全文获取类型
收费全文 | 12379篇 |
免费 | 483篇 |
国内免费 | 4727篇 |
专业分类
安全科学 | 817篇 |
废物处理 | 798篇 |
环保管理 | 931篇 |
综合类 | 6845篇 |
基础理论 | 2038篇 |
环境理论 | 6篇 |
污染及防治 | 4689篇 |
评价与监测 | 469篇 |
社会与环境 | 433篇 |
灾害及防治 | 563篇 |
出版年
2024年 | 2篇 |
2023年 | 198篇 |
2022年 | 580篇 |
2021年 | 480篇 |
2020年 | 353篇 |
2019年 | 358篇 |
2018年 | 482篇 |
2017年 | 559篇 |
2016年 | 641篇 |
2015年 | 844篇 |
2014年 | 972篇 |
2013年 | 1273篇 |
2012年 | 1022篇 |
2011年 | 1191篇 |
2010年 | 855篇 |
2009年 | 847篇 |
2008年 | 889篇 |
2007年 | 695篇 |
2006年 | 656篇 |
2005年 | 483篇 |
2004年 | 351篇 |
2003年 | 437篇 |
2002年 | 383篇 |
2001年 | 312篇 |
2000年 | 342篇 |
1999年 | 399篇 |
1998年 | 328篇 |
1997年 | 311篇 |
1996年 | 295篇 |
1995年 | 260篇 |
1994年 | 179篇 |
1993年 | 157篇 |
1992年 | 113篇 |
1991年 | 95篇 |
1990年 | 64篇 |
1989年 | 54篇 |
1988年 | 44篇 |
1987年 | 19篇 |
1986年 | 22篇 |
1985年 | 11篇 |
1984年 | 11篇 |
1983年 | 10篇 |
1982年 | 10篇 |
1981年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
231.
232.
In this study, we report a novel magnetic biomimetic nanozyme(Fe_3O_4@Cu/GMP(guanosine5′-monophosphate)) with high laccase-like activity, which could oxidize toxic ophenylenediamine(OPD) and remove phenolic compounds.The magnetic laccase-like nanozyme was readily obtained via complexed Cu~(2+)and GMP that grew on the surface of magnetic Fe_3O_4 nanoparticles.The prepared Fe_3O_4@Cu/GMP catalyst could be magnetically recycled for at least five cycles while still retaining above 70% activity.As a laccase mimic,Fe_3O_4@Cu/GMP had more activity and robust stability than natural laccase for the oxidization of OPD.Fe_3O_4@Cu/GMP retained about 90% residual activity at 90℃ and showed little change at pH 3–9, and the nanozyme kept its excellent activity after long-term storage.Meanwhile, Fe_3O_4@Cu/GMP had better activity for removing phenolic compounds, and the removal of naphthol was more than 95%.Consequently, the proposed Fe_3O_4@Cu/GMP nanozyme shows potential for use as a robust catalyst for applications in environmental remediation. 相似文献
233.
234.
235.
Effect of seed sludge on characteristics and microbial community of
aerobic granular sludge 总被引:2,自引:1,他引:2
Aerobic granular sludge was cultivated by using different kinds of seed sludge in sequencing batch airlift reactor.The influence of seed sludge on physical and chemical properties of granular sludge was studied;the microbial community structure was probed by using scanning electron microscope and polymerase chain reaction-denaturing gradient gel electrophoresis(PCR-DGGE).The results showed that seed sludge played an important role on the formation of aerobic granules.Seed sludge taken from beer wastewater treatment plant(inoculum A) was more suitable for cultivating aerobic granules than that of sludge from municipal wastewater treatment plant(inoculum B).Cultivated with inoculum A, large amount of mature granules formed after 35 days operation, its SVI reached 32.75 mL/g, and SOUR of granular sludge was beyond 1.10 mg/(g·min).By contrast, it needed 56 days obtaining mature granules using inoculum B.DGGE profiles indicated that the dominant microbial species in mature granules were 18 and 11 OTU when inoculum A and B were respectively employed as seed sludge.The sequencing results suggested that dominant species in mature granules cultivated by inoculum A were Paracoccus sp., Devosia hwasunensi, Pseudoxanthomonas sp., while the dominant species were Lactococcus raffinolactis and Pseudomonas sp.in granules developed from inoculum B. 相似文献
236.
237.
Comparison of quartz sand, anthracite, shale and biological ceramsite for adsorptive removal of phosphorus from aqueous solution 总被引:1,自引:0,他引:1
The choice of substrates with high phosphorus adsorption capacity is vital for sustainable phosphorus removal from waste water in constructed wetlands. In this study, four substrates were used: quartz sand, anthracite, shale and biological ceramsite. These substrate samples were characterized by X- ray diffractometry and scanning electron microscopy studies for their mineral components (chemical components) and surface characteristics. The dynamic experimental results revealed the following ranking order for total phosphorus (TP) removal efficiency: anthracite 〉 biological ceramsite 〉 shale 〉 quartz sand. The adsorptive removal capacities for TP using anthracite, biological ceramsite, shale and quartz sand were 85.87, 81.44, 59.65, and 55.98 mg/kg, respectively. Phosphorus desorption was also studied to analyze the substrates' adsorption efficiency in wastewater treatment as well as the substrates' ability to be reused for treatment. It was noted that the removal performance for the different forms of phosphorus was dependent on the nature of the substrate and the adsorption mechanism. A comparative analysis showed that the removal of particulate phosphorus was much easier using shale. Whereas anthracite had the highest soluble reactive phosphorus (SRP) adsorptive capacity, biological ceramsite had the highest dissolved organic phosphorus (DOP) removal capacity. Phosphorus removal by shale and biological ceramsite was mainly through chemical adsorption, precipitation or biological adsorption. On the other hand, phosphorus removal through physical adsorption (electrostatic attraction or ion exchange) was dominant in anthracite and quartz sand. 相似文献
238.
239.
科技飞速发展的今天,射频及微波技术已经广泛应用于国民经济的各个领域,这使得越来越多的从业人员在工作场所受到电磁辐射污染的影响。本文总结归纳了我国电磁辐射职业危害状况,分析了现代企业电磁辐射防护的新特点,并提出企业电磁辐射防护对策。 相似文献
240.
Adsorption of mixed cationic-nonionic surfactant and its effect on bentonite structure 总被引:1,自引:0,他引:1
The adsorption of cationic-nonionic mixed surfactant onto bentonite and its effect on bentonite structure were investigated. The objective was to improve the understanding of surfactant behavior on clay mineral for its possible use in remediation technologies of soil and groundwater contaminated by toxic organic compounds. The cationic surfactant used was hexadecylpyridinium bromide (HDPB), and the nonionic surfactant was Triton X-100 (TX100). Adsorption of TX100 was enhanced significantly by the addition of HDPB, but this enhancement decreased with an increase in the fraction of the cationic surfactant. Part of HDPB was replaced by TX100 which decreased the adsorption of HDPB. However, the total adsorbed amount of the mixed surfactant was still increased substantially, indicating the synergistic effect between the cationic and nonionic surfactants. The surfactant-modified bentonite was characterized by Brunauer-Emmett-Teller specific surface area measurement, Fourier transform infrared spectroscopy, and thermogravimetric-derivative thermogravimetric/differential thermal analyses. Surfactant intercalation was found to decrease the bentonite specific surface area, pore volume, and surface roughness and irregularities, as calculated by nitrogen adsorption-desorption isotherms. The co-adsorption of the cationic and nonionic surfactants increased the ordering conformation of the adsorbed surfactants on bentonite, but decreased the thermal stability of the organobentonite system. 相似文献