ATR-FTIR investigation of the role of phenolic groups in the interaction of some NOM model compounds with aluminum hydroxide

The role of phenolic groups in the interaction of natural organic matter (NOM) with metal hydroxides was investigated with ATR-FTIR spectroscopy and adsorption tests by employing a series of dihydroxybenzoic acids (DHBAs) as the NOM surrogates and aluminum hydroxide as the adsorbent. All DHBAs examined in this study were found to be adsorbed on aluminum hydroxide by forming inner-sphere complexes. Carboxylic groups governed the complexation of DHBAs with aluminum hydroxide at low pH or in cases when the two hydroxyl groups were not adjacent to each other and neither of them was ortho to the carboxylic group. The involvement of the phenolic groups, ortho to another phenolic group or ortho to the carboxylic groups, in the complexation increased with increasing pH as the deprotonation of phenolic groups was easier at higher pH. The presence of phenolic groups increased the electron density of the carboxylic groups and facilitated the inner-sphere complexation of the carboxylic groups with metal hydroxide. The correlation between the pK_a values and the amount of organic acid adsorbed on the aluminum hydroxide revealed that the adsorption of DHBAs at acidic pH was largely dependent on the surface chelate formation rather than on the electronic effect.     

SIMULATING THREE-DIMENSIONAL GROUND WATER RESPONSE IN A SMALL MOUNTAINOUS WATERSHED1

ABSTRACT: Snowmelt from deep mountainous snowpacks is seldom rapid enough to exceed infiltration rates; thus, the source of streamflow in many mountainous watersheds is snowmelt recharge through shallow ground water systems. The hydrologic response and interaction between surface and sub-surface flow processes in these watersheds, which is controlled by basin structure, the spatial distribution of snowmelt, and the hydrogeology of the subsurface, are not well understood. The purpose of this study was to test a three-dimensional ground water model using simulated snowmelt input to simulate ground water response to spatially distributed snowmelt on the Upper Sheep Creek Watershed located within the Reynolds Creek Experimental Watershed in Southwestern Idaho. The model was used to characterize the mountainous aquifer and to delineate the subsurface flow mechanisms. Difficulty in finding a reasonable combination of grid spacing and time stepping within the model was encountered due to convergence problems with the Picard solution to the non-linear variably saturated ground water flow equations. Simulation results indicated that flow may be either unconfined or confined depending on inflow rate and hydrogeologic conditions in the watershed. The flow mechanism had a much faster response time when confined flow occurred. Response to snowmelt from a snow drift approximately 90 m away took only a few hours when flow was confined. Simulated results showed good agreement with piezometer measurements both in magnitude and timing; however, convergence problems with the Picard solution limited applicability of the model.     

从废催化剂中回收钼的新工艺

确定了用新型复合浸取剂从废催化剂中回收钼的最佳工艺条件废催化剂颗粒度１００目焙烧温度７５０℃,焙烧时间１ｈ复合浸取剂中助浸剂质量为５％,浸取固液质量比１：３,浸取温度６０℃,浸取时间６ｈ,在该条件下,钼的浸取率达到９２．７％～９５．５％。     

古裂谷双模式地质特征

裂谷特有的作用过程——早期沿上地幔热异常带岩石圈遭受拉张上隆、减薄,中期断裂下陷及晚期的挤压、回返,造成陆内古裂谷具一系列双模式地质特征:先张后压构造形迹互相叠置、基性与酸性火山岩同时并存、非补偿性沉积与补偿性沉积构成沉积双元结构、双向式水流体系以及双模式成矿,变质作用。     

城市机动车尾气污染控制的综合对策体系研究

在综述城市机动车尾气污染的已有对策基础上，阐述了包括规划层次、管理层次、工程层次和车辆层次在内的综合对策体系，并就国内不同阶段所侧重的对策层次进行了探讨。     

铁路旅客列车垃圾中重金属元素调查及防治对策的研究

采用现场调研、取样、理化检测和分析的方法 ,以掌握铁路旅客列车垃圾中重金属含量水平 ,垃圾中主要污染元素和主要污染物有关的数据和信息 ;在调查和综合分析的基础上 ,提出铁路旅客列车垃圾重金属污染的防治对策 ,为有效地处理铁路旅客列车垃圾提供了科学依据     

小型制药厂污水处理工程设计

小型制药厂生产废水具有水质、水量波动大的特点,应用普通处理工艺很难适应水质、水量的大幅度波动。多级水解酸化-接触氧化工艺具有较高的抗冲击负荷,工程实例结果表明应用该工艺可以使处理设施长期稳定运行,并实现出水达标排放。     

长波紫外线对M13mp2噬菌体的致突变作用

以野生型大肠菌CSH50及mutM缺陷的大肠菌MF67为宿主,检测了长波紫外线（UVA）对M13mp2噬菌体单链DNAlacZα基因区域的致突变能力。结果显示,UVA照射可引起噬菌体lacZα基因区域的突变,在mutM缺陷的宿主中,UVA照射的致突变作用更明显。进一步研究了抗氧化剂甘露醇对UVA照射致突变作用的影响,结果显示,0.1mol/L的甘露醇可以部分拮抗UVA的致突变作用。说明UVA照射具有致突变作用,这种作用可能与DNA的氧化损伤有关     

掺铁TiO2对庚烷气相光催化活性的研究

以乙酰丙酮铁和钛酸四丁酯为前驱体,制备掺铁TiO2复合光催化剂,以光催化降解正庚烷为反应模型,测定掺铁对TiO2光催化剂的结构、光吸收和光催化活性的影响．XRD的表征结果显示,焙烧温度升高,锐钛矿型TiO2转化成金红石型,且在700℃下有铁板钛矿生成;UV-Vis的结果表明,TiO2掺铁后增强了在可见光区的吸收,并且随着含铁量的增大,红移增大,提高了对可见光的利用率．相同掺铁量(Fe／Ti=0．07)下,500℃焙烧的光催化剂对庚烷的光催化降解活性最高,300℃次之,700℃最差．相同焙烧温度下,掺铁量在0．007-0．07范围内,光催化活性随掺杂量的增大而下降．