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391.
Seepage from Hg mine wastes and calcines contains high concentrations of mercury (Hg). Hg pollution is a major environmental
problem in areas with abandoned mercury mines and retorting units. This study evaluates factors, especially the hydrological and
sedimentary variables, governing temporal and spatial variation in levels and state of mercury in streams impacted by Hg contaminated
runo . Samples were taken during di erent flow regimes in theWanshan Hg mining area in Guizhou Province, China. In its headwaters
the sampled streams/rivers pass by several mine wastes and calcines with high concentration of Hg. Seepage causes serious Hg
contamination to the downstream area. Concentrations of Hg in water samples showed significant seasonal variations. Periods of
higher flow showed high concentrations of total Hg (THg) in water due to more particles being re-suspended and transported. The
concentrations of major anions (e.g., Cl??, F??, NO3?? and SO4
2??) were lower during higher flow due to dilution. Due to both sedimentation
of particles and dilution from tributaries the concentration of THg decreased from 2100 ng/L to background levels (< 50 ng/L) within
10 km distance downstream. Sedimentation is the main reason for the fast decrease of the concentration, it accounts for 69% and 60%
for higher flow and lower flow regimes respectively in the upper part of the stream. Speciation calculation of the dissolved Hg fraction
(DHg) (using Visual MINTEQ) showed that Hg(OH)2 associated with dissolved organic matter is the main form of Hg in dissolved
phase in surface waters in Wanshan (over 95%). 相似文献
392.
Soonchul Kwon Maohong Fan Herbert F. M. DaCost Armistead G. Russell 《环境科学学报(英文版)》2011,23(8):1233-1239
Olivine, one of the most abundant minerals existing in nature, is explored as a CO2 carbonation agent for direct carbonation of
CO2 in flue gas. Olivine based CO2 capture is thermodynamically favorable and can form a stable carbonate for long-term storage.
Experimental results have shown that water vapor plays an important role in improving CO2 carbonation rate and capacities. Other
operation conditions including reaction temperature, initial CO2 concentration, residence time corresponding to the flow rate of CO2
gas stream, and water vapor concentration also considerably affect the performance of the technology. 相似文献
393.
Meeta Lavani Priyangshu M. Sarm Ajoy K. Man Simrita Cheem Banwari La 《环境科学学报(英文版)》2011,23(8):1394-1402
We compared the efficacy of a natural biocide with four chemical tetrakishydroxymethyl phosphonium sulfonate, benzyl trimethyl
ammonium chloride, and formaldehyde, glutaraldehyde, to control microbial induced corrosion in oil pipelines. The efficacy of biocides
were monitored against Desulfovibrio vulgaris and Desulfovibrio gigas in experimental pipes by measuring cell counts, H2S production,
Fe(II) production, production of extracellular polymeric substances and structure of biofilm. The treatment with cow urine had minimum
planktonic cell counts of 3 102 CFU/mL as well as biofilm cell counts of 9 101 CFU/mL as compared with tetrakishydroxyl methyl
phosphonium sulfonate, benzyl trimethyl ammonium chloride, formaldehyde and glutaraldehyde. Sulfide production was the lowest
with cow urine (0.08 mmol/L), followed by tetrakishydroxymethyl phosphonium sulfonate 0.72 mmol/L. On day 90 of treatment,
Fe(II) production was also found to be the lowest with cow urine. The scanning electron microscopic studies indicated that the biofilm
bacteria were killed by cow urine. These results demonstrate the cow urine mediated control of microbially induced corrosion, and this
is indicative of its potential as a viable substitute of toxic biocides. To the best of our knowledge, this seems to be the first report which
screens possible biocidal activity by cow urine as compared to the most common biocides which oil industry is currently using. 相似文献
394.
2012年1月~2012年12月采集乌鲁木齐大气PM2.5样品,使用质粒DNA评价法研究了不同季节PM2.5的氧化能力,并进行氧化性毒性与相应气象因素和质量浓度之间的相关性研究.结果表明,乌鲁木齐大气PM2.5的质量浓度具有冬季最高,春季和秋季次之,夏季最低的季节性变化特征;PM2.5全样和水溶部分氧化能力的季节差异较大,对质粒DNA的氧化性损伤具有冬季最大,春季和夏季之次,秋季最低.冬、春、夏、秋季大气PM2.5全样的TD30(PM2.5对质粒DNA造成破坏达到30%所需要的颗粒物的剂量)平均值分别为440,491,503,515μg/mL,水溶部分分别为474,721,666,600μg/mL.绝大部分PM2.5样品全样的TD30值均小于水溶部分样,表明全样的毒性大于相应的水溶部分样.全样TD30值与平均温度显著(P<0.05)正相关,表明寒冷的天气/季节可能造成PM2.5的高毒性.水溶样TD30值与风速显著(P<0.01)正相关,与相对湿度显著负相关.这表明,高的风速和低的相对湿度可能跟较低和较高的PM2.5的毒性有关.PM2.5氧化性损伤能力的大小与其质量浓度之间的相关性不明显,表明仅以颗粒物的质量浓度来评价大气颗粒物氧化性损伤能力大小的方法并不能真实地反映其对人体健康的危害程度,起决定作用的还是颗粒物的化学组成及其表面吸附的有害成分. 相似文献
395.
Evaluation of accuracy of linear regression models in predicting urban stormwater discharge characteristics 总被引:1,自引:0,他引:1
Stormwater runoff has been identified as a source of pollution for the environment, especially for receiving waters. In order to quantify and manage the impacts of stormwater runoff on the environment, predictive models and mathematical models have been developed. Predictive tools such as regression models have been widely used to predict stormwater discharge characteristics. Storm event characteristics, such as antecedent dry days (ADD), have been related to response variables, such as pollutant loads and concentrations. However it has been a controversial issue among many studies to consider ADD as an important variable in predicting stormwater discharge characteristics. In this study, we examined the accuracy of general linear regression models in predicting discharge characteristics of roadway runoff. A total of 17 storm events were monitored in two highway segments, located in Gwangju, Korea. Data from the monitoring were used to calibrate United States Environmental Protection Agency's Storm Water Management Model (SWMM). The calibrated SWMM was simulated for 55 storm events, and the results of total suspended solid (TSS) discharge loads and event mean concentrations (EMC) were extracted. From these data, linear regression models were developed. R2 and p-values of the regression of ADD for both TSS loads and EMCs were investigated. Results showed that pollutant loads were better predicted than pollutant EMC in the multiple regression models. Regression may not provide the true effect of site-specific characteristics, due to uncertainty in the data. 相似文献
396.
Mengnjo J. Wirmvem Takeshi Oh Wilson Y. Fantong Samuel N. Ayonghe Jonathan N. Hogarh Justice Y. Suil Asobo Nkengmatia E. Asaah Seigo Ooki Gregory Tanyileke Joseph V. Hell 《环境科学学报(英文版)》2014,26(4):801-809
Rainwater characteristics can reveal emissions from various anthropogenic and natural sources into the atmosphere. The physico-chemical characteristics of 44 monthly rainfall events (collected between January and December 2012) from 4 weather stations (Bamenda, Ndop plain, Ndawara and Kumbo) in the Bamenda Highlands (BH) were investigated. The purpose was to determine the sources of chemical species, their seasonal inputs and suitability of the rainwater for drinking. The mean pH of 5 indicated the slightly acidic nature of the rainwater. Average total dissolved solids (TDS) were low (6.7 mg/L), characteristic of unpolluted atmospheric moisture/air. Major ion concentrations (mg/L) were low and in the order K+ 〉 Ca2+ 〉 Mg2~ 〉 Na+ for cations and NO3 〉〉 HCO3 〉 SO] 〉 CI- 〉 PO3- 〉 F- for anions. The average rainwater in the area was mixed Ca-Mg-SO4-CI water type. The CI-/Na+ ratio (1.04) was comparable to that of seawater (1.16), an indication that N a+ and CI originated mainly from marine (Atlantic Ocean) aerosols. High enrichments of Ca2+, Mg2+ and SO2- to Na+ ratios relative to seawater ratios (constituting 44% of the total ions) demonstrated their terrigenous origin, mainly from Saharan and Sahelian arid dusts. The K+/Na+ ratio (2.24), which was similar to tropical vegetation ash (2.38), and NO3 was essentially from biomass burning. Light (〈 100 mm) pre-monsoon and post-monsoon convective rains were enriched in major ions than the heavy (〉 100 mm) monsoon rains, indicating a high contribution of major ions during the low convective showers. Despite the acidic nature, the TDS and major ion concentrations classified the rainwater as potable based on the WHO guidelines. 相似文献
397.
The nitrogen changes and the nitrogen mass balance in a free water surface flow constructed wetland (CW) using the four-year monitoring data from 2008 to 2012 were estimated. The CW was composed of six cells in series that include the first settling basin (Cell 1), aeration pond (Cell 2), deep marsh (Cell 3), shallow marsh (Cell 4), deep marsh (Cell 5) and final settling basin (Cell 6). Analysis revealed that the NH4+-N concentration decreased because of ammonification which was then followed by nitrification. The NO4+-N and NO4+-N were also further reduced by means of microbial activities and plant uptake during photosynthesis. The average nitrogen concentration at the influent was 37,819 kg/year and approximately 45% of that amount exited the CW in the effluent. The denitrification amounted to 34% of the net nitrogen input, whereas the accretion of sediment was only 7%. The biomass uptake of plants was able to retain only 1% of total nitrogen load. In order to improve the nutrient removal by plant uptake, plant coverage in four cells (i.e., Cells 1, 3, 4 and 5) could be increased. 相似文献
398.
不同添加剂对铅冶炼污染石灰性土壤的修复及土壤性质的影响研究 总被引:2,自引:2,他引:0
探讨了污水处理厂脱水污泥、枯草和磷矿粉对受铅冶炼污染的石灰性土壤(全Pb、Cd、Zn含量分别为2337、21.4、486 mg·kg-1,DTPA提取态Pb、Cd、Zn含量分别为1035、14.5、68.7 mg·kg-1)中重金属的稳定效果及对土壤性质的影响.其中,污泥和枯草均按200 g·kg-1(干重)的用量施用,磷矿粉按n(P)∶n(Pb)=2∶1比例施用,培养80 d.研究结果表明,单独施用污泥可使土壤DTPA-Pb含量降低18.0%(p0.05),并可显著降低土壤pH,增加土壤氮、磷有效性和电导率、DTPA-Cd、DTPA-Zn含量,其中,DTPA-Cd、DTPA-Zn含量增加比例均达到10%以上.单独施用枯草可使土壤DTPA-Pb含量降低10.7%(p0.05),土壤有机质含量增加26.4%(p0.05),对土壤其它性状影响较小.磷矿粉单独施用时对土壤性质影响较小.与污泥单独施用相比,磷矿粉与污泥配合施用时,可使土壤DTPA-Cd含量降低11.9%. 相似文献
399.
为探讨纳米Fe0粒子对产乙烯脱卤菌群脱氯性能和物种多样性的影响,采用纳米Fe0粒子与产乙烯脱卤菌群联合脱氯,并通过气相色谱、PCR-DGGE和TEM等技术手段进行相关表征.结果表明:当纳米Fe0粒子浓度为0~0.50 g·L-1时,体系的脱氯速率提高较小,低于40%,且菌种数量无明显变化;当其浓度为0.50~1.00 g·L-1时,体系的脱氯速率由0.31μmol·h-1提高到0.77μmol·h-1,体系的脱氯速率提高了60%,部分DGGE条带消失,多样性减少.TEM结果显示,产乙烯脱卤拟球菌在与纳米Fe0粒子接触部位有轻度破损,但细胞没有破裂.纳米Fe0粒子浓度较高时对产乙烯脱卤菌群的脱氯有明显的促进作用,但会使产乙烯脱卤菌群物种多样性减少. 相似文献
400.
钙、氯对磷酸盐稳定污染土壤中铅的促进作用研究 总被引:1,自引:0,他引:1
为探讨促进磷酸盐稳定污染土壤中铅的方法,在全铅含量为517 mg·kg-1的铅冶炼污染土壤中加入5 mmol·kg-1磷酸盐,同时加入10mmol·kg-1硝酸钙或5 mmol·kg-1氯化钾,在15%或30%的含水率下培养40 d,之后种植黑麦草.结果表明,与单独施用磷酸盐相比,采用磷酸盐与钙、氯结合或增加培养期间的土壤含水率后,土壤DTPA-Pb含量下降3.92%~26.1%;对于同一添加剂处理,培养期间土壤含水率从15%增加到30%,土壤有效铅(DTPA-Pb)含量下降8.83%~24.4%.增加土壤含水率后,土壤有效磷(Olsen-P)含量均显著升高(p0.05).土壤铅的EXAFS分析表明,与未施用磷酸盐的对照相比,土壤中加入磷酸盐后矿物态铅的比例由57%上升至81%,加施钙、氯或增加土壤含水率后,多数处理矿物态铅的比例有所下降,而有机结合态铅比例上升.与对照相比,污染土壤中施用磷酸盐后,植物产量大幅增加,但施用钙、氯或增加培养期间含水率后,部分处理植物产量有所下降.以上结果表明,在铅冶炼污染土壤中加入磷酸盐时,加入钙、氯或者增加土壤含水率均有利于铅的稳定,但以上措施可能对植物生长产生不利影响. 相似文献