments and historic sites which help the promotion of tourism. An environmental management program is essential for upgrading tourism, promoting urban development and protecting coastal lands. 相似文献