Characterisation of heavy metal discharge into the Ria of Huelva

The Ria of Huelva estuary, in SW Spain, is known to be one of the most heavy metal contaminated estuaries in the world. River contribution to the estuary of dissolved Cu, Zn, Mn, Cr, Ni, Cd, and As were analysed for the period 1988-2001. The obtained mean values show that this contribution, both because of the magnitude of total metals (895.1 kg/h), composition, toxicity (8.7 kg/h of As+Cd+Pb) and persistence, is an incomparable case in heavy metal contamination of estuaries. The amount and typology of heavy metal discharge to the Ria of Huelva are related to freshwater flow (and, consequently, to rainfall); as a result, two different types of heavy metal discharge can be distinguished in the estuary: during low water (50% of the days), with only 19.3 kg/h of heavy metals, and during high water or flood (17% of the days), where daily maximum discharge of 72,475 kg of heavy metals were recorded, from which 1481 kg were of As, 470 kg of Pb, and 170 kg of Cd. In the most frequent situation (77% of the days), the Odiel River discharges from 90% to 100% of the freshwater received by the estuary. Despite this, the high concentration of heavy metals in the Tinto River water causes this river to discharge into the Ria of Huelva 12.5% of fluvial total dissolved metal load received by the estuary.     

Quality assurance for the measurements and monitoring of radioactivity in the environment

During the Fifth Framework Programme (FP5) of the European Commission--according to an institutional programme in support to the policy of the European Commission for the implementation of Art. 35 and 36 of the Euratom Treaty as well as in the framework of the OSPAR Convention for the protection of marine environment of the north-east Atlantic--at the Institute for Transuranium Elements (ITU--General Directorate Joint Research Centre--European Commission), a reference laboratory for the measurement of radioactivity in the environment (MaRE laboratory) has been set up. In this paper, the principles and philosophy in order to improve the quality and reliability of analytical data for the measurement and monitoring of radioactivity in the environment under a quality assurance (QA) programme are presented. Examples of how a QA programme at the MaRE laboratory is developed and applied are given. Internal and external quality control (QC) programmes are also discussed.     

Radon concentrations in groundwaters of the Polish part of the Sudety Mountains (SW Poland)

In the course of researches into radon occurrence in the groundwaters of the Polish part of the Sudety Mountains, conducted in various research centres in Poland, almost 1000 radon concentration determinations have been collected. These results have given the basis for an attempt to characterise the groundwaters of this region with respect to radon content. Radon concentrations oscillated within the range of 0.2-1645 Bq/dm3, with the arithmetic mean at 240.0 Bq/dm3 and the geometric mean at 106.7 Bq/dm3. The largest number of radon concentrations found in the Sudetic groundwaters ranged between ca. 3-6 and 1000 Bq/dm3. The values over 1000 Bq/dm3 can be considered anomalously high. They constitute 3.9% of all the results and occur around six localities within different geological units of the Sudety Mountains. These are shallow circulation, low mineralised groundwaters, which outflow from gneisses and granites. In the face of the fact that from 12.8% to 72.7% (depending on the adopted norm of maximum radon concentration for drinking waters) of the examined waters cannot be drunk directly without removing at least part of the radon, and in the face of the possibility of recognizing as many as 63.5% of the waters as potentially medicinal, extensive research of radon geochemistry in the Sudety Mountains area should be urgently undertaken.     

Land Evaluation for Maize Based on Fuzzy Set and Interpolation

The objective of this article is to apply fuzzy set and interpolation techniques for land suitability evaluation for maize in Northern Ghana. Land suitability indices were computed at point observations using the Semantic Import (SI) model, whereas spatial interpolation was carried out by block kriging. Interpolated land suitability shows a high correlation (R2 = 0.87) with observed maize yield at the village level. This indicates that land suitability is closely related to maize yield in the study area. Membership functions were further used to assess the degree of limitation of land characteristics to maize. Sixty percent of the data has membership functions ranging from 0.23 for ECEC to 1.00 for drainage. ECEC, organic C, and clay are the major constraints to maize yield. The use of the fuzzy technique is helpful for land suitability evaluation, especially in applications in which subtle differences in soil quality are of a major interest. Furthermore, the use of kriging that exploits spatial variability of data is useful in producing continuous land suitability maps and in estimating uncertainties associated with predicted land suitability indices.     

Modeling flow and nitrate fate at catchment scale in Brittany (France)

In the intensive pig-farming (Sus scrofa) area of Brittany (western France), many surface and subsurface water resources are contaminated by nitrate (NO3) with concentrations that chronically exceed the European Community 50 mg L(-1) drinking standard. To ensure sustainable water supply, the fate of NO3 must be considered in both surface water and ground water. The fate of N was investigated in a Britain catchment, the Co?t-Dan watershed, with an integrated management tool: the hydrological SWAT model coupled with the ground water model MODFLOW, and its companion contaminant and solute transport model MT3DMS. The model was validated with respect to water quantity during a 6-yr period and for the NO3 concentration during a 44-mo period, at two gauging stations in the catchment. The coupled models reproduced accurately the measurements. At the basin outlet, the Nash-Sutcliffe coefficients were 0.88 for monthly flow for the entire period and 0.87 for monthly N load. Alternative scenarios were simulated and showed potential benefits of decreasing manure application from 210 to 170 kg N ha(-1) as required by the European Commission Nitrates Directive.     

Nitrous oxide emission and denitrification in chronically nitrate-loaded riparian buffer zones

Riparian buffer zones are known to reduce diffuse N pollution of streams by removing and modifying N from agricultural runoff. Denitrification, often identified as the key N removal process, is also considered as a major source of the greenhouse gas nitrous oxide (N2O). The risks of high N2O emissions during nitrate mitigation and the environmental controls of emissions have been examined in relatively few riparian zones and the interactions between controls and emissions are still poorly understood. Our objectives were to assess the rates of N2O emission from riparian buffer zones that receive large loads of nitrate, and to evaluate various factors that are purported to control N emissions. Denitrification, nitrification, and N2O emissions were measured seasonally in grassland and forested buffer zones along first-order streams in The Netherlands. Lateral nitrate loading rates were high, up to 470 g N m(-2) yr(-1). Nitrogen process rates were determined using flux chamber measurements and incubation experiments. Nitrous oxide emissions were found to be significantly higher in the forested (20 kg N ha(-1) yr(-1)) compared with the grassland buffer zone (2-4 kg N ha(-1) yr(-1)), whereas denitrification rates were not significantly different. Higher rates of N2O emissions in the forested buffer zone were associated with higher nitrate concentrations in the ground water. We conclude that N transformation by nitrate-loaded buffer zones results in a significant increase of greenhouse gas emission. Considerable N2O fluxes measured in this study indicate that Intergovernmental Panel on Climate Change methodologies for quantifying indirect N2O emissions have to distinguish between agricultural uplands and riparian buffer zones in landscapes receiving large N inputs.     

Wax perception in honeybees: contact is not necessary

In social insects, much progress has been made in identifying variations in the cuticular signatures of sexes, castes, kin and reproductive status. In contrast to this, we still do not know how the receivers perceive these recognition cues. This study was designed to investigate whether honeybees use contact-chemosensory or olfactory sensilla to perceive wax components. To answer this question in a behavioral assay, we combined classical conditioning of the proboscis extension reaction and a recently established method using zinc sulfate to selectively block antennal contact-chemosensory sensilla. Comparison of the responses to sucrose, wax and geraniol before and after antennal zinc sulfate treatment revealed that the sucrose response is lost after treatment but the responses to wax and geraniol are maintained. As sucrose is perceived by the contact-chemosensory sensilla, the retention of the wax response indicates that contact-chemosensory sensilla are not necessary for wax perception.     

Methods for collecting time/activity pattern information related to exposure to combustion products

Focus groups, surveys and questionnaires, diaries and observations can be used to gather information about people's exposure to a wide range of combustion products. Information about locations and durations of exposure, and sources of exposure can be obtained with these instruments. The types of instruments used must be fine tuned to meet the design characteristics of the community in which the study will be conducted.     

Comparative studies of health hazard from radon (Rn-222) in two selected lithologic formations in the Suwałki region (in Poland)

The aim of this work was to make a comparison of indoor radon concentrations in dwellings and in soil air in the area of two geological formations in the Suwa?ki region (Poland). The mean arithmetic airborne concentration was found to be the highest (301 Bq m (-3)) in the basements of buildings in the gravel and sand areas, whereas in the boulder clay areas it reached 587 Bq m (-3). Out of 54 measurements of radon concentrations performed at the ground floor, in eight cases concentrations were found to exceed 200 Bq m (-3) - permissible radon level in new-built houses in Poland and in three cases these values were even higher than 400 Bq m (-3). The highest radon levels were noted in houses with earthen basement floors and with direct entrance from the basement to rooms or kitchens. The mean arithmetic radon concentration in the soil air in the sandy and gravel formations was 39.7 kBq m (-3) and in clay formation it was 26.5 kBq m (-3). Higher radon levels were also found in the water obtained from household wells reaching 8367 Bq m (-3) as compared with tap water (2690 Bqm (-3)). The mean indoor concentration for the whole area under study was found to be 169.4 Bq m (-3), which is higher than the mean value for Poland (49.1 Bq m (-3)) by a factor of 3.5.