Landfill leachate treatment by electrochemical oxidation

This study investigated the electrochemical oxidation of stabilized leachate from Pulau Burung semi-aerobic sanitary landfill by conducting laboratory experiments with sodium sulfate Na₂SO₄ (as electrolyte) and graphite carbon electrodes. The control parameters were influent COD, current density and reaction time, while the responses were BOD removal, COD removal, BOD:COD ratio, color and pH. Na₂SO₄ concentration was 1 g/L. Experiments were conducted based on a three-level factorial design and response surface methodology (RSM) was used to analyze the results. The optimum conditions were obtained as 1414 mg/L influent COD concentration, 79.9 mA/cm² current density and 4 h reaction time. This resulted in 70% BOD removal, 68% COD removal, 84% color removal, 0.04 BOD/COD ratio and 9.1 pH. Electrochemical treatment using graphite carbon electrode was found to be effective in BOD, COD and color removal but was not effective in increasing the BOD/COD ratio or enhancing biodegradability of the leachate. The color intensity of the treated samples increased at low influent COD and high current density due to corrosion of electrode material.     

Ozonation of metoprolol in aqueous solution: ozonation by-products and mechanisms of degradation

This study investigated the degradation pathway of metoprolol, a widely used β-blocker, in the ozonation via the identification of generated ozonation by-products (OPs). Structure elucidation of OPs was performed using HPLC coupled with quadrupole time-of-flight high-resolution mass spectrometry. Seven OPs were identified, and four of these have not been reported elsewhere. Identified OPs of metoprolol included aromatic ring breakdown by-products; aliphatic chain degraded by-products and aromatic ring mono-, di-, and tetrahydroxylated derivatives. Based on the detected OPs, metoprolol could be degraded through aromatic ring opening reaction via reaction with ozone (O₃) and degradation of aliphatic chain and aromatic ring via reaction with hydroxyl radical (?OH).     

Kinetic studies of the degradation of parabens in aqueous solution by ozone oxidation

Ozone degradation of a mixture containing methylparaben, ethylparaben, propylparaben, butylparaben and benzylparaben was carried out in aqueous solution. The degradation followed the pseudo-first-order kinetic model and occurs with two ozonation stages with the observed rate constants of second stage ozonation, k _obs2, being higher than the observed rate constants in first stage, k _obs1. The k _obs1 of parabens was found to increase exponentially whilst k _obs2 was found to maximize at 35°C. Both k _obs1 and k _obs2 were found to decrease exponentially with respect to the initial concentration of parabens. Both pH and ozone dose showed positive effects on the rate of degradation. It was also observed that an ozone dose of 0.67 g/h resulted in the removal of 99% of parabens in 12 min, and also the removal of 61 and 32% of chemical oxygen demand (COD) and total organic carbon (TOC), respectively, in 3 h of ozonation time for a 500 μM of solution of parabens.     

Development of shopping centres in Jeddah

Recently developed shopping centres have become one of the main features of shopping activities in Jeddah. In fact the city of Jeddah experienced a surprising increase in the development of shopping centres during the last decade. Developers entered the land development process with the intention of realising profits from a long‐term investment, but a considerable number of shopping centres were developed on the basis of insufficient or no feasibility studies thereby underestimating or neglecting expected rate of return and occupancy. Spatially, shopping centres present distinctive spatial and rental value patterns. This article is concerned with explaining the supply side of shopping centres by examining the development process through which they were built. The analytical framework is based on discussing the interaction of three sets of variables: contextual factors, including land policy and market mechanisms; site characteristics, and the developer's characteristics.     

Can machines recognise stress in plants?

In this paper we show that chlorophyll a fluorescence signals analysed with the self-organizing map (SOM) can be used as a routine tool for the monitoring and classification of pea varieties (Pisum sativum) according to their degree of resistance against drought stress. Fluorescence kinetics measurements were obtained from non-stressed plants. The aim of this study is to evaluate the applicability of artificial intelligence techniques in eco-physiological research. Our goal is to provide a fast tool that will contribute to the knowledge needed to develop strategies that would help to decrease the impact of environmental stress in agriculture and forestry.     

Evaluation of the effectiveness of low frequency workpiece vibration in deep-hole micro-EDM drilling of tungsten carbide

The application of micro-electrical discharge machining (micro-EDM) in deep-hole drilling is still limited due to the difficulty in flushing of debris and unstable machining. Present study introduces a simplistic analytical model to evaluate the effectiveness of low frequency workpiece vibration during the micro-EDM drilling of deep micro-holes. In addition, experimental investigation has been conducted to validate the model by studying the effects of workpiece vibration on machining performance, surface quality and dimensional accuracy of the micro-holes. The effect of vibration frequency and amplitude for three different settings of aspect ratios has been studied experimentally. Moreover, the vibration experiments have been conducted at different levels of gap voltages and capacitances in order to understand the effect of electrical parameters and effectiveness of low-frequency workpiece-vibration at different levels of discharge energies. It has been shown analytically that the effectiveness of low frequency workpiece vibration during micro-EDM drilling can be evaluated by a parameter ‘K_v’ (ratio of maximum acceleration of the vibrating plate in gravitational direction to gravitational acceleration ‘g’), which can be determined from the vibration frequency, amplitude and phase angle of the vibrating workpiece. The theoretical model reveals that for K_v > 1, the position of debris particles will be above the workpiece; thus can be flushed away from machined zone effectively. The experimental reasons for improved micro-EDM drilling performance at the setting of K_v > 1 are found to be the increased effective discharge ratio, reduced short-circuits and improved dielectric flushing. The experimental results also reveal that the low frequency vibration is more effective at the low discharge energy level, thus making it more suitable for micro-EDM. Considering the effect on both the machining characteristics and micro-hole accuracy parameters, vibration frequency of 750 Hz and amplitude of 1.5 μm was found to provide improved performance for the developed vibration device.     

Ecotoxicological assessment of oil-based paint using three-dimensional multi-species bio-testing model: pre- and post-bioremediation analysis

The present study validates the oil-based paint bioremediation potential of Bacillus subtilis NAP1 for ecotoxicological assessment using a three-dimensional multi-species bio-testing model. The model included bioassays to determine phytotoxic effect, cytotoxic effect, and antimicrobial effect of oil-based paint. Additionally, the antioxidant activity of pre- and post-bioremediation samples was also detected to confirm its detoxification. Although, the pre-bioremediation samples of oil-based paint displayed significant toxicity against all the life forms. However, post-bioremediation, the cytotoxic effect against Artemia salina revealed substantial detoxification of oil-based paint with LD₅₀ of 121 μl ml^?1 (without glucose) and >?400 μl ml^?1 (with glucose). Similarly, the reduction in toxicity against Raphanus raphanistrum seeds germination (%FG?=?98 to 100%) was also evident of successful detoxification under experimental conditions. Moreover, the toxicity against test bacterial strains and fungal strains was completely removed after bioremediation. In addition, the post-bioremediation samples showed reduced antioxidant activities (% scavenging?=?23.5?±?0.35 and 28.9?±?2.7) without and with glucose, respectively. Convincingly, the present multi-species bio-testing model in addition to antioxidant studies could be suggested as a validation tool for bioremediation experiments, especially for middle and low-income countries.

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Green examination: integration of technology for sustainability

The recent development of infrastructure all around the world has resulted in an increasing trend of online examination in universities. The paper is an approach in theory and practical aimed at analyzing the feasibility of sustainable examination in four universities and its environmental impact reducing the paper use terming it as green examination. The paper studied the integration of sustainability through the use of computers and technology in the examination of the universities viz. King Khalid University (KKU), Saudi Arabia, Integral University (IU), India, Aligarh Muslim University (AMU), India, and The Hague University (HU), The Netherlands. The study has analyzed the trend of paper requirement, paper utilized and paper wasted in all the four universities. The environmental impact resulting from reduced paper use has been also analyzed. The feasibility of e-examination, its implementation and the implications has been undertaken in the study. The study concludes that the e-examination can almost make the examinations paperless and feasible in the four universities.     

Shell disturbances and butyltins burden in commercial bivalves collected from the Bizerta lagoon (northern Tunisia)

Shell disturbances and soft tissues butyltin burden were investigated in commercial bivalves Lithophaga lithophaga, Mytilus galloprovincialis, Solen marginatus and Crassostrea gigas from the Bizerta lagoon. Shell disturbances were found in all bivalves, being scarce in S. marginatus. In the internal valve of L. lithophaga, burrowing annelids and sipunculids living inside galleries were observed, while in the external valve, brown-blackish or white stains were found. In M. galloprovincialis, a yellowish mass located at the shell anterior side was found fixed firmly to the pearly layer by a hard brownish structure covering some annelid elliptic eggs. In the internal shell layer of some specimens collected in April, embryos belonging to tubiculous annelids at various developmental stages were observed. In C. gigas, shell thickening was revealed in some specimens corresponding to white doughy deposits at the internal valve and between shell layers. In S. marginatus, only one specimen showing a cavity at the posterior site was found. Total butyltin concentrations in the studied bivalves varied between 30 and 245?ng/g dry weight with tributyltin (TBT) being the predominant compound. The highest concentration was recorded in L. lithophaga collected from the Bizerta Bay and the lowest concentration in S. marginatus from Maghraoua. This study provided baseline data that could serve for long-term monitoring of TBT pollution in Tunisia, since legislation to reduce the use of TBT-based antifouling paints has not been introduced yet.     

Nested numerical scheme in a polar coordinate shallow water model for the coast of Bangladesh

This study is concerned with the development of storm surge model to predict water level accurately due to surge associated with a cyclone along the coast of Bangladesh. Considering the funnel shape of the Bay of Bengal, coastal bending and the existence of off-shore islands, a vertically integrated model in cylindrical polar coordinate system is developed using nested numerical scheme. A fine mesh scheme capable of incorporating coastal bending and offshore islands properly in the numerical scheme is nested into a coarse mesh scheme covering up to 15° N latitude of the Bay of Bengal. The developed model is used to estimate water levels at different coastal and island stations associated with a few storms that hit the coast of Bangladesh. The computed surge levels compared well with observed ones and predicted surge levels investigated with different approaches.