Production and growth of microalgae in urine and wastewater: A review

Environmental Chemistry Letters - Issues of climate change, energy demand, and natural resources depletion are calling for circular methods to produce value-added products such as biomass, biofuel,...     

Analysing land cover changes for understanding of forest dynamics using temporal forest management plans

This study analyses forest dynamics and land use/land cover change over a 43-year period using spatial-stand-type maps of temporal forest management plans of Karaisal? Forest Enterprise in the Eastern Mediterranean Region of Turkey. Stand parameters (tree species, crown closures and developmental stages) of the dynamics and changes caused by natural or artificial intervention were introduced and mapped in a Geographic Information System (GIS) and subjected to fragmentation analysis using FRAGSTATS. The Karaisal? Forest Enterprise was first planned in 1969 and then the study area was planned under the Mediterranean Forest Use project in 1991 and five-term forest management plans were made. In this study, we analysed only four periods (excluding 1982 revision plans): 1969, 1991, 2002 and 2012. Between 1969 and 2012, overall changes included a net increase of 3,026 ha in forested areas. Cumulative forest improvement accounted for 2.12 % and the annual rate of total forest improvement averaged 0.08 %. In addition, productive forest areas increased from 36,174 to 70,205 ha between 1969 and 2012. This translates into an average annual productive forest improvement rate of 1.54 %. At the same time, fully covered forest areas with crown closure of “3” (>70 %) increased about 21,321 ha, and young forest areas in developmental stage of “a” (diameter at breast height (dbh)?<?8 cm) increased from 716 to 13,305 ha over the 43-year study period. Overall changes show that productive and fully covered forest areas have increased egregiously with a focus on regenerated and young developmental stages. A spatial analysis of metrics over the 43-year study period indicated a more fragmented landscape resulting in a susceptible forest to harsh disturbances.     

Monitoring forest structure at landscape level: a case study of Scots pine forest in NE Turkey

This study aims to investigate the change in spatial-temporal configuration of secondary forest succession and generate measurements for monitoring the changes in structural plant diversity in Yaln?zçam Scots pine forest in NE Turkey from 1972 to 2005. The successional stages were mapped using the combination of Geographic Information System (GIS), Global Positioning System (GPS), aerial photos and high resolution satellite images (IKONOS). Forest structure and its relationship with structural plant diversity along with its changes over time were characterized using FRAGSTATS. In terms of spatial configuration of seral stages, the total number of fragments increased from 572 to 735, and mean size of patch (MPS) decreased from 154.97 ha to 120.60 ha over 33 years. The situation resulted in forestation serving appropriate conditions for plant diversity in the area. As an overall change in study area, there was a net increase of 1823.3 ha forest during the period with an average annual forestation rate of 55.25 ha year^?1(0.4% per year). In conclusion, the study revealed that stand type maps of forest management plans in Turkey provide a great chance to monitor the changes in structural plant diversity over time. The study further contributes to the development of a framework for effective integration of biodiversity conservation into Multiple Use Forest Management (MUFM) plans using the successional stages as a critical mechanism.     

Monitoring of bisphenol A diglycidyl ether (BADGE) and some derivatives in fish products in the Turkey market

The exposure to bisphenols and their derivatives was assessed in 33 fish products sold in Turkey using high-performance liquid chromatography-tandem mass spectrometry (LC–MS/MS). BADGE was determined in only four samples at concentrations ranging between 0.06 and 0.22 mg/kg. As the most abundant bisphenol groups, BADGE-hydrolyzed products such as BADGE·H₂O and BADGE·2H₂O were present in nine and fourteen samples in the range between 0.06–0.16 and 0.06–0.72 mg/kg, respectively. The total concentration of BADGE and hydrolyzed products was below the specific migration limit (SML) value of 9 mg/kg food, which in the European Union stated as tolerable. Chlorinated derivatives of BADGE were detected in fewer samples compared with hydrolyzed ones. BADGE·H₂O·HCl was the predominant migrant among chlorinated derivatives and was present in seven samples in a range between 0.02 and 0.06 mg/kg. All other samples contained less than or equal to 0.03 mg/kg of BADGE·HCl and BADGE·2HCl. The sum of these derivatives was lower than the SML value (1 mg/kg) of BADGE chlorohydrins legislated by the European Union. Besides these migrants, the analyzed samples did not contain any BFDGE and 3R-NOGE, which are prohibited in manufacturing food contact materials.

     

Biomonitoring of bisphenol A, 4-nonylphenol,and 4-t-octylphenol in Turkish population: exposure and risk assessment

Environmental Science and Pollution Research - Biomonitoring studies are important tools to understand the effects of endocrine-disrupting compounds on human health. Up to now, there have been no...     

Nickel and Cadmium Concentrations in Plasma and Na+/K+ATPase Activities in Erythrocyte Membranes of the People Exposed to Cement Dust Emissions

The aim of this study was to determine the concentrations of nickel and cadmium in blood plasma of the people exposed to cement dust emissions and to investigate the effects of exposure period on the activities of Na⁺/K⁺ ATPase enzymes in their erythrocyte membranes. The study was carried out on people living in Eskiehir Çukurhisar rural area, located near a cement factory. Blood samples of the individuals residing in this area were taken from 80subjects (30 for control) following a physical examination. The analysis of plasma samples showed that nickel concentrations in subject group were found to be significantly higher than those of the control group (p < 0.001). Cadmium concentrations were found to be within the reference values for both group and no difference was found between the subjects and controls (p > 0.05). Furthermore, no correlation was observed between the levels of Na⁺/K⁺ ATPase activity in erythrocyte membranes of the subject group and the ages of people living in the region (p > 0.05, r = 0.133). It was also observed that nickel concentrations increased by age (p < 0.001, r = 0.646) while no effect was observed in means of cadmium. Na⁺/K⁺ ATPase activities in the erythrocyte membranes were not affected.In conclusion although there was no difference between the Na⁺/K⁺ ATPase activity in means of age, there was an environmental pollution and may be it was due to the industrial plant.     

Removal of 2, 4‐D from aqueous solution by the adsorbents from spent bleaching earth

Abstract

The removal of 2, 4‐D (2, 4‐ dichlorophenoxyacetic acid) from aqueous solutions by activated spent bleaching earths (SBE) was studied at 20 °C. Experiments were performed as a function of time, initial concentration, dose and particle size of the adsorbent. The Langmuir and Freundlich adsorption equations were fitted by the adsorption data obtained. The values of Langmuir and Freundlich constants were determined. The adsorption kinetic was found to follow Lagergren equation. Both the boundary layer and intraparticle diffusion played important roles in the adsorption rate of 2, 4‐D. As the size of the adsorbent increased, the time to reach equilibrium increased but adsorption capacity decreased.     

Assessing implications of land use and land cover changes in forest ecosystems of NE Turkey

Monitoring land use and land cover change (LUCC) and understanding forest cover dynamics is extremely important in sustainable development and management of forest ecosystems. This study analyzed the spatial and temporal pattern of LUCC in the Yaln?zçam and U?urlu forest planning units which are located in the northeast corner of Turkey. The investigation also evaluates the temporal changes of the spatial structure of forest conditions through the spatial analysis of forest-cover type maps from 1972 and 2005 using geographical information systems and FRAGSTATS^TM. As an overall change between 1972 and 2005, there was a net increase of 1,823 ha in forested areas, and cumulative forest improvement accounted for 2.06 %. In terms of spatial configuration, the landscape structure in the study area changed substantially over the 33-year study period, resulting in fragmentation of the landscape as indicated by large patch numbers and smaller mean patch sizes, owing to heavy grazing, illegal cutting, and uncontrolled stand treatments.     

Assessing the effects of land use changes on soil sensitivity to erosion in a highland ecosystem of semi-arid Turkey

There has been increasing concern in highlands of semiarid Turkey that conversion of these systems results in excessive soil erosion, ecosystem degradation, and loss of sustainable resources. An increasing rate of land use/cover changes especially in semiarid mountainous areas has resulted in important effects on physical and ecological processes, causing many regions to undergo accelerated environmental degradation in terms of soil erosion, mass movement and reservoir sedimentation. This paper, therefore, explores the impact of land use changes on land degradation in a linkage to the soil erodibility, RUSLE-K, in Cankiri–Indagi Mountain Pass, Turkey. The characterization of soil erodibility in this ecosystem is important from the standpoint of conserving fragile ecosystems and planning management practices. Five adjacent land uses (cropland, grassland, woodland, plantation, and recreational land) were selected for this research. Analysis of variance showed that soil properties and RUSLE-K statistically changed with land use changes and soils of the recreational land and cropland were more sensitive to water erosion than those of the woodland, grassland, and plantation. This was mainly due to the significant decreases in soil organic matter (SOM) and hydraulic conductivity (HC) in those lands. Additionally, soil samples randomly collected from the depths of 0–10 cm (D ₁) and 10–20 cm (D ₂) with irregular intervals in an area of 1,200 by 4,200 m sufficiently characterized not only the spatial distribution of soil organic matter (SOM), hydraulic conductivity (HC), clay (C), silt (Si), sand (S) and silt plus very fine sand (Si + VFS) but also the spatial distribution of RUSLE-K as an algebraically estimate of these parameters together with field assessment of soil structure to assess the dynamic relationships between soil properties and land use types. In this study, in order to perform the spatial analyses, the mean sampling intervals were 43, 50, 64, 78, 85 m for woodland, plantation, grassland, recreation, and cropland with the sample numbers of 56, 79, 72, 13, and 69, respectively, resulting in an average interval of 64 m for whole study area. Although nugget effect and nugget effect–sill ratio gave an idea about the sampling design adequacy, the better results are undoubtedly likely by both equi-probable spatial sampling and random sampling representative of all land uses.     

Appraisal of methane production and anaerobic fermentation kinetics of livestock manures using artificial neural networks and sinusoidal growth functions

This study aimed to perform a comparative analysis of the performance of five models (Gompertz, logistic, Richards, the first-order, artificial neural networks) in predicting methane production rate from anaerobic digestion of livestock manures. The input variables were fermentation time, digestion temperature, biogas temperature, ambient temperature, pH, and specific biogas production rate. The physicochemical compositions of cow manure and sheep manure showed that volatile solid (VS) contents were close to each other in manure compositions (77.6% and 64.7%, respectively), while the potential of methane production from cow manure (673.44 mL CH₄/g VS) was greater than that from sheep manure (320.32 mL CH₄/g VS). The determination coefficients (R²) for logistic function, Gompertz, Richards, the first-order, and ANN models were obtained as 0.968, 0.967, 0.975, 0.825, and 0.995 for the cow manure, respectively. In case of the sheep manure, the R² values obtained from these models were 0.976, 0.979, 0.981, 0.968 and 0.991, respectively. Although the determination coefficients of all models were in satisfactory agreement with the experimental data, the ANN model showed competitive lower RMSE values of 0.111 and 0.164 for cow and sheep manure data sets, respectively, indicating its superior performance than other models.