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821.
Dingyong Wang Yongguang Yin Shufang Zeng Xun Wang Wei Yuan Ji Luo Yong Cai Xinbin Feng Shuxiao Wang Huan Zhong Ping Li 《环境科学学报(英文版)》2022,119(9):1-10
Understanding atmospheric mercury (Hg) accumulation in remote montane forests is critical to assess the Hg ecological risk to wildlife and human health. To quantify impacts of vegetation, climatic and topographic factors on Hg accumulation in montane forests, we assessed the Hg distribution and stoichiometric relations among Hg, carbon (C), and nitrogen (N) in four forest types along the elevation of Mt. Gongga. Our results show that Hg concentration in plant tissues follows the descending order of litter > leaf, bark > root > branch > bole wood, indicating the importance of atmospheric Hg uptake by foliage for Hg accumulation in plants. The foliar Hg/C (from 237.0 ± 171.4 to 56.8 ± 27.7 µg/kg) and Hg/N (from 7.5 ± 3.9 to 2.5 ± 1.2 mg/kg) both decrease along the elevation. These elevation gradients are caused by the heterogeneity of vegetation uptake of atmospheric Hg and the variation of atmospheric Hg° concentrations at different altitudes. Organic soil Hg accumulation is controlled by forest types, topographic and climatic factors, with the highest concentration in the mixed forest (244.9 ± 55.7 µg/kg) and the lowest value in the alpine forest (151.9 ± 44.5 µg/kg). Further analysis suggests that soil Hg is positively correlated to C (r2 = 0.66) and N (r2 = 0.57), and Hg/C and Hg/N both increase with the soil depth. These stoichiometric relations highlight the combined effects from environmental and climatic factors which mediating legacy Hg accumulation and selective Hg absorption during processes of organic soil mineralization. 相似文献
822.
Jinsheng Chen Ping Li Yongguang Yin Kaiyun Liu Qingru Wu Shuxiao Wang Xing Chang Yi Tang Long Wang Tonghao Liu Lei Zhang Yu Zhao Yong Cai Xinbin Feng Huan Zhong 《环境科学学报(英文版)》2022,119(9):106-118
The gaseous or particulate forms of divalent mercury (HgII) significantly impact the spatial distribution of atmospheric mercury concentration and deposition flux (FLX). In the new nested-grid GEOS-Chem model, we try to modify the HgII gas-particle partitioning relationship with synchronous and hourly observations at four sites in China. Observations of gaseous oxidized Hg (GOM), particulate-bound Hg (PBM), and PM2.5 were used to derive an empirical gas-particle partitioning coefficient as a function of temperature (T) and organic aerosol (OA) concentrations under different relative humidity (RH). Results showed that with increasing RH, the dominant process of HgII gas-particle partitioning changed from physical adsorption to chemical desorption. And the dominant factor of HgII gas-particle partitioning changed from T to OA concentrations. We thus improved the simulated OA concentration field by introducing intermediate-volatility and semi-volatile organic compounds (I/SVOCs) emission inventory into the model framework and refining the volatile distributions of I/SVOCs according to new filed tests in the recent literatures. Finally, normalized mean biases (NMBs) of monthly gaseous element mercury (GEM), GOM, PBM, WFLX were reduced from −33%–29%, 95%–300%, 64%–261%, 117%–122% to −13%–0%, −20%–80%, −31%–50%, −17%–23%. The improved model explains 69%–98% of the observed atmospheric Hg decrease during 2013–2020 and can serve as a useful tool to evaluate the effectiveness of the Minamata Convention on Mercury. 相似文献
823.
Deliang Yin Yongguang Yin Shu Ran Tianrong He Xian Zhou Yong Cai Xinbin Feng Shuxiao Wang Huan Zhong Ping Li 《环境科学学报(英文版)》2022,119(9):93-105
Humus is often used as an organic modifier to reduce the bioaccumulation of heavy metals in plants, but the effects of different humus components from different sources on the fate of mercury (Hg) in paddy fields are still unclear. Here, fulvic acid (FA) and humic acid (HA) extracted from composted straw (CS), composted cow dung (CCD), peat soil (PM) and lignite coal (LC) were used to understand their effects on the methylation and bioaccumulation of Hg in paddy soil by pot experiments. Amendments of both FA and HA largely increased the abundance of Hg-methylating microbes and low-molecular-weight organic matters (e.g, cysteine) in paddy soil. They were also found to change the aromaticity, molecular size and Chromophoric DOM concentration of DOM, and resulted in heterogeneous effects on migration and transformation of Hg. All the FA-amended treatments increased the mobility and methylation of Hg in soil and its absorption in roots. Nevertheless, FA from different sources have heterogeneous effects on transport of Hg between rice tissues. FA-CCD and FA-PM promoted the translocation of MeHg from roots to rice grains by 32.95% and 41.12%, while FA-CS and FA-LC significantly inhibited the translocation of inorganic Hg (IHg) by 52.65% and 66.06% and of MeHg by 46.65% and 36.23%, respectively. In contrast, all HA-amended treatments reduced the mobility of soil Hg, but promoted Hg methylation in soil. Among which, HA-CCD and HA-PM promoted the translocation of MeHg in rice tissues by 88.95% and 64.10%, while its accumulation in rice grains by 28.43% and 28.69%, respectively. In general, the application of some FA and HA as organic modifiers to reduce Hg bioaccumulation in rice is not feasible. 相似文献
824.
Nitrate (NO3−) has been the dominant ion of secondary inorganic aerosols (SIAs) in PM2.5 in North China. Tracking the formation mechanisms and sources of particulate nitrate are vital to mitigate air pollution. In this study, PM2.5 samples in winter (January 2020) and in summer (June 2020) were collected in Jiaozuo, China, and water-soluble ions and (δ15N, δ18O)-NO3− were analyzed. The results showed that the increase of NO3− concentrations was the most remarkable with increasing PM2.5 pollution level. δ18O-NO3− values for winter samples (82.7‰ to 103.9‰) were close to calculated δ18O-HNO3 (103‰ ± 0.8‰) values by N2O5 pathway, while δ18O-NO3− values (67.8‰ to 85.7‰) for summer samples were close to calculated δ18O-HNO3 values (61‰ ± 0.8‰) by OH oxidation pathway, suggesting that PM2.5 nitrate is largely from N2O5 pathway in winter, while is largely from OH pathway in summer. Averaged fractional contributions of PN2O5+H2O were 70% and 39% in winter and summer sampling periods, respectively, those of POH were 30% and 61%, respectively. Higher δ15N-NO3− values for winter samples (3.0‰ to 14.4‰) than those for summer samples (-3.7‰ to 8.6‰) might be due to more contributions from coal combustion in winter. Coal combustion (31% ± 9%, 25% ± 9% in winter and summer, respectively) and biomass burning (30% ± 12%, 36% ± 12% in winter and summer, respectively) were the main sources using Bayesian mixing model. These results provided clear evidence of particulate nitrate formation and sources under different PM2.5 levels, and aided in reducing atmospheric nitrate in urban environments. 相似文献
825.
Hussain Sajjad Ouyang Ping Zhu Yingkun Khalique Abdul He Changliang Liang Xiaoxia Shu Gang Yin Lizi 《Environmental science and pollution research international》2021,28(26):34154-34166
Environmental Science and Pollution Research - Unsuccessful vaccination against Salmonella due to a large number of serovars, and antibiotic resistance, necessitates the development of novel... 相似文献
826.
Lv Ya-kun Mei Lin Zhang Liu-xue Yang De-hong Yin Zi-yu 《Environmental science and pollution research international》2021,28(36):49880-49888
Environmental Science and Pollution Research - A new strategy for the wastewater treatment was proposed by combining polyvinylpyrrolidone-functionalized silver nanoparticles with reduced graphene... 相似文献
827.
Yin Qian Wang Jinfeng Su Jianting Wei Zaihua 《Environmental science and pollution research international》2019,26(9):8895-8901
Environmental Science and Pollution Research - Few detailed, individual-focused studies have researched the added effect of temperature on cardiovascular disease (CVD), particularly in China.... 相似文献
828.
Qian Feiyue Yin Honggui Liu Feng Sheng Jiayi Gao Shiqian Shen Yaoliang 《Environmental science and pollution research international》2021,28(21):26828-26839
Environmental Science and Pollution Research - Metal-free carbonaceous composite membranes have been proven to effectively drive novel in situ catalytic oxidation for the degradation of organic... 相似文献
829.
采用文献研读、专家访谈、逻辑分析等方法,基于邻域系统理论的视角构建了由学生、教师、政策、管理等五大邻元素组成的高校"阳光体育"运动开展的邻域系统,并对其优化管理的思路、过程、原则进行了阐述,旨在为我国高校"阳光体育"运动顺利开展以及为管理部门的决策提供有力的理论参考。 相似文献
830.
Cheng Jiali Tang Zhenwu Ma Yan Yin Hongmin Meng Tong Sun Jiazheng 《Environmental science and pollution research international》2021,28(13):16054-16064
Environmental Science and Pollution Research - Methyl siloxanes are becoming increasingly prevalent in the environment because of their extensive use in various consumer products. Little is known... 相似文献