两种AHLs信号分子对生物膜法养殖污水处理条件下水体内环境的影响

为提高生物膜法处理养殖污水的效果,对不同信号分子条件下的生物膜处理情况进行研究。在室内循环水养殖系统中,设定3个实验组和1个对照组,分别添加乙醇、C6-HSL、N-3-oxo-C8-HSL和蒸馏水,并在模拟过程中取样分析。实验结果表明,3个实验组附着基上的生物量明显多于对照组,尤其是添加N-3-oxo-C8-HSL组产生的生物量约为对照组的6倍;经添加C6-HSL和N-3-oxo-C8-HSL处理的养殖水体中,亚硝酸盐最终浓度比对照组低28.6%,但无机磷浓度稍高。数据因子分析结果表明,实验过程中(9～27 d),添加AHLs信号因子C6-HSL和N-3-oxo-C8-HSL两组养殖水体内环境的总体得分较高,说明养殖水体的内环境处于较好状态。     

Carbonyl emissions from vehicular exhausts sources in Hong Kong

Vehicular emission (VE) is one of the important anthropogenic sources for airborne carbonyls in urban area. Six types of VE-dominated samples were collected at representative locations in Hong Kong where polluted by a particular fueled type of vehicles, including (i) a gas refilling taxis station (liquefied petroleum gas [LPG] emission); (ii) a light-duty passenger car park (gasoline emission); (iii) a minibus station (diesel emission); (iv) a single-deck-bus depot (diesel emission); (v) a double-deck-bus depot (diesel emission); and (vi) a whole-food market entrance for light- and heavy-duty vehicles (diesel emission). A total of 15 carbonyls in the samples were quantified. Formaldehyde was the most abundant carbonyl among the VE-dominated samples, and its contribution to the total quantified amount on a molar basis ranged from 54.8% to 60.8%. Acetaldehyde and acetone were the next two abundant carbonyls. The carbonyls were quantified at three roadside locations in Hong Kong. The highest concentrations of formaldehyde and acetaldehyde, 22.7 +/- 8.4 and 6.0 +/- 2.8 microg/m3, respectively, were determined in the samples collected at a main transportation gate for goods between Hong Kong and Mainland China. The total quantified carbonyl concentration, 37.9 +/- 9.3 microg/m3, was the highest at an entrance of a cross-harbor tunnel in downtown area. The theoretical carbonyls compositions of the three roadside locations were estimated according to the VE-dominated sample profiles and the statistics on vehicle numbers and types during the sampling period. The measured compositions of formaldehyde were much higher than the theoretical compositions in summer, demonstrating that photochemical reactions significantly contributed to the formaldehyde production in the roadsides.     

脂肽类生物表面活性剂液体发酵条件的响应面优化

通过Plackett-Burman和Box-Behnken实验对解淀粉芽孢杆菌XZ-173液体发酵生产表面活性素进行了响应面优化研究。首先使用Plackett-Burman实验对影响表面活性素产量的17个因素进行显著性筛选,结果表明,MnSO4、CuSO4、温度和转速为显著性因素。再运用Box-Behnken实验对这4个显著因素的取值进一步优化,得到各因素优化后的数值分别为4.4 mg/L(MnSO4)、0.18 mg/L(CuSO4)、29℃(温度)和163 r/min(转速)。响应面分析结果表明:该菌株产生表面活性素的最佳培养基为:葡萄糖15 g/L,蛋白胨5 g/L,L-谷氨酸钠6 g/L,KH2PO40.8 g/L,MgSO40.4 g/L,KCl 0.4 g/L,酵母提取物3 g/L,L-苯丙氨酸2.5 mg/L,MnSO44.4 mg/L,CuSO40.18 mg/L,FeSO40.12 mg/L;最适培养条件:pH 7.5,温度29℃,转速163 r/min,接种量5%,装液量50 mL/250 mL,摇床培养36 h。在优化后的条件下,表面活性素实际产量为336 mg/L,实际实验结果与模型预测结果相一致。表面活性素采用HPLC技术分离,发现其在浓度仅为50 mg/L时EI24就可达到70%以上,反映了表面活性素优异的乳化活性以及广阔的应用前景。     

Degradation of aqueous Rhodamine B by plasma generated along the water surface and its enhancement using nanocrystalline Fe-, Mn-, and Ce-doped TiO2 films

The degradation of aqueous Rhodamine B (RhB) was examined using a dual-channel spark switch module designed to regulate the steepness of pulsed high voltage with microsecond rise time. Depending on the energy per pulse, a spark along the water surface (SPWS) or streamer along the water surface (STWS) was formed. STWS was found to have a better degradation effect and energy efficiency toward RhB than SPWS at the same power; however, addition of H₂O₂ amounts resulted in increased degradation, the effect being more pronounced using SPWS. The initial concentration of RhB also appeared to influence the rate constant of the degradation reaction. Furthermore, TiO₂ films doped with Fe, Mn, and Ce were found to enhance the degradation performance of plasma. A possible reaction mechanism of plasma formation along the water surface was concluded by determination of the main inorganic products in the liquid and gas phases.     

三峡工程运用对鄱阳湖水资源利用影响分析

三峡工程是我国有史以来建设的最大型的工程项目,具有防洪、发电、航运等方面巨大的经济和社会效益。然而,三峡工程的运用不可避免地会对原有江河湖泊水文情势产生一定影响。通过建立长江中下游（宜昌~大通）水沙模拟模型,定量分析了三峡工程运用对鄱阳湖水位的影响。三峡水库蓄水期（9月中下旬~11月）,三峡水库下泄流量比水库运用前减少3 000~6 000 m3/s,湖区各站水位最大降幅为07~19 m,平均降幅04~09 m。以此为基础,通过典型调查分析了三峡水库蓄水对鄱阳湖区农田灌溉用水和城镇供水的影响,提出了消除或降低影响的对策措施。研究结果可为鄱阳湖及长江中下游地区经济社会可持续发展和鄱阳湖综合治理提供科学依据和技术支撑     

中国碳交易市场发展现状及对策分析

中国强制碳交易标的物的确定、排放权的分配、排放源的监测核查等制度设计尚不明晰,也未出台温室气体交易活动的相关管理办法,碳减排体系尚未真正确立。碳市场处于初建期、探索期。通过对碳交易活动的背景、实质、运行机制以及国内碳交易现状的分析,结合应对气候变化的国际进展和国内政策行动对中国碳交易市场发展对策进行了探讨。     

Spatial distribution of perfluoroalkyl acids in the Pearl River of Southern China

An intensive campaign was conducted in September 2012 to collect surface water samples along the tributaries of the Pearl River in southern China. Thirteen perfluoroalkyl acids (PFAAs), including perfluorocarboxylates (PFCAs, C4–C11) and perfluorosulfonates (PFSAs, C4, C6–C8, and C10), were determined using high-performance liquid chromatography/negative electrospray ionization–tandem mass spectrometry (HPLC/(-)ESI–MS/MS). The concentrations of total PFAAs (ΣPFAAs) ranged from 3.0 to 52 ng L⁻¹, with an average of 19 ± 12 ng L⁻¹. The highest concentrations of ΣPFAAs were detected in the surface water of the Dong Jiang tributary (17–52 ng L⁻¹), followed by the main stream (13–26 ng L⁻¹) and the Sha Wan stream (3.0–4.5 ng L⁻¹). Perfluorooctanoate (PFOA), perfluorobutane sulfonate (PFBS), and perfluorooctane sulfonate (PFOS) were the three most abundant PFAAs and on average accounted for 20%, 24%, and 19% of ΣPFAAs, respectively. PFBS was the most abundant PFAA in the Dong Jiang tributary, and PFOA was the highest PFAA in the samples from the main stream of the Pearl River. A correlation was found between PFBS and PFOA, which suggests that both of these PFAAs originate from common source(s) in the region. Nevertheless, the slope of PFBS/PFOA was different in the different tributaries sampled, which indicates a spatial difference in the source profiles of the PFAAs.     

出口角度对防烟空气幕防烟效果影响的数值模拟

利用火灾动力学模拟软件FDS,以四川消防研究所高层实验塔二层为原型,模拟在不同防烟空气幕出口角度情况下高层建筑前室烟气运动情况,获得在其他条件不变情况下,空气幕运行时的最佳出口角度。试验结果表明:空气幕角度为5°及20°时,模拟试验后期烟气基本突破了空气幕蔓延至前室内,而当出口角度为10°和15°时防烟效果较好,且15°时防烟效果优于10°,故推荐空气幕运行时的最佳出口角度为15°。     

不同采样方法测算结果的分析与比较

通过瞬时采样、等时采样、等比例采样测算结果的分析和比较 ,说明用等比例采样法采集水样并核定出污染物的排放总量 ,解决了水样的代表性问题。