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31.
Andreas Züttel 《Mitigation and Adaptation Strategies for Global Change》2007,12(3):343-365
Hydrogen storage and transportation or distribution is closely linked together. Hydrogen can be distributed continuously in
pipelines or batch wise by ships, trucks, railway or airplanes. All batch transportation requires a storage system but also
pipelines can be used as pressure storage system. Hydrogen exhibits the highest heating value per weight of all chemical fuels.
Furthermore, hydrogen is regenerative and environment friendly. There are two reasons why hydrogen is not the major fuel of
toady’s energy consumption: First of all, hydrogen is just an energy carrier. And, although it is the most abundant element
in the universe, it has to be produced, since on earth it only occurs in the form of water. This implies that we have to pay
for this energy, which results in a difficult economic task, because since the industrialization we are used to consuming
energy for free. The second difficulty with hydrogen as an energy carrier is the low critical temperature of 33 K, i.e. hydrogen
is a gas at room temperature. For mobile and in many cases also for stationary applications the volumetric and gravimetric
density of hydrogen in a storage system is crucial. Hydrogen can be stored by six different methods and phenomena: high pressure
gas cylinders (up to 800 bar), liquid hydrogen in cryogenic tanks (at 21 K), adsorbed hydrogen on materials with a large specific
surface area (at T < 100 K), absorbed on interstitial sites in a host metal (at ambient pressure and temperature), chemically bond in covalent
and ionic compounds (at ambient pressure), oxidation of reactive metals e.g. Li, Na, Mg, Al, Zn with water. These metals easily
react with water to the corresponding hydroxide and liberate the hydrogen from the water. Finally, the metal hydroxides can
be thermally reduced to the metals in a solar furnace. 相似文献
32.
FUENSANTA CARAVACA DINO FIGUEROA ANTONIO ROLDÁn CONCEPCIÓN AZCÓN-AGUILAR 《Environmental management》2003,31(3):0412-0420
The reestablisment of autochthonous plant species is an essential strategy for recovering degraded areas under semiarid conditions.
A field experiment was carried out to assess the short-term effect of two reafforestation methods involving mycorrhizal inoculation
and compost addition on soil quality parameters and Rhamnus lycioides seedling growth. The nutrient content (NPK) and enzymatic activities (dehydrogenase, urease, protease-BAA, acid phosphatase
and β-glucosidase) increased and bulk density decreased in the rhizosphere soil with the organic amendment. Biomass C of rhizosphere
soil increased by at least 240% with respect to the control soil after mycorrhizal inoculation and the combination of compost
addition + mycorrhizal inoculation. Both mycorrhizal inoculation and composted organic residue addition increased R. lycioides seedling growth in the same proportion. In the short term, we conclude that the application of both reafforestation methods
not only enhances the establishment of R. lycioides seedlings, but also improves soil quality. 相似文献
33.
J. Y. Kim M.-C. Shin J.-R. Park K. Nam 《Journal of Material Cycles and Waste Management》2003,5(1):0055-0062
The effect of the soil solids concentration in batch tests on the measured values of the partition coefficient (K
p) of organic pollutants in landfill liner-soil material was investigated. Since this study was based on the results of batch
and column tests conducted independently, there were limitations to the conclusions derived. The organic compounds tested
were benzene, methylene chloride, toluene, trichloroethylene, and p-xylene. The results of this study showed that as soil solids concentrations increased, the measured K
p values of these organic compounds strongly decreased. The observed values of K
p stabilized when the soil solids concentration was above a certain value. Typical K
p values obtained from batch tests conducted under high soil solids concentrations were close to those obtained from column
tests. It was concluded that the K
p values of organic compounds measured under low soil solids concentrations, i.e., less than 100 g/l, may not correctly simulate
the field situation. Consequently, the values of K
p obtained with low soil solids concentrations can result in an overestimation of the retardation factor of the landfill liner
material.
Received: March 14, 2002 / Accepted: August 25, 2002 相似文献
34.
A data analysis of three major Korean cities was conducted to assess roadside inhalable particulate matter 10 μm or smaller
in aerodynamic diameter (PM10), including temporal and meteorological variations, over a recent period of 4 to 6 years. The yearly roadside PM10 concentrations presented a well-defined increasing trend or no trend depending on the roadside monitoring station. Most mean
values exceeded or approximated the Korean standard of 70 μg/m3 per year for PM10. A representative roadside diurnal trend was characterized by a distinct morning maximum. In most cases, the Sunday roadside
concentrations were similar to or somewhat lower than the weekday concentrations, and the PM10 concentrations presented a well-defined seasonal variation, with the maximum concentration in March. The monthly maximum
concentrations observed in March were most likely attributable to Asian dust storms. In two metropolitan cities (Seoul and
Busan), the frequency of days with roadside PM10 concentrations exceeding the standard of 150μg/m3 per 24 h was much lower for the roadside monitoring stations than for the residential monitoring station, whereas in the
third city (Daegu), this result was reversed. Interestingly, the average maximum concentrations observed for the roadside
sites in Seoul and Busan during March were higher than those for the residential sites, suggesting that the roadside concentrations
responded more to the dust storms than the residential areas. The relationship between the pollutant concentrations and five
important meteorological parameters (solar radiation, wind speed, air temperature, relative humidity, and precipitation) showed
that the number and type of meteorological variables included in the equations varied according to the monitoring station
or season. Finally, the current results confirmed that attention should be given to the PM10 exposure of residents living near roadways. 相似文献
35.
Assessment of Soil Erodibility Indices for Conservation Reserve Program Lands in Southwestern Kansas Using Satellite Imagery and GIS Techniques 总被引:2,自引:0,他引:2
The soil erodibility index (EI) of Conservation Reserve Program (CRP) lands, which was the major criterion for CRP enrollment,
was assessed for six counties in southwestern Kansas using USGS seamless digital elevation model data and Geographical Informational
System techniques. The proportion of land areas with EI values of 8 or lower was less than 1% of the entire study area and
most of the land areas (72.5%) were concentrated on EI values between 8 and 24. Although land acreage with EI values of 24
or higher decreased dramatically, the proportion of CRP lands to the other land-use types did not change much from low to
high EI levels. The soil EI and physical soil characteristics of the CRP lands were compared to those of other land-use types.
In general, the mean EI values of the land-use types were strongly correlated with physical soil properties, including organic
matter content, clay content, available water capacity, permeability, and texture. CRP lands were compared in detail with
cropland in terms of their soil characteristics to infer the pivotal cause of the land transformation. Although there was
no significant statistical difference in EI between cropland and CRP soils, soil texture, soil family, and permeability were
statistically different between the two. Statistical analyses of these three variables showed that CRP soils had coarser texture
and higher permeability on average than cropland soils, indicating that CRP lands in the study area are drier than cropland
soils. Therefore, soil moisture characteristics, not necessarily soil erosion potential, might have been the key factor for
CRP enrollment in the study area. 相似文献
36.
37.
Biochar physicochemical parameters as a result of feedstock material and pyrolysis temperature: predictable for the fate of biochar in soil? 总被引:1,自引:0,他引:1
38.
Nguyen Kim Nga Huynh Dang Chinh Phi Thi Thuy Hong Tran Quang Huy 《Journal of Polymers and the Environment》2017,25(2):146-155
This study aimed at finding effective strategies for high-performance removal of reactive blue 19 (RB19) dye from aqueous solution. Chitosan (CS) films had been prepared by using solvent casting with mild drying for this purpose. The CS films were characterized by X-ray diffraction, field-emission scanning electron microscopy, and Fourier transform infrared (FTIR) spectroscopy. The performance of RB19 removal using CS were evaluated by varying contact time, solution pH, initial dye concentration, and adsorbent dosage. Adsorption isotherms, kinetics, and desorption were investigated by batch experiments. Results showed that CS films exhibited the optimal adsorption performance for RB19 removal and high maximum adsorption capacities of RB19, which were 799 and 822.4 mg g?1 at 20 and 40 °C, respectively. Adsorption kinetic data were well described by the pseudo-second-order kinetic model. FTIR analyses further indicated that interactions between RB19 and the CS film occurred during adsorption. The CS films also exhibited satisfactory desorption of RB19 at about 80 % after 30 min of desorption at pH 11. Our study demonstrated that the CS films can be easily prepared and applied for effective removal of RB19 in treatment of wastewater. 相似文献
39.
Christian Mougin Agnès Bouchez Laurence Denaix Isabelle Lamy François Laurent Fabrice Martin-Laurent Michel Mench 《Environmental science and pollution research international》2016,23(4):2974-2976
The fifth meeting of INRA’s national network of ecotoxicologists took place on 25 to 27 November 2014 in Biarritz, France. The main aim of the meeting was to bring together ecotoxicologists from INRA and associated partners, providing them ample opportunity to share and discuss their latest scientific results as well as the national policy of research in ecotoxicology and to precise perspectives for the network. 相似文献
40.