水源地生态补偿标准估算——以贵阳鱼洞峡水库为例

鱼洞河是乌江水系的一个小支流,为下游贵阳市提供饮用水水源。在鱼洞河上下游之间建立生态补偿机制,理论上需要知道上游治理污染和维护生态环境的费用,以及下游对上游提供的生态环境服务的支付意愿。只有下游的支付意愿大于上游的费用,上下游之间的生态补偿机制才有理论可能性。在对上游龙里县汇水区进行实地调研后,重点评估了当地安装沼气系统、坡耕地(≥25°)退耕还林、其他地区的土壤侵蚀防治以及点源污染治理费用,得出上游治理投资费用为199万元,年度费用每年89.2万元-168万元。采用意愿调查法(CVM)对贵阳市自来水用户对上游环境服务的支付意愿进行了评估。采用简单随机抽样方法在贵阳3个区内选取了900户作为样本,结果表明,有62.7%的人愿意为生态补偿付费。采用PROBIT模型,可以计算出为避免鱼洞河水质恶化的支付意愿均值为0.37元/m3,贵阳市自来水用户总的支付意愿每年达847万元。结果表明在鱼洞河水源地进行上下游生态补偿理论上是可能的,补偿标准介于上游费用与下游支付意愿之间。     

西北地区水资源—生态可持续发展的若干问题探讨

基于对西北地区大开发的关键性难题与一些违背自然规律的不良倾向的讨论 ,认为大开发的实施需要在系统科学思维的基础上综合考虑资源—环境—经济的协调发展。近年来 ,许多科学家从各种角度揭示了我国西北乃至北半球中纬度地区持续干旱的发展规律 ,对干旱化趋势与水盐失衡的分析表明 ,西北地区气候干旱化将长期存在 ,生态将继续退化 ,这种趋势是人力不可抗拒的。人为活动尤其是水资源的开发利用 ,对土壤生态的影响是非常明显的 ,应该在严格控制水资源利用总量的前提下 ,调整用水格局 ,发展节水经济 ,科学确定社会经济用水和生态用水的比例 ,保证必须的生态用水 ,大力发展生态植被。指出在分析西北生态环境问题时过于强调人为活动而忽视自然因素作用的倾向 ,讨论了水库兴修、灌溉、土地利用与改良、深层水利用、水环境脆弱性等水资源—生态建设与可持续发展中的若干关键性问题     

经济发达县域耕地土壤重金属污染评价及其影响因素分析——以江苏省昆山市为例

通过对昆山市14个区镇91个土壤样品中As、Cd、Cr、Cu、Pb、Ni、Hg、Zn 8种重金属测定分析,对该市耕地土壤重金属污染进行评价并进行重金属污染的影响因素分析.结果表明,昆山市耕地土壤存在不同程度的轻微污染,重金属Cd、Cr、Cu、Pb、Hg、Zn均超过国家土壤背景值,旱地、水田中均以Hg污染范围较广、变异系数较大.综合污染指数表现为水田(1.15)＞旱地(1.00).区镇耕地重金属污染评价表明千灯、陆扬、石浦、锦溪、石牌处于警戒值之内,蓬朗、周庄、张浦、正仪、周市、巴城、淀山湖、花桥、陆家轻度污染;昆山市耕地土壤中重金属元素均未超过土壤环境基本容量,能够保证作物品质和农业持续发展.同时,研究表明区域重金属轻微污染具有复合污染的特性,Cd、Pb相关性最高(P=0.621 0), Pb与Hg、Cu、Zn、Cu与Cr也有相关性(0.438 7、0.426 0、0.350 9、0.394 0),区域重金属的轻微污染受人为因素影响显著,研究指出应加强对区域优先控制污染物Hg、次优先控制污染物Pb、Cd、Zn、Cu、Cr的控制与治理.     

基于ARCGIS的长株潭城市群核心区环境容量评价

区域环境容量评价与分析是区域合理开发和布局的重要依据。在ARCGIS技术的支持下,首先对长株潭城市群核心区大气、水和土壤环境容量分别进行评价与分析,形成等级图,然后,进行各因素空间叠加,经综合分析与评价,将核心区划分为5个区域：优良区、合理区、饱和区、超饱和区、过度饱和区,并且还提出了相应的建议与对策。其主旨是为促进该区域空间科学开发与布局、生态环境的合理保护,对规范长株潭城市群“两型社会”建设理性发展具有非常重要的意义,并提供参考依据     

Effect of alginate on the aggregation kinetics of copper oxide nanoparticles (CuO NPs): bridging interaction and hetero-aggregation induced by Ca<Superscript>2+</Superscript>

The stability of CuO nanoparticles (NPs) is expected to play a key role in the environmental risk assessment of nanotoxicity in aquatic systems. In this study, the effect of alginate (model polysaccharides) on the stability of CuO NPs in various environmentally relevant ionic strength conditions was investigated by using time-resolved dynamic light scattering. Significant aggregation of CuO NPs was observed in the presence of both monovalent and divalent cations. The critical coagulation concentrations (CCC) were 54.5 and 2.9 mM for NaNO₃ and Ca(NO₃)₂, respectively. The presence of alginate slowed nano-CuO aggregation rates over the entire NaNO₃ concentration range due to the combined electrostatic and steric effect. High concentrations of Ca²⁺ (>6 mM) resulted in stronger adsorption of alginate onto CuO NPs; however, enhanced aggregation of CuO NPs occurred simultaneously under the same conditions. Spectroscopic analysis revealed that the bridging interaction of alginate with Ca²⁺ might be an important mechanism for the enhanced aggregation. Furthermore, significant coagulation of the alginate molecules was observed in solutions of high Ca²⁺ concentrations, indicating a hetero-aggregation mechanism between the alginate-covered CuO NPs and the unabsorbed alginate. These results suggested a different aggregation mechanism of NPs might co-exist in aqueous systems enriched with natural organic matter, which should be taken into consideration in future studies.

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Graphical abstract Hetero-aggregation mechanism of CuO nanoparticles and alginate under high concentration of Ca²⁺

     

Rebound effect and its decomposition – an analysis based on energy types in China

Rebound effect derived from energy efficiency improvement has been widely invested. However, most of studies focus on the rebound effect of the energy composite level and neither distinguish nor compare different energy types. We compare the differences in energy saving and energy rebound between primary and secondary energy sources, and further decompose the rebound effect into production rebound part and final demand component. To do so, we add a module for rebound into a comparative state China-CGE model. We design and test two simulation scenarios using the model. In Scenario 1, all production sectors’ energy efficiency of using primary energy increases by 5%. In Scenario 2, all production sectors’ energy efficiency of using secondary energy increases by 5%. The results show that Scenario 2 leads to more GDP growth and more energy saving. Our scenarios show rebound effects range between 9.6% and 27.9%, and in general are higher when energy efficiency of using primary energy sources is improved. Our decomposition analysis shows that improving energy efficiency in production sectors would stimulates energy use of final demand. Indeed, the consumption side has significant contribution to rebound in secondary energy use, especially in crude oil and gas. This study reveals that improving efficiency of using secondary energy is better than improving that of primary energy, both in terms of economic impact and energy rebound. And complementary policies that prevent energy services prices from falling too much can be adopted to reduce rebound. Controlling residential energy use could also be effective in reducing rebound, this has particular implication to economies in which residential energy consumption are far from saturation.     

丝素/SiO_2杂化膜固定化多酚氧化酶处理模拟含酚废水

粗马铃薯多酚氧化酶固定于丝素/SiO2杂化膜上,从而得到丝素/SiO2杂化膜固定化多酚氧化酶.并用于处理模拟含酚废水.丝素/SiO2杂化膜在水中的溶失率小于丝素膜在水中的溶失率.所得丝素/SiO2杂化膜固定化多酚氧化酶的最适宜pH为7.4.相对于游离多酚氧化酶.该酶具有较好的热稳定性、贮存稳定性及重复使用性.研究表明,丝素/SiO2杂化膜固定化多酚氧化酶有实际处理含酚废水的可能.     

无银催化-分光光度法测定COD的研究

以XS-LP为催化剂,探讨了改进的无银催化HACH法测定污水中COD的系列条件实验。结果表明:在药剂A,B的投配比为1∶2,投加总量为12 g/L的条件下,其准确度、精密度与国标法有较好的可比性,分别小于10%和3%;对实际废水的测量结果与国标回流法的相关系数分别高达0.9951和0.9874,可满足一般环境检测技术规范要求。     

水泥厂煤粉制备系统袋除尘器的选型及应用

本文介绍了煤粉制备系统含尘废气的特性及治理技术的发展与应用,并从袋除尘器类型的确定、处理风量的确定、过滤风速的选取、过滤面积的计算和除尘器规格的选取等方面介绍了煤磨袋除尘器的选型,以及FGM（M）型气箱脉冲防爆袋除尘器、MMC型脉冲喷吹防爆袋除尘器和LPMC型低阻高效防爆袋除尘器在煤粉制备系统除尘中的应用推广情况。     

衡水市空气主要污染物体积质量的时间分布特征

利用衡水市环境监测站2005—2007年度大气例行检测的数据,对衡水市大气中主要污染物SO^2、NO^2、PM10体积质量值的逐日数据进行统计分析,得出了衡水市空气污染的现状和时间变化规律：（1）污染物体积质量值的月变化曲线呈槽型分布,非取暖期的空气状况明显好于取暖期,取暖期SO^2平均体积质量是非取暖期的2．45倍;（2）污染物体积质量值的日变化曲线基本为两高两低型,其中取暖期污染指数早晨出现极高值的时间比非取暖期明显偏晚;（3）污染物体积质量值的年变化表明了SO^2的体积质量在降低,而NO^2的体积质量却有了小幅增长。