水坝建设影响下澜沧江中游沉积物重金属形态分析及污染指数研究

采集了漫湾库区和大朝山库区25个采样断面的沉积物样品.每个库区均从上游到下游分为河流区、过渡区和湖泊区,研究了沉积物中As、Cd、Cr、Cu、Mn、Ni、Pb、Zn元素的含量和赋存形态差异,利用次生相与原生相分布比值法(RSP)分析重金属元素的污染水平.结果表明,各库区从上游到下游沉积物中的重金属元素和碳氮元素均呈现出增加的趋势,而沉积物的中值粒径呈现出减小的趋势.漫湾库区的As、Cd、Zn元素平均含量均高于大朝山库区;大朝山库区的Cr、Mn、Ni、Pb元素平均含量均高于漫湾库区.在重金属赋存形态中,Cd和Mn元素以可交换态和残渣态为主;Cu、Pb以有机质态和残渣态为主;其余重金属元素均以残渣态为主.沉积物中的可交换态在有机碳的络合作用下转化成有机质态.在水坝建设的影响下沉积物中细颗粒和有机质含量明显上升,重金属在细颗粒物和有机质的共同作用下蓄积于坝前的沉积物中.PSR分析结果表明,在水坝运行影响下,各库区湖泊区和过渡区的污染水平均高于河流区.其中,Cd元素所有地区处于重度污染水平;Mn和Pb大部分区域处于中度污染水平;Cu元素大部分区域处于轻度污染水平;其余元素基本无污染.     

我国大陆地区电器电子产品报废量预测研究

随着我国电器电子产品的报废量不断增长,准确预测报废量及其分布对回收网络体系规划研究十分关键.本文利用Gompertz模型及保有量系数法对我国电器电子产品报废量进行建模,在验证预测模型及结果准确性的前提下,对全国31个省2003—2020年电视机、电冰箱、洗衣机、空调及电脑的报废量进行预测,并对5种家用电器报废总量构成、时间序列及空间分布进行分析.结果表明,到2020年,我国5种家用电器报废量将达到20.3亿台,广东省以1794万台报废量列居全国首位,上海市以1083台·km~(-2)的报废密度列居首位;按现有回收处理规模,2014年全国仍存在103万t待处理缺口.最后对废旧电器电子产品拆解处理产能布局提出了合理化建议,为我国的家用电器回收网络规划提供参考.     

城市热环境季相变异及与非渗透地表的定量关系分析——以广州市中心区为例

基于遥感卫星影像的热环境时空格局及与地表特征相关性分析是目前城市热环境研究的主要内容,但此类研究针对季相变异特征的分析较为缺乏。以广州市中心区2005年下半年3期不同季相的Landsat TM影像为数据源,提出一种面向对象分割的方法提取城市热岛/冷岛分布,并利用重心模型定量其季相变化移动轨迹;采用回归树模型构建地表温度(Land surface temperature,LST)与非渗透地表的关系方程,旨在揭示城市热环境季相变异性规律。结果表明:(1)随夏季到深秋,热岛呈现从中心区退出的态势,南部冷岛大面积消失,7月18日至10月22日热岛重心向东移动2.5 km,冷岛重心向西北移动3.4 km。10月22日至11月23日冷岛重心向西北移动9 km,热岛重心向东南移动8 km;(2)随季相变化,地表温度与非渗透地表的正相关关系趋于复杂,二者相关性从7月18日的0.994 1降至11月23日的0.869 1,对于11月23日数据,使用二次多项式方程更能表达二者的关系;(3)与传统的线性回归模型相比,回归树模型能更好地模拟地表温度的空间异质性,非渗透地表的增温作用存在非线性趋势,并且二者的关系模型存在明显的空间异质性。     

酵母生物转化生产2-苯乙醇的研究进展

主要论述了利用酵母菌生物转化合成天然2苯乙醇的研究进展,从应用微生物学的角度介绍了2苯乙醇生产菌株的筛选,分析了2苯乙醇合成过程中几方面因素的影响和培养条件的选择,并对产物原位转移技术作了简要说明.并从分子生物学的角度出发,对生物转化的重点途径———艾利希途径在基因水平上作了诠释,且例举了利用从头合成途径进行的基因工程育种,旨在为利用微生物生产2苯乙醇的研究开发提供参考.图1参40     

Exposure of children aged 0–7 years to perfluorinated compounds in Foshan,China

Environmental Science and Pollution Research - To evaluate the exposure of children to 14 perfluorinated compounds (PFCs) in a typical and representative industrial city, plasma samples from 476...     

氯氰菊酯降解菌CY22-7的分离鉴定及降解特性研究

从采集的多种土壤样品中.获得了19株在3种筛选平板上均生长良好的候选氯氰菊酯降解菌.通过生理生化特性鉴定和16S rDNA序列的测定及比对.将其中的氯氰菊酯降解菌CY22-7鉴定为中华根瘤菌属(Sinorhizobium sp.).同时,对氯氰菊酯降解菌CY22-7的降解特性研究结果表明:(1)氯氰菊酯降解菌CY22-7以5%(体积分数)的接种鼍接种到氯氰菊酯起始质量浓度为100 mg/L的氯氰菊酯乙醇培养基后,于200 r/min、30℃摇床中培养.经过6 d的培养,氯氰菊酯降解菌CY22-7降解了约60%的氯氰菊酯.(2)加人外源营养物质有利于促进氯氰菊酯的降解.其中,葡萄糖和酵母提取物的促进作用最为明显.(3)氯氰菊酯降解菌CY22-7降解氯氰菊酯的最适温度为30℃,最佳pH为6.0.     

Study on the aerosol optical properties and their relationship with aerosol chemical compositions over three regional background stations in China

The special and temporal characteristics of aerosol optical depth (AOD) and Angstrom wavelength exponent (Alpha) and their relationship with aerosol chemical compositions were analyzed by using the data of CE318 sun-photometer and aerosol sampling instruments at Lin'an, Shangdianzi and Longfengshan regional atmospheric background stations. Having the highest AOD among the three stations, Lin'an shows two peaks in a year. The AOD at Shangdianzi station shows a single annual peak with an obvious seasonal variation. The AOD at Longfengshan station has obvious seasonal variation which peaks in spring. The Alpha analysis suggests that the aerosol sizes in Lin'an, Longfengshan and Shangdianzi change from fine to coarse categories. The relationship between the aerosol optical depths of the Lin'an and Longfengshan stations and their chemical compositions is not significant, which suggests that there is not a simple linear relationship between column aerosol optical depth and the near surface chemical compositions of atmospheric aerosols. The aerosol optical depth may be affected by the chemical composition, the particle size and the shape of aerosol as well as the water vapor in the atmosphere.     

Distribution and contamination assessment of heavy metals in sediment of the Second Songhua River, China

The Second Songhua River was subjected to a large amount of raw or primary effluent from chemical industries in Jilin city in 1960s to 1970s, resulting in serious mercury pollution. However, an understanding of other trace metal pollution has remained unclear. The objective of this study was to investigate trace metal contamination in the sediment of the river. Bottom sediment samples were taken in the river between Jilin city and Haerbin city in 2005. An uncontaminated sediment profile was taken in the Nen River at the same time. Total concentrations of Al, Fe, Mg, Ca, K, Na, Ti, Mn, V, Sc, Co, Cu, Cr, Ni, Pb and Zn in the sediment samples were measured by ICP-MS or ICP-OES, following digestion with various acids. Concentrations of Co, Cu, Cr, Ni, Pb and Zn in the surface sediments were 5.1–14.7, 18.5–78.9, 2.4–75.4, 7.2–29.0, 13.5–124.4, and 21.8–403.1 mg/kg, respectively, generally decreasing along the course of the river from Jilin city to Haerbin city. Background concentrations of trace metals were reconstructed by geochemical normalization to a conservative element scandium. Results showed that concentrations of Co, Cr, and Ni in the sediment were generally only slightly higher than or equal to their background values, while concentrations of Cu, Pb, and Zn in the some sediment samples were significantly higher than their background values. In detail, the sediment at Jilin city was moderately contaminated by Cu, and the sediment of the Second Songhua River was moderately contaminated by Pb and Zn. The top layer (0–10 cm depth) and bottom layers (30–46 cm depth) of one sediment profile at Wukeshu town were generally moderately polluted by Pb and Zn. Synthetically, the surface sediment in the studied river section was classified as natural sediment without ecological risk by the sediment pollution index (SPI) of Cu, Cr, Ni, Pb and Zn. Only the 30–45 cm depth of the sediment profile at Wukeshu town was classified as low polluted sediment by the SPI of these metals, recording a historical contamination of the river in the 1960s to 1970s. This buried contamination of trace metals might pose a potential risk to water column under disturbance of sediment. Foundation item: The National Basic Research Priorities Program of China (2004CB418502)     

结合生态需水的黄河水资源水质水量联合评价

在分析河水满足人类用水和河道生态功能需水双重功能的前提下,提出了河水生态功能强度的概念,以及结合生态需水的流域水资源数量与质量联合评价的方法.根据黄河流域1997-1999年间主要水文站点逐月的水质监测数据、水文数据及各取水口逐月的取水量数据,结合生态需水对黄河流域的水资源进行了水质水量综合评价.结果表明,河水生态功能强度的时空分布不均,这与水量和水质的时空分布相关.在1997、1998和1999年,黄河总可利用水资源量分别为371.17×108、425.50×108和500.64×10 m3,其中具备河道生态功能的水资源量分别为129.51×108、151.51×108和205.88×108m3,远远小于维持河道生态系统健康所需的水资源量230.60×108m3,导致了黄河断流和其它生态环境问题的出现.     

河流生态基流量整合计算模型

针对北方地区流域水域生态系统人工化明显和河流断流的现状,提出了河流生态基流量的概念,并分析了其内涵．河流生态基流量包括河道生态基流量、河口生态基流量和湿地生态基流量．河流生态基流量计算应考虑流域内不同水系、不同河段生态环境的差异性和时空变化规律．通过改进生态环境需水量的计算方法,分析河流的空间结构特征、各河段的相互关系以及流域的水特征,提出了整合计算模型．整合计算模型分为2类：不同水系和同一水系的整合．同一水系整合计算模型又分为：河流生态基流量整合模型、河流与湿地生态基流量的整合以及河道生态基流量的整合模型．其中最为复杂的河道生态基流量的整合模型共分为6种形式：简单式、汇流式、分流式、组合式、交叉式和河口式．研究结果表明：各子系统的生态基流量是河流生态基流量整合计算的基础;河流生态基流量保证系数是计算的重要参数,其值在确定基数的基础上,通过恢复模式和空间优化配置这2个影响因子进行调整而得到,取值范围为[0,1];整合计算模型需要明确消耗性生态基流量和非消耗性生态基流量,消耗性生态基流量不受保证系数的影响,非消耗性生态基流量因保证系数取值的不同而变化．