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201.
对聚酯装置工艺废气的形成,稳定性,采样方法及其浓度变化等进行了研究,结果表明,经冷的乙二醇娟收后排放出的聚酯放心气化学性质稳定,可采用聚四氟乙烯袋直接采样,采用DB-5大口径石英毛细管柱气相色谱法分析废气净化前后的有机污染物含量,净化前乙醛浓度变化在2000-30000mg/m^3之间,超出GB16297新污染源大气污染物排放限值(125mg/m^3)10-250倍,经处理后可达到国家排放标准,本方法可用于聚酯装置废气的监控。 相似文献
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203.
通过两起浮顶油罐雷击着火事故的成功扑救案例,结合某单位浮顶油罐的管理现状,提出了整治消防设施隐患、特大型储油罐增加等电位连接点、加强应急预案实战技术演练、完善通讯设施、加强管理、提高员工责任意识、狠抓安全培训、提高职工技术素质等防止浮顶油罐雷击着火的预防措施和在事故状态下将事故损失降到最低的建议。 相似文献
204.
大孔树脂对柠檬黄吸附行为的研究 总被引:2,自引:0,他引:2
用三种大孔树脂NDA-7、NDA-99和ND-900作为吸附剂,对水溶液中柠檬黄进行吸附,探讨了温度、盐含量和pH值对不同类型树脂吸附行为的影响。实验结果表明,三种树脂对柠檬黄的吸附均符合Freun-dlich公式,在相同温度下,三种树脂对柠檬黄的吸附量大小顺序为ND-900〉NDA-99〉NDA-7;降温和减小溶液初始pH值均有利于三种树脂对柠檬黄的吸附;盐分对三种树脂的吸附效果均有严重的负效应,但是随着盐含量的增加,三种树脂对柠檬黄的吸附曲线又表现出不同的变化趋势。 相似文献
205.
Myat Sandar Win Zhengyang Tian Hui Zhao Kai Xiao Jiaxian Peng Yu Shang Minghong Wu Guangli Xiu Senlin Lu Shinich Yonemochi Qingyue Wang 《环境科学学报(英文版)》2018,30(9):13-31
Atmospheric humic-like substances(HULIS) are not only an unresolved mixture of macroorganic compounds but also powerful chelating agents in atmospheric particulate matters(PMs); impacting on both the properties of aerosol particles and health effects by generating reactive oxygen species(ROS). Currently, the interests of HULIS are intensively shifting to the investigations of HULIS-metal synergic effects and kinetics modeling studies, as well as the development of HULIS quantification, findings of possible HULIS sources and generation of ROS from HULIS. In light of HULIS studies, we comprehensively review the current knowledge of isolation and physicochemical characterization of HULIS from atmospheric samples as well as HULIS properties(hygroscopic, surface activity, and colloidal) and possible sources of HULIS.This review mainly highlights the generation of reactive oxygen species(ROS) from PMs, HULIS and transition metals, especially iron. This review also summarized the mechanism of ironorganic complexation and recent findings of OH formation from HULIS-metal complexes. This review will be helpful to carry out the modeling studies that concern with HULIS-transition metals and for further studies in the generation of ROS from HULIS-metal complexes. 相似文献
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207.
文章对造成环境污染的外部不经济性原因进行了分析,指出只有通过政府干预,加强立法,明确环境资源产权,征收环境污染税收,开放排污权交易市场,才能利用市场机制优化环境资源的配置,合理的分配环境资源,从而实现整个社会最有效率地控制污染. 相似文献
208.
室内氡子体浓度的动态观测 总被引:1,自引:0,他引:1
采用Markov快速潜能法,观测了武汉市某一建筑物室内氡子体浓度随季节和昼夜的变化规律.结果表明:全年(215天)室内氡子体浓度呈正态分布,24小时内最大值与最小值之比为2.9,月均值在年均值±60%内变化.对气压、气温、日照、相对湿度等气象因素的影响也进行了初步探讨. 相似文献
209.
Douglas A. Day Shang Liu Lynn M. Russell Paul J. Ziemann 《Atmospheric environment (Oxford, England : 1994)》2010,44(16):1970-1979
During wintertime measurements in coastal southern California, organonitrate groups accounted for up to 10% of organic mass (OM) in submicron particles. In this study, we report the calibrated absorptivity, the uncertainties in the calibrations, the detection limits for 12 and 24 h ambient sampling, and the multipeak retrieval algorithm for the method developed. Organonitrate groups were observed when both submicron particle-phase nitrate and OM concentrations exceeded 1 μg m?3. These high concentrations were associated with a mixed urban fossil fuel combustion source type that had potential source regions near Riverside and the South Coast Air Basin. The high frequency of these organonitrate observations contrasts with a number of studies of aerosol particles in other regions with more humid conditions, in which organonitrate groups were not detected and submicron sulfate concentrations exceeded those of nitrate. Our results suggest both that organonitrates form and/or exist in significant concentrations during polluted urban conditions and that their lifetime may be limited by hydrolysis in the particle phase. 相似文献
210.
Ai H. Shang Dong H. Chen Xiao X. Lu Hai D. Lu Chao N. Liu 《Journal of environmental science and health. Part. B》2013,48(11):809-818
This study aimed to evaluate the aquatic toxicity of three typical tetracycline antibiotics, including tetracycline, oxytetracycline, and chlortetracycline, on the cyanobacterium Microcystis aeruginosa. The cell density, chlorophyll a content, protein content, and enzymatic antioxidant activities were determined. The results showed that the cell growth was significantly inhibited by the three compounds at a low concentration. The chlorophyll a and protein content decreased significantly after exposure to 0.05 mg L?1 of each compound for 9 d. When exposed to 0.2–1 mg L?1 of tetracycline, the superoxide dismutase (SOD) activity increased, but peroxidase (POD) and catalase (CAT) activities decreased. In contrast, when exposed to oxytetracycline and chlortetracycline at different concentrations ranging from 0.2 to 1 mg L?1 and from 0.01 to 0.05 mg L?1, the SOD activity decreased, but the POD and CAT activities increased. These findings indicate that tetracycline antibiotics influence cell growth and protein synthesis, and they also induce oxidative stress in M. aeruginosa at environmentally similar concentrations. Thus, this study may provide further insights into the toxic effects of tetracycline antibiotics and the controlled use of antibiotics. 相似文献