全文获取类型
收费全文 | 1892篇 |
免费 | 44篇 |
国内免费 | 505篇 |
专业分类
安全科学 | 78篇 |
废物处理 | 130篇 |
环保管理 | 153篇 |
综合类 | 608篇 |
基础理论 | 433篇 |
环境理论 | 1篇 |
污染及防治 | 806篇 |
评价与监测 | 120篇 |
社会与环境 | 72篇 |
灾害及防治 | 40篇 |
出版年
2023年 | 22篇 |
2022年 | 74篇 |
2021年 | 42篇 |
2020年 | 40篇 |
2019年 | 41篇 |
2018年 | 96篇 |
2017年 | 48篇 |
2016年 | 86篇 |
2015年 | 100篇 |
2014年 | 120篇 |
2013年 | 149篇 |
2012年 | 107篇 |
2011年 | 146篇 |
2010年 | 115篇 |
2009年 | 121篇 |
2008年 | 146篇 |
2007年 | 123篇 |
2006年 | 106篇 |
2005年 | 64篇 |
2004年 | 101篇 |
2003年 | 89篇 |
2002年 | 79篇 |
2001年 | 119篇 |
2000年 | 62篇 |
1999年 | 42篇 |
1998年 | 42篇 |
1997年 | 29篇 |
1996年 | 39篇 |
1995年 | 25篇 |
1994年 | 13篇 |
1993年 | 7篇 |
1992年 | 9篇 |
1991年 | 9篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1983年 | 3篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1977年 | 1篇 |
1964年 | 1篇 |
1960年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有2441条查询结果,搜索用时 15 毫秒
311.
Domènech X Ayllón JA Peral J 《Environmental science and pollution research international》2001,8(4):285-287
The paper focuses on the production of H2O2 by photocatalysis over ZnO in an aerated aqueous phase. The presence of different reductants that increase the H2O2 production in the aqueous phase is analysed; particular attention is paid to nitrite, which has been shown to be the reductant that produces the most significant increments in the H2O2 production. The photocatalytic anodic decomposition of ZnO in the presence of the different reductants is also investigated. From the results obtained, the relevance of the ZnO photocatalysis in the formation of environmental hydrogen peroxide is estimated. 相似文献
312.
Effects of metabolites of benzo(a)pyrene on unschedule DNA synthesis in BALB/3T3 cell line 总被引:3,自引:0,他引:3
In order to explore the damage from metabolites of benzo(a)pyrene on DNA of mammalian cells, the effects of four metabolites of benzo(a)pyrene (anti-BPDE, syn-BPDE, 3-OH-BP and 9-OH-BP) on synthesis of DNA and unschedule DNA synthesis (UDS) in BALB/3T3 cells were assayed, by methods of single-labeling and double-labeling. The results showed that all of the four agents were able to increase the synthesis of DNA, but only three of them (apart from syn-BPDE) induced UDS in BALB/3T3 cells. The above indicates that the metabolites of benzo(a)pyrene are able to damage DNA in BALB/3T3 cells, and that this effect may be relative to the sterical structure of metabolites of benzo(a)pyrene. 相似文献
313.
我们于1995年3月 ̄4月调查了武汉市高位铁皮水箱的供水质量。结果表明:高层住宅水箱近年虽曾清洗消毒,但高层用户龙头水及水箱水中游离性全氯未达标比例较大,分别为73.3%和66.7%。个别底层住户水样中铁超标。高位水箱水样中细菌总数超标比例为20%。反映了高层住宅二次供水中在水的输送、贮存过程中有二次污染存在。经水样监测指标相关性和灰色关联性分析,认为游离性余氯可作为常规监测高层住宅二次供水质量的 相似文献
314.
Determination of polycyclic musks in sewage sludge from Guangdong, China using GC-EI-MS 总被引:12,自引:0,他引:12
Polycyclic musks [Cashmeran (DPMI), Celestolide (ADBI), Phantolide (AHMI), Traseolide (ATII), Tonalide (AHTN) and Galaxolide (HHCB)] were Soxhlet extracted, separated and analyzed in sewage sludge from six different wastewater treatment plants from Guangdong, China, using GC and GC-EI-MS. DPMI, ADBI, HHCB, AHTN were found in all samples, and ATII was not found in any sample. AHMI was detected in five out of six samples. HHCB and AHTN were the two major polycyclic musks found in highest concentrations in sludge. The sludge from municipal wastewater treatment plants contained HHCB, AHTN and DPMI at concentrations between 5.416 and 21.214, 0.715 and 6.195 and 0.599 and 2.870 mg/kg (dry), respectively. The highest concentration was found in sludge from one cosmetic plant at 703.681 mg HHCB/kg (dry). The results indicate that there are two sources of polycyclic musks: domestic sewage and industrial wastewater. 相似文献
315.
Pan B Liu WX Shi Z Cao J Shen WR Qing BP Sun R Tao S 《Journal of environmental science and health. Part. B》2004,39(3):353-365
The methods of sample purification for determinations of organochlorine pesticides (OCPs) in sediment and fish muscle were investigated in this study. A two-step procedure with preliminary cleanup and florisil column fraction was adopted. The working conditions of florisil column were firstly optimized. As to preliminary cleanup, liquid-liquid extraction by mixture of dimethyl formamide (DMF) and hexane and sulphonation by concentrated sulfuric acid were applied respectively and compared for the studied samples. The results indicated that liquid-liquid distribution could effectively separate lipids from fish muscle extracts, while failed in elimination of chlorophyll extracted from the relicts of hydrophytes in the sediment sample. In view of the sample appearance and clarity of gas chromatogram, sulphonation was more suitable to purify the sediment sample, however, the recoveries of the spiked standards were poor. The use of eluting solvent with stronger polarity could improve the corresponding recoveries significantly. Due to complete loss of Dieldrin, Endrin, and Endrin aldehyde after sulphonation, this pretreatment was improper to the three components. Sulfur, as the particular disturbing element in sediment, could be removed sufficiently by addition of activated copper powder. The relevant detection limits of the selected methods for OCPs in the studied substrates were also provided. 相似文献
316.
317.
Persistent organochlorine (OC) and toxic butyltin compounds (BTs) were determined in walleye pollock (Theragra chalcogramma) collected from Gulf of Alaska, Bering Sea and Japan Sea, during 1991 and 1992. Polychlorinated biphenyls (PCBs) and dichlorodiphenyltrichloroethane (DDTs) and its metabolites were the most abundant compounds ranging up to 3200 and 2500 ng/g on lipid weight, respectively, followed by chlordane compounds (CHLs), hexachlorocyclohexane isomers (HCHs) and hexachlorobenzene (HCB) in the liver of walleye pollock. Concentrations of HCHs and HCB in walleye pollock from these remote areas were higher than those in fishes from the western North Pacific and Japanese coastal waters, indicating atmospheric transport of these compounds to higher latitude regions such as Bering Sea and Gulf of Alaska and/or local input around northern Japan Sea. The concentrations of other OCs were generally comparable to those in fishes from North Pacific Ocean and Japanese waters but significantly lower than in cod-like fishes from North Atlantic and European countries. Among sampling locations, walleye pollock from Japan Sea showed higher concentrations of DDTs and HCHs compared to fishes from Bering Sea and Gulf of Alaska, suggesting greater input of these compounds around Japan Sea. Slower declining trend of DDTs and CHLs and an increasing pattern of PCBs concentrations were found in walleye pollock from Bering Sea during 1982-1992. This may imply a continuous input of these compounds by long-range transport and/or long-term persistency in these cold regions. Compared to the fishes from Japan Sea, walleye pollock from Bering Sea and Gulf of Alaska showed higher proportions of alpha-HCH and p,p'-DDE in the composition of HCH isomers and DDT compounds, respectively. This suggests selective transportability of these compounds during long-range transport to higher latitude remote areas. Concentrations of tributyltin (TBT) in the muscle of walleye pollock ranged from 1.1 to 5.5 ng/g on wet weight. Concentrations of TBT in deep-sea walleye pollock from Gulf of Alaska and Bering Sea were lower than those in Japan Sea. 相似文献
318.
Chlorinated and polycyclic aromatic hydrocarbons in riverine and estuarine sediments from Pearl River Delta, China 总被引:53,自引:0,他引:53
Mai BX Fu JM Sheng GY Kang YH Lin Z Zhang G Min YS Zeng EY 《Environmental pollution (Barking, Essex : 1987)》2002,117(3):457-474
Spatial distribution of chlorinated hydrocarbons [chlorinated pesticides (CPs) and polychlorinated biphenyls (PCBs)] and polycyclic aromatic hydrocarbons (PAHs) was measured in riverine and estuarine sediment samples from Pearl River Delta, China, collected in 1997. Concentrations of CPs of the riverine sediment samples range from 12 to 158 ng/g, dry weight, while those of PCBs range from 11 to 486 ng/g. The CPs concentrations of the estuarine sediment samples are in the range 6-1658 ng/g, while concentrations of PCBs are in the range 10-339 ng/g. Total PAH concentration ranges from 1168 to 21,329 ng/g in the riverine sediment samples, whereas the PAH concentration ranges from 323 to 14,812 ng/g in the sediment samples of the Estuary. Sediment samples of the Zhujiang River and Macao harbor around the Estuary show the highest concentrations of CPs, PCBs, and PAHs. Possible factors affecting the distribution patterns are also discussed based on the usage history of the chemicals, hydrologic condition, and land erosion due to urbanization processes. The composition of PAHs is investigated and used to assess petrogenic, combustion and naturally derived PAHs of the sediment samples of the Pearl River Delta. In addition, the concentrations of a number of organic compounds of the Pearl River Delta samples indicate that sediments of the Zhujiang river and Macao harbor are most likely to pose biological impairment. 相似文献
319.
The effects of cadmium stress on nodulation, N2-fixation capabilities of the root nodule, the change in ultrastructure of the root nodule, soybean growth, and the distribution of cadmium in plants were studied. The results obtained show that the nodulation of soybean roots was greatly inhibited by the addition of Cd, especially at the addition level of 10 and 20 mg kg(-1) soil. The inhibition of plant growth, especially the root growth, increased as the cadmium concentration increased, with deleterious effects observed for the roots. The weight ratio of soybean root/leaf decreased as the Cd concentration increased, which might explain the reason for nodulation decreases. The results also indicate that N2-fixation of root nodule was stimulated to some extent at the low levels of Cd addition, but decreased sharply with further increase of the Cd concentration. High Cd levels were also associated with changes in the ultrastructure of root nodule, in which the effective N2-fixing area was reduced and the N2-fixing cells in the area also reduced. In addition, the results also reveal that the content of Cd in different parts of the plants was as follows: roots > stems > seeds, indicating that the accumulation of Cd by roots is much larger than that by any other part of the soybean plant, and might cause deleterious effects to root systems. 相似文献
320.