全文获取类型
收费全文 | 2236篇 |
免费 | 150篇 |
国内免费 | 838篇 |
专业分类
安全科学 | 183篇 |
废物处理 | 139篇 |
环保管理 | 205篇 |
综合类 | 1327篇 |
基础理论 | 365篇 |
污染及防治 | 738篇 |
评价与监测 | 132篇 |
社会与环境 | 70篇 |
灾害及防治 | 65篇 |
出版年
2024年 | 1篇 |
2023年 | 43篇 |
2022年 | 174篇 |
2021年 | 162篇 |
2020年 | 107篇 |
2019年 | 74篇 |
2018年 | 97篇 |
2017年 | 137篇 |
2016年 | 113篇 |
2015年 | 147篇 |
2014年 | 189篇 |
2013年 | 260篇 |
2012年 | 208篇 |
2011年 | 196篇 |
2010年 | 145篇 |
2009年 | 140篇 |
2008年 | 166篇 |
2007年 | 122篇 |
2006年 | 143篇 |
2005年 | 96篇 |
2004年 | 60篇 |
2003年 | 46篇 |
2002年 | 45篇 |
2001年 | 40篇 |
2000年 | 49篇 |
1999年 | 53篇 |
1998年 | 49篇 |
1997年 | 40篇 |
1996年 | 35篇 |
1995年 | 22篇 |
1994年 | 18篇 |
1993年 | 11篇 |
1992年 | 8篇 |
1991年 | 7篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有3224条查询结果,搜索用时 15 毫秒
151.
152.
153.
154.
155.
156.
阳离子表面活性剂十六烷基三甲基溴化铵对酞酸酯类化合物增溶性研究 总被引:4,自引:0,他引:4
用阳离子表面活性剂十六烷基三甲基溴化铵对六种酞酸酯类化合物(五种脂肪链酞酸酯和一种苯基酞酸酯)进行了增溶性实验.结果表明,在表观浓度(Cs)小于临界胶速浓度(CMC)时,十六烷基三甲基溴化铵对四种酞酸酯(DMP和DPhP除外)有一定程度的增溶作用;当Cs大于CMC时,对六种化合物的增溶性显著增强.其增溶性(St/Sw)随Cs增大而线性递增:当Cs<CMC时,St/Sw=a+Kmn·Cs,r>0.90,n=5;当Cs>CMC时,St/Sw=a+Kmc·Cs,r>0.99,n=5. 各化合物增溶系数随各自固有水溶性(Sw)减小而增大(苯基酞酸酯有所反常),lgKmn和lgKmc与各自lgl/Sw具有良好的线性正相关性.本文进一步对增溶机理进行了分析解释. 相似文献
157.
以间歇-分阶段进水方式进行了模拟酸雨柱式动态淋溶实验.结果表明,间歇-阶段性酸雨入侵会影响填埋飞灰中Pb、Zn、Cu、Cr和Ni的浸出行为;尤其间歇停滞期后的初期酸雨入侵会增加多数重金属的再浸出水平,且该部分重金属的释放主要源于前阶段酸雨侵蚀过程中所形成的非稳定性(弱酸态)重金属.各酸雨侵蚀阶段,部分重金属(如Pb-Zn)的浸出行为具有相关性,这与各重金属在飞灰基质内的赋存形态、矿物相稳定性及酸性侵蚀程度等有关.各阶段酸雨入侵会相继溶出飞灰中的可溶性(NaCl、KCl等)、难溶性氯盐(CaClOH)以及微溶性钙盐(CaSO4),并增加CaCO3和Ca-Al-Si-O等矿物的峰强.各阶段酸雨入侵会使初始飞灰表面的团簇状结构逐渐被酸性(H+)侵蚀作用破坏,并暴露出大量棒状或条形状CaCO3晶体,且随着酸雨入侵次数的增加,CaCO3也将逐渐被侵蚀破坏.本研究为非连续酸性降雨条件下填埋稳定化飞灰的重金属浸出行为评价及风险管控提供了科学依据. 相似文献
158.
Qiang Huang Jianzhong Song Ying Zhong Ping’an Peng Weilin Huang 《Environmental monitoring and assessment》2014,186(1):247-256
Organochlorine pesticides (OCPs) have variously been phased out in agricultural activities, but they are still widely detected in air, water, and soil systems due to their recalcitrant nature in the environment. The purposes of this study were to assess potential OCP pollution via dry and wet deposition over the fast developing Pearl River Delta area with 41,700 km2, where the main effort has been focused on emerging pollutants such as petroleum hydrocarbons and PM2.5. We quantified both the dry and wet deposition fluxes of 19 OCPs including dichlorodiphenyltrichloroethanes (DDTs), endosulfans (Endos), and hexachlorocyclohexanes (HCHs). The results showed that each year about 67.4, 42.0, 15.0, and 8.07 kg of total OCPs, DDTs, Endos, and HCHs were returned to the ground, among which 11.7, 10.4, 0.84, and 0.16 kg were in the dry deposition forms. The large spatial variations in OCP deposition fluxes indicated that OCP pollution in the air is mainly influenced on local scales because evaporation from local soil is likely the major source of the phased out OCPs. Source analysis indicated that DDTs may be still in use as antifouling agent and/or dicofol, but Endos and HCHs were mainly derived from the residual of historical usage. The study suggests that the historical OCP pollutants are persistent at high levels in this area and should not be overlooked, while we tackle emerging pollutants. 相似文献
159.
The effectiveness and risk comparison of EDTA with EGTA in enhancing Cd phytoextraction by Mirabilis jalapa L. 总被引:2,自引:0,他引:2
In the previous study, Mirabilis jalapa L. had revealed the basic Cd hyperaccumulator characteristics, but the accumulation ability was not as strong as that of other known Cd hyperaccumulators. In order to improve the accumulation ability of this ornamental plant, the chelants were used to activate the Cd in soil. As a substitute, ethylene glycol bis(2-aminoethyl) tetraacetic acid (EGTA) was selected to testify whether it has better effectiveness and can bring lesser metal leaching risk than EDTA. The data showed that the growth of M. jalapa was inhibited, while the Cd concentration of the plant was significantly increased under the treatments containing EDTA or EGTA. The Cd translocation ability under the EGTA treatments was higher than that under the EDTA treatments. The available Cd resulted from the application of chelant EGTA to the contaminated soils can be limited to the top 5 cm, while the application of chelant EDTA to the contaminated soils can be limited to the top 10 cm. In a word, EGTA showed better effectiveness than EDTA in enhancing Cd phytoextraction of M. jalapa. As an ornamental plant, M. jalapa has the potential to be used for phytoextraction of Cd-contaminated soils and it can beautify the environment at the same time. 相似文献
160.
Bioaccumulation of zinc,lead, copper,and cadmium from contaminated sediments by native plant species and Acrida cinerea in South China 总被引:1,自引:0,他引:1
Chang Zhang Na Song Guang-Ming Zeng Min Jiang Jia-Chao Zhang Xin-Jiang Hu An-Wei Chen Jia-Mei Zhen 《Environmental monitoring and assessment》2014,186(3):1735-1745
This research was conducted to search and identify spontaneously growing heavy metal-tolerant plant species that are potentially useful for phytoremediation in contaminated sediment. Five sites were selected for collection of plants growing on polluted shore (river bank) sediment of the Xiang River, China. The concentrations of Zn, Pb, Cu and Cd in plants, sediments, and grasshoppers were determined using flame atomic absorption spectrophotometer (AAS700, Perkin-Elmer, USA). Considering translocation factor and bioaccumulation factor, Rumex crispus (Polygonaceae), Rumex dentatus (Polygonaceae), and Lagopsis supina (Labiatae) could be potentially useful for phytostabilization of metals. R. crispus can be considered potentially useful for phytoextraction of Cd. In light of the biomagnification factors, grasshoppers are deconcentrators for Pb and Cd, microconcentrators for Zn and macroconcentrators for Cu to the plants, respectively. To the best of our knowledge, the present study is the first report on Zn, Pb, Cu and Cd accumulation in R. crispus and L. supina, providing a pioneer contribution to the very small volume of data available on the potential use of native plant species from contaminated sediments in phytostabilization and phytoremediation technologies. 相似文献