Occurrence and fate of pesticides in four contrasting agricultural settings in the United States

Occurrence and fate of 45 pesticides and 40 pesticide degradates were investigated in four contrasting agricultural settings--in Maryland, Nebraska, California, and Washington. Primary crops included corn at all sites, soybeans in Maryland, orchards in California and Washington, and vineyards in Washington. Pesticides and pesticide degradates detected in water samples from all four areas were predominantly from two classes of herbicides--triazines and chloroacetanilides; insecticides and fungicides were not present in the shallow ground water. In most samples, pesticide degradates greatly exceeded the concentrations of parent pesticide. In samples from Nebraska, the parent pesticide atrazine [6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4-diamine] was about the same concentration as the degradate, but in samples from Maryland and California atrazine concentrations were substantially smaller than its degradate. Simazine [6-chloro-N,N'-diethyl-1,3,5-triazine-2,4-diamine], the second most detected triazine, was detected in ground water from Maryland, California, and Washington. Metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide] rarely was detected without its degradates, and when they were detected in the same sample metolachlor always had smaller concentrations. The Root-Zone Water-Quality Model was used to examine the occurrence and fate of metolachlor at the Maryland site. Simulations accurately predicted which metolachlor degradate would be predominant in the unsaturated zone. In analyses of relations among redox indicators and pesticide variance, apparent age, concentrations of dissolved oxygen, and excess nitrogen gas (from denitrification) were important indicators of the presence and concentration of pesticides in these ground water systems.     

Water movement within the unsaturated zone in four agricultural areas of the United States

Millions of tons of agricultural fertilizer and pesticides are applied annually in the USA. Due to the potential for these chemicals to migrate to groundwater, a study was conducted in 2004 using field data to calculate water budgets, rates of groundwater recharge and times of water travel through the unsaturated zone and to identify factors that influence these phenomena. Precipitation was the only water input at sites in Indiana and Maryland; irrigation accounted for about 80% of total water input at sites in California and Washington. Recharge at the Indiana site (47.5 cm) and at the Maryland site (31.5 cm) were equivalent to 51 and 32%, respectively, of annual precipitation and occurred between growing seasons. Recharge at the California site (42.3 cm) and Washington site (11.9 cm) occurred in response to irrigation events and was about 29 and 13% of total water input, respectively. Average residence time of water in the unsaturated zone, calculated using a piston-flow approach, ranged from less than 1 yr at the Indiana site to more than 8 yr at the Washington site. Results of bromide tracer tests indicate that at three of the four sites, a fraction of the water applied at land surface may have traveled to the water table in less than 1 yr. The timing and intensity of precipitation and irrigation were the dominant factors controlling recharge, suggesting that the time of the year at which chemicals are applied may be important for chemical transport through the unsaturated zone.     

Coupling a 3D patch model and a rockfall module to assess rockfall protection in mountain forests

Many forests in the Alps are acknowledged for protecting objects, such as (rail) roads, against rockfall. However, there is a lack of knowledge on efficient silvicultural strategies and interventions to maintain these forests at optimal protection level. Therefore, assessment tools are required that quantify the rockfall protection effect of forest stands over time, and thereby provide the ability to evaluate the necessity and effect of management interventions. This paper introduces such a tool that consists of a 3D rockfall module embedded in the patch based forest simulator PICUS. The latter is extended for this study with a new regeneration module. In a series of experiments the new combined simulation tool is evaluated with regard to parameter sensitivity, model intercomparison experiments with recently proposed algorithms from the literature, and the ability to respond realistically to different management regimes in rockfall protection forests. Results confirm the potential of the new tool for realistic simulation of rockfall activity in heterogeneous mountain forests, but point at the urgent need to improve the knowledge base on the interaction of understory and rockfall activity. Further work will focus on model validation against empirical rockfall data, and include reduced tree vitality due to damage from boulder collisions as well as the explicit consideration of downed dead wood.     

Atrazine and alachlor transport in claypan soils as influenced by differential antecedent soil water content

Increased attention to ground water contamination has encouraged an interest in mechanisms of solute transport through soils. Few studies have investigated the effect of the initial soil water content on the transport and degradation of herbicides for claypan soils. We investigated the effect of claypan soils at initial field capacity vs. permanent wilting level on atrazine and alachlor transport. The soil studied was Mexico silt loam (fine, smectitic, mesic Aeric Vertic Epiaqualf) with a subsoil clay content, primarily montmorillonite, of >40%. Strontium bromide, atrazine, and alachlor were applied to plots; half were at field capacity (Wet treatment), and half were near the permanent wilting point (Dry treatment). Soil cores were removed at selected depths and times, and cores were analyzed for bromide and herbicide concentrations. Bromide, atrazine, and alachlor were detected at the 0.90-m depth in dry plots within 15 d after experiment initiation. Bromide was detected 0.15 m deeper (P < 0.05) in the Dry compared with the Wet treatment at 1, 7, and 60 d after application and >0.30 m deeper (P < 0.01) in the Dry treatment at 15 and 30 d after application; similar treatment results were found for atrazine and alachlor, although on fewer dates with significant differences. The mobility order of the applied chemicals was bromide > atrazine > alachlor. The atrazine apparent half-life was significantly longer in the Dry plots compared with the Wet plots. The retardation factor determined from the relative velocity of each herbicide to that of bromide was higher for alachlor than for atrazine. This study identifies the impact that shrinkage cracks have for different moisture conditions on preferential transport of herbicides in claypan soils.     

Treatment of drainage water with industrial by-products to prevent phosphorus loss from tile-drained land

Tile drained land with phosphorus (P)-rich topsoil is prone to P loss, which can impair surface water quality via eutrophication. We used by-products from steel and energy industries to mitigate P loss from tile drains. For each by-product, P sorption maximum (P(max)) and strength (k) were determined, while a fluvarium trial assessed P uptake with flow rate. Although two ash materials (fly ash and bottom ash) had high P(max) and k values, heavy metal concentrations negated their use in the field. The fluvarium experiment determined that P uptake with by-products was best at low flow, but decreased at higher flow in proportion to k. A mixture of melter slag (<10 mm) and basic slag (high P(max), 7250 mg kg(-1); and k, 0.508 L mg P(-1)) was installed as backfill in eight drains on a dairy farm. Four drains with greywacke as backfill were constructed for controls. The site (10 ha) had P-rich topsoil (Olsen P of 64 mg kg(-1)) and yielded a mean dissolved reactive P (DRP) and total P (TP) concentration from greywacke backfilled drains of 0.33 and 1.20 mg L(-1), respectively. In contrast, slag backfilled drains had DRP and TP concentrations of 0.09 and 0.36 mg L(-1), respectively. Loads of DRP and TP in greywacke drains (0.45 and 1.92, respectively) were significantly greater (P < 0.05) than those from slag drains (0.18 and 0.85, respectively). Data from a farm where melter slag was used as a backfill suggested that slag would have a life expectancy of about 25 yr. Thus, backfilling tile drains with melter slag and a small proportion of basic slag is recommended as an effective means of decreasing P loss from high P soils.     

Nutrient dynamics and tree growth of silvopastoral systems: impact of poultry litter

Fertilizing pastures with poultry litter has led to an increased incidence of nutrient-saturated soils, particularly on highly fertilized, well drained soils. Applying litter to silvopastures, in which loblolly pine (Pinus taeda L.) and bahiagrass (Paspalum notatum) production are integrated, may be an ecologically desirable alternative for upland soils of the southeastern USA. Integrating subterranean clover (Trifolium subterraneum) into silvopastures may enhance nutrient retention potential. This study evaluated soil nutrient dynamics, loblolly pine nutrient composition, and loblolly pine growth of an annually fertilized silvopasture on a well drained soil in response to fertilizer type, litter application rate, and subterranean clover. Three fertilizer treatments were applied annually for 4 yr: (i) 5 Mg litter ha(-1) (5LIT), (ii) 10 Mg litter ha(-1) (10LIT), and (iii) an inorganic N, P, K pasture blend (INO). Litter stimulated loblolly pine growth, and neither litter treatment produced soil test P concentrations above runoff potential threshold ranges. However, both litter treatments led to accumulation of several nutrients (notably P) in upper soil horizons relative to INO and unfertilized control treatments. The 10LIT treatment may have increased N and P leaching potential. Subterranean clover kept more P sequestered in the upper soil horizon and conferred some growth benefits to loblolly pine. Thus, although these silvopasture systems had a relatively high capacity for nutrient use and retention at this site, litter should be applied less frequently than in this study to reduce environmental risks.     

Relationships between street characteristics and perceived attractiveness for walking reported by elderly people

Walking is important for the health of elderly people. Previous studies have found a relationship between neighbourhood characteristics, physical activity and related health aspects. The multivariate linear regression model presented here describes the relationships between the perceived attractiveness of streets for walking along and (physical) street characteristics. Two hundred and eighty-eight independently living elderly people (between 55 and 80 years old) participated in the study. Street characteristics were assessed along homogeneous street subsections defined as ‘links’. Positively related to perceived attractiveness of links were the following street characteristics: slopes and/or stairs, zebra crossings, trees along the route, front gardens, bus and tram stops, shops, business buildings, catering establishments, passing through parks or the city centre, and traffic volume. Litter on the street, high-rise buildings, and neighbourhood density of dwellings were negatively related to perceived link attractiveness. Overall, the results suggest that three main aspects affect perceived attractiveness of streets for walking, namely tidiness of the street, its scenic value and the presence of activity or other people along the street. The results are discussed within the context of these three aspects.     

Monitoring Contrasting Land Management in the Savanna Landscapes of Northern Australia

We compared measures of ecosystem state across six adjacent land-tenure groups in the intact tropical savanna landscapes of northern Australia. Tenure groups include two managed by Aboriginal owners, two national parks, a cluster of pastoral leases, and a military training area. This information is of relevance to the debate about the role of indigenous lands in the Australian conservation estate. The timing and frequency of fire was determined by satellite imagery; the biomass and composition of the herb-layer and the abundance of large feral herbivores by field surveys; and weediness by analysis of a Herbarium database. European tenures varied greatly in fire frequencies but were consistently burnt earlier in the dry season than the two Aboriginal tenures, the latter having intermediate fire frequencies. Weeds were more frequent in the European tenures, whilst feral animals were most abundant in the Aboriginal tenures. This variation strongly implies a signature of current management and/or recent environmental history. We identify indices suitable for monitoring of management outcomes in an extensive and sparsely populated landscape. Aboriginal land offers a unique opportunity for the conservation of biodiversity through the maintenance of traditional fire regimes. However, without financial support, traditional practices may prove unsustainable both economically and because exotic weeds and feral animals will alter fire regimes. An additional return on investment in Aboriginal land management is likely to be improved livelihoods and health outcomes for these disadvantaged communities.     

Effects of Riparian Vegetation and Watershed Urbanization on Fishes in Streams of the Mid‐Atlantic Piedmont (USA)1

Abstract: The joint influences of riparian vegetation and urbanization on fish assemblages were analyzed by depletion sampling in paired forested and nonforested reaches of 25 small streams along an urbanization gradient. Nonforested reaches were narrower than their forested counterparts, so densities based on surface area differ from linear densities (based on reach length). Linear densities (based on number or biomass of fish) of American eel, white sucker and tesselated darter, and the proportion of biomass of benthic invertivores were significantly higher in nonforested reaches, while linear densities of margined madtom and the number of pool species were significantly higher in forested reaches. Observed riparian effects may reflect differences in habitat and algal productivity between forested and nonforested reaches. These results suggest that relatively small‐scale riparian restoration projects can affect local geomorphology and the abundance of fish. Dense vegetative cover in riparian zones and similar or analogous habitats in both forested and nonforested reaches, the relatively small scale of the nonforested reaches, and the low statistical power to detect differences in abundance of rare species may have limited the observed differences between forested and nonforested reaches. There was a strong urbanization gradient, with reductions of intolerant species and increases of tolerant species and omnivores with increasing urbanization. Interactions between riparian vegetation type and urbanization were found for blacknose dace, creek chub, tesselated darter, and the proportion of biomass of lithophilic spawners. The study did not provide consistent support for the hypotheses that responses of fish to riparian vegetation would be overwhelmed by urban degradation or insignificant at low urbanization.     

Effects of Flow Augmentations in the Snake River Basin on Farms Profitability1

Abstract: For over 10 years, several species of salmon have been identified as either threatened or endangered in the Snake River Basin of Idaho. The United States Bureau of Reclamation, in cooperation with the National Marine Fisheries Service, has proposed a variety of plans to increase stream flows in the Snake River Basin to facilitate movement by juvenile salmon smolts to the ocean. This research examines two of the flow augmentation plans proposed by the Bureau of Reclamation as well as two alternative plans, one founded purely on existing priority‐based water rights and another geared toward minimizing the effects of flow augmentations on farms profitability. Results from a basin‐wide model of agricultural production in the Snake River Basin, the Snake River Agricultural Model, present evidence that (1) older water rights are used towards production of less valuable crops, (2) flow augmentation scenarios have unequal effects on farms profitability across agricultural regions within the basin, and (3) irrigation water is valued from US$4 to US$59 an acre‐foot.