全文获取类型
收费全文 | 1219篇 |
免费 | 72篇 |
国内免费 | 516篇 |
专业分类
安全科学 | 86篇 |
废物处理 | 57篇 |
环保管理 | 125篇 |
综合类 | 709篇 |
基础理论 | 241篇 |
污染及防治 | 407篇 |
评价与监测 | 71篇 |
社会与环境 | 51篇 |
灾害及防治 | 60篇 |
出版年
2024年 | 3篇 |
2023年 | 27篇 |
2022年 | 81篇 |
2021年 | 60篇 |
2020年 | 58篇 |
2019年 | 48篇 |
2018年 | 55篇 |
2017年 | 73篇 |
2016年 | 59篇 |
2015年 | 61篇 |
2014年 | 94篇 |
2013年 | 120篇 |
2012年 | 102篇 |
2011年 | 131篇 |
2010年 | 85篇 |
2009年 | 84篇 |
2008年 | 81篇 |
2007年 | 70篇 |
2006年 | 80篇 |
2005年 | 56篇 |
2004年 | 38篇 |
2003年 | 27篇 |
2002年 | 48篇 |
2001年 | 41篇 |
2000年 | 43篇 |
1999年 | 35篇 |
1998年 | 18篇 |
1997年 | 25篇 |
1996年 | 15篇 |
1995年 | 18篇 |
1994年 | 11篇 |
1993年 | 20篇 |
1992年 | 11篇 |
1991年 | 10篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 1篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1973年 | 1篇 |
排序方式: 共有1807条查询结果,搜索用时 500 毫秒
681.
682.
683.
Decolorization and biodegradation of dye wastewaters by a facultative-aerobic process 总被引:1,自引:0,他引:1
BACKGROUND: Dye wastewater is one of the main pollution sources of water bodies in China. Conventional biological processes are relatively ineffective for color removal, the development of alternative treatment methods will become important. Our subjective was that of introducing a new biotreatment technology which combined a facultative biofilm reactor (FBR) with an aerobic reactor (AR) to treat a dye wastewater. The efficiencies of color and chemical oxygen demand (COD) removal and the mechanism of dye degradation were investigated. METHODS: The anthraquinone acid dye (acid blue BRLL) concentration, organic loading rate (OLR) and hydraulic retention time (HRT) were varied in the experiments to evaluate the treatment efficiency and process stability. The biodegradation products were detected by infrared (IR) and high performance liquid chromatography and mass spectrometry (HPLC-MS). RESULTS AND DISCUSSION: The results demonstrated that the facultative biofilm process was more effective for decolorization than the anaerobic stage of an anaerobic-aerobic process. Most color removal occurred in the facultative reaction (maximum to 88.5%) and the BOD (biochemical oxygen demand): COD of the FBR effluent increased by 82.2%, thus improving the biodegradability of dyes for further aerobic treatment. The dye concentration, OLR and HRT will be the factors affecting decolorization. Color removal efficiency falls as the influent dye concentration increases, but rises with increased HRT. The infrared and HPLC-MS analyses of the effluents of FBR and AR reveal that the dye parent compound was degraded in each reactor during the process. CONCLUSION: The Facultative-aerobic (F-A) system can effectively remove both color and COD from the dye wastewater. The FBR played an essential role in the process. The average overall color and COD in the system were removed by more than 93.9% and 97.1%, respectively, at an OLR of 1.1 kg COD m(-3) d(-1) and at the HRT of 18-20 hours in the FBR and 4-5 hours in the AR. The color removal mechanism in each reactor was not only a sort of biosorption on the floc materials, but even more an effect of biodegradation, especially in the facultative process. Recommendation and Outlook. In applying the F-A system to treat a dye wastewater, the control of facultative processes and the set up of appropriate operation conditions appear to be critical factors. Also, it is suggested a moderate COD loading rate and about a 24-hour HRT will favor the F-A system. 相似文献
684.
Yangyang Gao Sha Wang Fengjun Yin Pin Hu Xingzu Wang Yuan Liu Hong Liu 《环境科学学报(英文版)》2021,33(3):227-235
The relatively low sensitivity is an important reason for restricting the microbial fuel cell (MFC) sensors’ application in low concentration biodegradable organic matter (BOM) detection. The startup parameters, including substrate concentration, anode area and external resistance, were regulated to enhance the sensitivity of MFC sensors. The results demonstrated that both the substrate concentration and anode area were positively correlated with the sensitivity of MFC sensors, and an external resistance of 210 Ω was found to be optimal in terms of sensitivity of MFC sensors. Optimized MFC sensors had lower detection limit (1 mg/L) and higher sensitivity (Slope value of the linear regression curve was 1.02), which effectively overcome the limitation of low concentration BOM detection. The essential reason is that optimized MFC sensors had higher coulombic efficiency, which was beneficial to improve the sensitivity of MFC sensors. The main impact of the substrate concentration and anode area was to regulate the proportion between electrogens and nonelectrogens, biomass and living cells of the anode biofilm. The external resistance mainly affected the morphology structure and the proportion of living cells of the anode. This study demonstrated an effective way to improve the sensitivity of MFC sensors for low concentration BOM detection. 相似文献
685.
686.
687.
Luhua Jiang Shaobo Liu Yunguo Liu Guangming Zeng Yiming Guo Yicheng Yin Xiaoxi Cai Lu Zhou Xiaofei Tan Xixian Huang 《Environmental science and pollution research international》2017,24(30):23528-23537
This paper explored biochar modification to enhance biochar’s ability to adsorb hexavalent chromium from aqueous solution. The ramie stem biomass was pyrolyzed and then treated by β-cyclodextrin/poly(L-glutamic acid) which contained plentiful functional groups. The pristine and modified biochar were characterized by FTIR, X-ray photoelectron spectroscopy, specific surface area, and zeta potential measurement. Results indicated that the β-cyclodextrin/poly(L-glutamic acid) was successfully bound to the biochar surface. Batch experiments were conducted to investigate the kinetics, isotherm, thermodynamics, and adsorption/desorption of Cr(VI). Adsorption capacities of CGA-biochar were significantly higher than that of the untreated biochar, and its maximum adsorption capacity could reach up to 197.21 mg/g at pH 2.0. Results also illustrated that sorption performance depended on initial solution pH; in addition, acidic condition was beneficial to the Cr(VI) uptake. Furthermore, the Cr(VI) uptake was significantly affected by the ion strength and cation species. This study demonstrated that CGA-biochar could be a potential adsorbent for Cr(VI) pollution control. 相似文献
688.
Rundong Li Jing Yin Weiyun Wang Yanlong Li Ziheng Zhang 《Waste management (New York, N.Y.)》2014,34(7):1211-1216
Sewage sludge (SS), a by-product of wastewater treatment, consists of highly concentrated organic and inorganic pollutants, including phosphorus (P). In this study, P with different chemical fractions in SS under different drying and roasting temperatures was investigated with the use of appropriate standards, measurements, and testing protocol. The drying and roasting treatment of SS was conducted in a laboratory-scale furnace. Two types of SS samples under different treatment temperatures were analyzed by 31P NMR spectroscopy. These samples were dried by a vacuum freeze dryer at ?50 °C and a thermoelectric thermostat drying box at 105 °C. Results show that the inorganic P (IP) content increased as the organic P content decreased, and the bio-availability of P increased because IP is a form of phosphorous that can be directly absorbed by plants. 31P NMR analysis results indicate the change in P fractions at different temperatures. Non-apatite P was the dominant form of P under low-temperature drying and roasting, whereas apatite P was the major one under high-temperature drying and roasting. Results indicate that temperature affects the transformation of P. 相似文献
689.
690.