The Use of Nahcolite Ore and Bag Filters For Sulfur Dioxide Emission Control

This paper describes some technical and economic aspects of the nahcolite ore injection process for the simultaneous removal of fly ash and sulfur oxides from stack gases. The process is capable of removing greater than 99% of the particulate matter and greater than 70% of the sulfur oxides present in such gases. In the process, nahcolite ore, a naturally occurring material containing 70 to 90% sodium bicarbonate, is ground to 90% passing through —200 mesh screens. Approximately 20% of the ground ore is used to precoat the filter bags in a baghouse filter while the remainder of the material is fed into the flue gas Just ahead of the baghouse. The flue gas is drawn through the baghouse by induced draft fans and sent up the stack. Most of the SO₂ and practically all of the fly ash in the flue gas can be removed as the gas passes through the filter bags. The spent nahcolite ore and fly ash are collected and conveyed to waste disposal as landfill, or alternatively processed for insolubilization by coprecipitation prior to landfilling. The technical feasibility of the process has been demonstrated in both bench scale and pilot scale engineering studies. Economic analyses performed for the cases of plants located in the midwest and southwest indicate lower capital costs for the nahcolite injection process when compared to wet scrubbing. On an annual cost basis, the nahcolite ore Injection process is comparable in cost to wet scrubbing for the case of the southwestern power plant, and somewhat more expensive for the case of the midwestern plant.     

Pyrolysis technologies for municipal solid waste: A review

Pyrolysis has been examined as an attractive alternative to incineration for municipal solid waste (MSW) disposal that allows energy and resource recovery; however, it has seldom been applied independently with the output of pyrolysis products as end products. This review addresses the state-of-the-art of MSW pyrolysis in regards to its technologies and reactors, products and environmental impacts. In this review, first, the influence of important operating parameters such as final temperature, heating rate (HR) and residence time in the reaction zone on the pyrolysis behaviours and products is reviewed; then the pyrolysis technologies and reactors adopted in literatures and scale-up plants are evaluated. Third, the yields and main properties of the pyrolytic products from individual MSW components, refuse-derived fuel (RDF) made from MSW, and MSW are summarised. In the fourth section, in addition to emissions from pyrolysis processes, such as HCl, SO₂ and NH₃, contaminants in the products, including PCDD/F and heavy metals, are also reviewed, and available measures for improving the environmental impacts of pyrolysis are surveyed. It can be concluded that the single pyrolysis process is an effective waste-to-energy convertor but is not a guaranteed clean solution for MSW disposal. Based on this information, the prospects of applying pyrolysis technologies to dealing with MSW are evaluated and suggested.     

采用支持向量机算法优化电化学处理油田污水的工艺参数

采用支持向量机(SVM)算法,将Box-Behnken设计法与支持向量回归算法(SVR)实验参数优化软件相结合,优化电化学去除油田污水COD的工艺参数。通过量子粒子群算法对SVM算法参数进行优化,从建立的回归模型中找到工艺参数的全局最佳点:电解时间60 min,电解电流3 A,三维电极填充料中石英砂质量695 g。模型得到的COD理论最优去除率为92.48%,验证实验得到的COD去除率为91.43%。     

5—(4—磺酸基苯偶氮)8—(2,4—二硝基苯氨基)喹啉测定食品中铜的研究应用

在弱碱性介质中 ,5— (4—磺酸基苯偶氮 ) 8— (2 ,4—二硝基苯氨基 )喹啉 (SPDNPAQ)与铜反应生成 2∶ 1紫红色络合物 ,体系 λmax=56 0 nm,ε=1.2 3× 10 5L· mol-1· cm-1。铜含量在 0～ 0 .4 mg/ L内符合比耳定律 ,方法用于一些生物样品和水样中铜的测定。     

噻唑类缓蚀剂QADT的合成及缓蚀性能研究＊

以正丙醇、氯气和硫脲合成了2-氨基-5-甲基噻唑,将上述产物作为碱组分,与苯甲醛和苯乙酮反应得到曼尼希碱,最后采用溴代十二烷作为季铵化试剂,制得目标产物溴代2-氨基(1,4-二苯基-3-氧代丁基)-5-甲基噻唑铵(QADT)。静态失重法表明,QADT缓蚀效果显著。当温度为50℃,QADT的用量在200 mg/L时,缓蚀率达到95%以上。     

改造现有工艺回收地面计量天然气

为解决牙哈作业区A区块3口井在见水后含水上升较快、单井产液量增加、现有装置处理能力不足,导致A区块所有生产井不能全部进站的问题,同时为提高最终采收率,需要延长见水时间,见水后控制含水的上升趋势。这就要求掌握含水井的生产动态,而现有装置无法对单井的含水进行计量,塔里木油田公司牙哈作业区A区块建造集中试采装置,文章介绍了改造前后的工艺流程及改造效果。     

Effects of the "Conversion of Cropland to Forest and Grassland Program" on the water budget of the Jinghe River catchment in China

In 1999 China adopted the "Conversion of Cropland to Forest and Grassland Program" (CCFGP), a nationwide ecological recovery program, to minimize wide-scale soil erosion and vegetation degradation in China, as well as to improve water budgeting results. In the 10 yr since implementation, the CCFGP has resulted in the recovery and reforestation of >100,000 km of cropland and bare land, though the quantitative effect of this program on catchment water budget is not entirely clear. Therefore, we used the Soil and Water Assessment Tool to evaluate and quantify the effects of the CCFGP on the water budget of the Jinghe River catchment, a tributary of the Yellow River covering the central region of the Loess Plateau. Our results indicated that precipitation had dropped by 12.0% from the 1970s (611.6 mm) to the 2000s (538 mm) and that there was a corresponding 25.2% decrease in humidity index from 0.48 to 0.36. Before the CCFGP's implementation, forest and grassland had been decreasing, while bare land, cropland, and shrub land had been increasing. After the implementation of the CCFGP, the opposite trend was observed. Moreover, streamflow increased by about 15 and 20% for the upstream and middle stream subbasins, respectively, while soil water content also showed an obvious increase. Over the same period, evapotranspiration decreased by 5.2 and 13.5 mm and runoff decreased by 37.5 and 38.6% in the two subbasins. The same trends were obtained in the downstream subbasin, where changes were even greater. As a result of the reduced runoff and evapotranspiration, utilization of water resources was more efficient and ecological environment was improved under the CCFGP policy. Our results indicate the CCFGP resulted in a favorable ecological impact and should therefore be maintained.     

淮南矿区土地利用变化对区域景观格局的影响

以淮南矿区5期遥感影像图作为基本信息源,利用土地利用转移矩阵和景观格局指数分析了淮南矿区的土地利用变化及其对区域景观格局的影响。土地利用变化相关结果表明:1980 — 2015年淮南矿区及区域土地利用变化主要表现为耕地的减少,建设用地、水域的增加。矿区耕地面积减少117.6 km~2,其中46.7%的面积转换成建设用地,51.2%转换成塌陷水域,其所在区域(流域)耕地减少了274.4 km~2,有63.1%转换成建设用地,33.1%转换成水域。将矿区增加的塌陷水域面积还原作为无采矿活动的对照,分析采矿活动对区域景观格局的影响,结果表明:采矿活动使得区域景观多样性指数增加了0.07,矿区土地利用变化使得区域景观多样性增加、优势度减小,区域景观格局更加趋于多样、均衡。     

Separation of selected PAHs by using high performance capillary electrophoresis with modifiers

The effect of varying SDS concentration in a micellar electrokinetic capillary chromatographic system (MECC) is investigated. In addition, the introduction of -cyclodextrin as modifier to the electrophoretic medium, containing SDS and a phosphate-borate buffer, is shown to give satisfactory separation of the seven selected PAHs. The separation efficiency is increased with the addition of -cyclodextrin.     

特警战训服面料开发技术研究

本文介绍了以芳纶纤维为主要材料的我国新一代特警战训服面料的技术研发及达到的主要性能指标。通过试验研究,开发了具有高强防撕裂、永久阻燃、耐高温、防静电、防油拒水、防酸碱等具有集成防护功能的特警战训服系列面料。