氯代有机污染物在厌氧条件下还原脱氯的研究进展

对氯代有机污染物在产甲烷和硫酸盐还原条件下还原脱氯的研究成果进行了综述 ,并介绍了国内外加速厌氧条件下还原脱氯的方法与成果以及缓释氢物质 (hydrogenreleasecompounds ,HRC)的工作原理与工程应用。此外 ,作者还对厌氧还原脱氯的机理和未来的研究方向进行了讨论和展望     

液态高炉渣热量回收利用方法及问题

钢铁冶金行业生产会产生大量的高炉渣。高炉渣由于自身温度比较高，含热量丰富，对能源工业来说是一种很好的二次资源。世界上已有一些国家对高炉渣热量的回收利用进行了一定的研究，而国内这方面的研究却很少。详细介绍了近几年国内外对高炉渣热量回收利用的情况，在此基础上，阐述了高炉渣热回收技术需要解决的关键问题和发展趋势。     

液态高炉渣热量回收利用方法及问题

钢铁冶金行业生产会产生大量的高炉渣.高炉渣由于自身温度比较高,含热量丰富,对能源工业来说是一种很好的二次资源.世界上已有一些国家对高炉渣热量的回收利用进行了一定的研究,而国内这方面的研究却很少.详细介绍了近几年国内外对高炉渣热量回收利用的情况,在此基础上,阐述了高炉渣热回收技术需要解决的关键问题和发展趋势.     

氯盐⁃硫酸盐环境下钢筋混凝土柱抗震性能退化过程的数值模拟∗

针对氯盐-硫酸盐环境中钢筋混凝土构件抗震性能的劣化问题,利用Fick定律、离子浓度与材料损伤的拟合关系,确定了硫酸盐侵蚀下混凝土的损伤本构模型,根据氯盐环境下钢筋锈蚀特征及法拉第定律建立了钢筋截面积损失时变模型,并通过OpenSees软件分析了柱构件在侵蚀环境中抗震性能的退化情况。结果表明:随着服役时间的增加,柱的受压、受弯承载力及刚度逐渐退化,构件的延性、滞回耗能能力先增大后减小;服役初期,增大轴向力能够提高构件受弯承载力,但服役超过一定时间后,该作用不明显;整个服役周期内,轴向力的增大都将造成构件弹塑性变形能力降低,故高轴向力作用下,构件的延性、滞回耗能能力均降低。     

自然生态循环的良性平衡和科技产业的发展

探求既能有效解决人类生存所面临的重大问题 ,又能实现可持续发展的途径是人类发展的永恒主题。本文以此为目的 ,根据对相关内容的深入分析得出 ,以恢复、保持和发展自然生态循环的良性平衡为锁定目标 ,发展、形成大规模或超大规模的巨大科技产业体系 ,是实现人类可持续发展的必由之路。在此基础上 ,本文进一步分析了科技产业的发展条件 ,指出科技与经济的有机结合是形成和实现科技产业的必要条件 ,同时就如何在知识经济的迅速兴起的环境中发展科技产业提出了建议。以“恢复、保持和发展自然生态循环的良性平衡”为锁定目标 ,建立造福人类的科技产业体系既是时代的要求 ,也是时代的迫切呼唤     

铁(Ⅲ)-草酸盐配合物的光化学性质及其对天然水相中有机物光降解的作用

本文综述了天然水相（大气水相、地表水等）中Ｆｅ（Ⅲ）－草酸盐配合物的含量与分布、光化学性质、对天然水相中有机物的降解、及其在废水光化学处理中的应用研究及前景。     

Immobilization of lead in anthropogenic contaminated soils using phosphates with/without oxalic acid

Understanding the effects of oxalic acid (OA) on the immobilization of Pb(II) in contaminated soils by phosphate materials, has considerable benefits for risk assessment and remediation strategies for the soil. A series of phosphate amendments with/without oxalic acid were applied to two anthropogenic contaminated soils. We investigated the immobilization of Pb(II) by KH₂PO₄, phosphate rock (PR), activated phosphate rock (APR) and synthetic hydroxyapatite (HAP) at different phosphate:Pb (P:Pb) molar ratios (0, 0.6, 2.0 and 4.0) in the presence/absence of 50 mmol oxalic acid/kg soil, respectively. The effects of treatments were evaluated using single extraction with deionized water or CaCl₂, Community Bureau of Reference (BCR) sequential extraction and toxicity characteristic leaching procedure (TCLP) methods. Our results showed that the concentration of water extractable, exchangeable and TCLP-Pb all decreased with incubation time. The concentration of water-extractable Pb after 120 days was reduced by 100% when soils were amended with APR, HAP and HAP + OA, and the TCLP-Pb was <5 mg/L for the red soil at P:Pb molar ratio 4.0. Water-soluble Pb could not be detected and the TCLP-Pb was <5 mg/L at all treatments applied to the yellow-brown soil. BCR results indicated that APR was most effective, although a slight enhancement of water-soluble phosphate was detected at the P:Pb molar ratio 4.0 at the beginning of incubation. Oxalic acid activated phosphates, and so mixing insoluble phosphates with oxalic acid may be a useful strategy to improve their effectiveness in reducing Pb bioavailability.     

A Water Yield‐Oriented Practical Approach for Multifunctional Forest Management and its Application in Dryland Regions of China

Mountainous forest areas are vitally important for water supply in dryland regions which suffer from high erosion risk and severe water shortage. Massive afforestation, mainly for erosion control, may reduce the water yield and threaten local water supply security. Moreover, many over‐dense forests due to a strict logging ban policy have produced remarkably negative impacts for both forests (e.g., low timber quality, restricted natural regeneration, and high stand instability) and water yield. To satisfy the rapidly increasing demands on water supply and other services, a practical approach for managing forest stands in a multifunctional way, which particularly addresses water yielding, is urgently required. For this purpose, we integrated the existing knowledge and experience, designed an “ideal” stand structure to represent multifunctional forest (MFF) and determined its key parameters (a ground coverage of >0.7, a canopy density around 0.7, and an H/DBH ratio (tree height [m] to the diameter at breast height [cm]) of <0.7). Moreover, a decision process for MFF stand management was recommended as: (1) investigating the site quality; (2) identifying the site‐specific main forest functions; (3) quantifying the stand structure; (4) diagnosing the stand structure by comparing with the “ideal” one; and (5) arranging the functions/structure‐oriented management measures. In this way, the water‐yielding function can be improved and meanwhile other forest functions can be promoted.     

渗滤液的反渗透浓缩液回灌技术应用

以宜昌、宁国、蒙城垃圾填埋场为例,介绍了碟管式反渗透(DTRO)——浓缩液回灌工艺,研究发现:浓缩液回灌方式应根据垃圾填埋场的地理特征和业主的具体要求来确定。山谷型填埋场可以采用石笼回灌法,施工简单,成本较低,另外也可采用两层生物滤化床方式,成本稍高,但效果较好;平原型填埋场宜采用两层生物滤化床方式,而采用石笼回灌法容易出现短流现象。浓缩液回灌对渗滤液电导率无明显影响,不会影响后续反渗透系统的正常运行。     

Reassessment of the Ocean-To-Atmosphere Flux of Carbon Monoxide

Abstract

Carbon monoxide (CO) in the surface sea waters is produced predominantly by photochemical processes, oxidized by micro-organisms and outgassed to the atmosphere. to assess carbon monoxide flux from the oceans to the atmosphere, the photochemical production and microbial oxidation of carbon monoxide in the oceanic mixed-layer was investigated during several oeanographic cruises and in the laboratory. the photoproduction rate of carbon monoxide was found to be well correlated to the concentration of dissolved organic carbon (DOC) in coastal and open ocean surface waters. Taking a global average carbon monoxide production rate of 10 ± 2 nmole litre^?1 (mg DOC hr)^?1 in the surface open ocean water, and 25 ± 7 nmole litre^?1 (mg DOC hr)^?1 in coastal sea water, at cloud-free summer solar noon, the photochemical production of carbon monoxide in the global oceans is estimated to be at a rate of 1200 ± 200 Tg CO y^?1. the microbial carbon monoxide turnover time in the mixed-layer was observed to range from hours in a coastal estuary to 16 days in the Pacific along 1057deg; W in dark incubations. Natural sunlight can largely inhibit the microbial consumption of carbon monoxide in surface water. On a global scale, microbial consumption is responsible for the loss of less than 10% of photochemical produced carbon monoxide in the surface ocean. Field measurements have shown that the net transport of carbon monoxide from the euphotic zone to the underlying deeper ocean water is limited and that the overall life time in surface sea waters is less than 3-4 hours. When combined, these field measurements with the photoproduction and microbial consumption rates obtained, we estimate the oceanic flux to the atmosphere is about 1000 ± 200 Tg CO y^?1, which represents the largest single source of atmospheric carbon monoxide.