全文获取类型
收费全文 | 10785篇 |
免费 | 687篇 |
国内免费 | 3649篇 |
专业分类
安全科学 | 1010篇 |
废物处理 | 562篇 |
环保管理 | 814篇 |
综合类 | 6181篇 |
基础理论 | 1799篇 |
污染及防治 | 3312篇 |
评价与监测 | 478篇 |
社会与环境 | 511篇 |
灾害及防治 | 454篇 |
出版年
2024年 | 32篇 |
2023年 | 203篇 |
2022年 | 593篇 |
2021年 | 517篇 |
2020年 | 470篇 |
2019年 | 397篇 |
2018年 | 399篇 |
2017年 | 505篇 |
2016年 | 478篇 |
2015年 | 571篇 |
2014年 | 758篇 |
2013年 | 1024篇 |
2012年 | 917篇 |
2011年 | 939篇 |
2010年 | 764篇 |
2009年 | 687篇 |
2008年 | 779篇 |
2007年 | 625篇 |
2006年 | 648篇 |
2005年 | 462篇 |
2004年 | 358篇 |
2003年 | 361篇 |
2002年 | 360篇 |
2001年 | 267篇 |
2000年 | 311篇 |
1999年 | 297篇 |
1998年 | 233篇 |
1997年 | 221篇 |
1996年 | 193篇 |
1995年 | 156篇 |
1994年 | 117篇 |
1993年 | 119篇 |
1992年 | 108篇 |
1991年 | 81篇 |
1990年 | 34篇 |
1989年 | 34篇 |
1988年 | 25篇 |
1987年 | 16篇 |
1986年 | 14篇 |
1985年 | 10篇 |
1984年 | 6篇 |
1983年 | 4篇 |
1982年 | 9篇 |
1981年 | 6篇 |
1979年 | 2篇 |
1976年 | 1篇 |
1974年 | 2篇 |
1973年 | 3篇 |
1972年 | 2篇 |
1970年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 734 毫秒
521.
采用微电解-芬顿氧化的组合工艺处理末端焦化废水,考察静态实验中微电解填料的铁碳比、过氧化氢添加方式及加入量、曝气量、反应时间、pH值等不同条件因素对COD去除率的影响情况,确定最佳条件是铁碳质量比是2.5∶1,分批加入过氧化氢,且加入量为0.25 mL/L,曝气量为1.25 L/min,pH值为3,反应时间140 min.最终实现将焦化废水COD的去除率达88%以上的目的.按静态实验的各因素条件进行动态实验,试验结果COD去除率可达87%以上,处理后℃OD质量浓度为为91 mg/L,达到排放标准.同时处理后焦化废水的颜色变淡. 相似文献
522.
通过对锅炉型号的简要介绍,提高对锅炉的认识,增强在污染源动态更新调查表的填报过程中锅炉技术指标的填报能力是十分必要的。 相似文献
523.
524.
以安徽某县污水处理厂的改良氧化沟工艺调试为例,采用自然培菌和间歇培养相接合的方式进行调试,结果表明方法可行。在进水COD100mg/L时,MLSS在1500mg/L时,出水COD、NH4-N均可取得较好的处理效果。同时对调试过程中的各环节如人员培训、带负荷试车、污泥培养等进行了详细阐述,并确定了各工艺段的控制参数。 相似文献
525.
526.
527.
An organo-montmorillonite-supported nanoscale zero-valent iron material(M-NZVI) was synthesized to degrade decabromodiphenyl ether(BDE-209). The results showed that nanoscale zero-valent iron had good dispersion on organo-montmorillonite and was present as a core-shell structure with a particle size range of nanoscale iron between 30–90 nm, characterized by XRD, SEM, TEM, XRF, ICP-AES, and XPS. The results of the degradation of BDE-209 by M-NZVI showed that the efficiency of M-NZVI in removing BDE-209 was much higher than that of NZVI. The efficiency of M-NZVI in removing BDE-209 decreased as the pH and the initial dissolved oxygen content of the reaction solution increased, but increased as the proportion of water in the reaction solution increased. 相似文献
528.
Pinpin Lu Xiaojian Zhang Chiqian Zhang Zhangbin Niu Shuguang Xie Chao Chen 《环境科学学报(英文版)》2014,26(2):323-331
This study investigated the bacterial regrowth in drinking water distribution systems receiving finished water from an advanced drinking water treatment plant in one city in southem China. Thirteen nodes in two water supply zones with different aged pipelines were selected to monitor water temperature, dissolved oxygen (DO), chloramine residual, assimilable organic carbon (AOC), and heterotrophic plate counts (HPC). Regression and principal component analyses indicated that HPC had a strong correlation with chloramine residual. Based on Chick-Watson's Law and the Monod equation, biostability curves under different conditions were developed to achieve the goal of HPC 100 CFU/mL. The biostability curves could interpret the scenario under various AOC concentrations and predict the required chloramine residual concentration under the condition of high AOC level. The simulation was also carded out to predict the scenario with a stricter HPC goal (≤50 CFU/mL) and determine the required chloramine residual. The biological regrowth control strategy was assessed using biostability curve analysis. The results indicated that maintaining high chloramine residual concentration was the most practical way to achieve the goal of HPC ≤ 100 CFU/mL. Biostability curves could be a very useful tool for biostability control in distribution systems. This work could provide some new insights towards biostability control in real distribution systems. 相似文献
529.
Photocatalytic ozonation of phenol and oxalic acid (OA) was conducted with a Ag^+/TiO2 catalyst and different pathways were found for the degradation of different compounds. Ag^+ greatly promoted the photocatalytic degradation of contaminants due to its role as an electron scavenger. It also accelerated the removal rate of OA in ozonation and the simultaneous process for its complex reaction with oxalate. Phenol could be degraded both in direct ozonation and photolysis, but the TOC removal rates were much higher in the simultaneous processes due to the oxidation of hydroxyl radicals resulting from synergetic effects. The sequence of photo-illumination and ozone exposure in the combined process showed quite different effects in phenol degradation and TOC removal. The synergetic effects in different combined processes were found to be highly related to the properties of the target pollutants. The color change of the solution and TEM result confirmed that Ag+ was easily reduced and deposited on the surface of Tit2 under photo-illumination, and dissolved again into solution in the presence of ozone. This simple cycle of enrichment and distribution of Ag^+ can greatly benefit the design of advanced oxidation processes, in which the sequences of ozone and photo-illumination can be varied according to the needs for catalyst recycling and the different properties of pollutants. 相似文献
530.
Removal of polycyclic aromatic hydrocarbons (PAHs), e.g., naphthalene, acenaphthene, phenanthrene and pyrene, from aqueous solution by raw and modified plant residues was investigated to develop low cost biosorbents for organic pollutant abatement. Bamboo wood, pine wood, pine needles and pine bark were selected as plant residues, and acid hydrolysis was used as an easily modification method. The raw and modified biosorbents were characterized by elemental analysis, Fourier transform infrared spectroscopy and scanning electron microscopy. The sorption isotherms of PAHs to raw biosorbents were apparently linear, and were dominated by a partitioning process. In comparison, the isotherms of the hydrolyzed biosorbents displayed nonlinearity, which was controlled by partitioning and the specific interaction mechanism. The sorpfion kinetic curves of PAHs to the raw and modified plant residues fit well with the pseudo second-order kinetics model. The sorption rates were faster for the raw biosorbents than the corresponding hydrolyzed biosorbents, which was attributed to the latter having more condensed domains (i.e., exposed aromatic core). By the consumption of the amorphous cellulose component under acid hydrolysis, the sorption capability of the hydrolyzed biosorbents was notably enhanced, i.e., 6-18 fold for phenanthrene, 6-8 fold for naphthalene and pyrene and 5-8 fold for acenaphthene. The sorpfion coefficients (Kd) were negatively correlated with the polarity index [(O+N)/C], and positively correlated with the aromaticity of the biosorbents. For a given biosorbent, a positive linear correlation between logKoc and logKow for different PAHs was observed. Interestingly, the linear plots of logKoc-logKow were parallel for different biosorbents. These observations suggest that the raw and modified plant residues have great potential as biosorbents to remove PAHs from wastewater. 相似文献