Statistical analysis and isotherm study of uranium biosorption by <Emphasis Type="Italic">Padina</Emphasis> sp. algae biomass

Introduction  

The application of response surface methodology is presented for optimizing the removal of U ions from aqueous solutions using Padina sp., a brown marine algal biomass.     

Hexachlorocyclohexane (HCH) as new Stockholm Convention POPs��a global perspective on the management of Lindane and its waste isomers

Purpose

Hexachlorocyclohexane (HCH) isomers (??-, ??- and ??- (Lindane)) were recently included as new persistent organic pollutants (POPs) in the Stockholm Convention, and therefore, the legacy of HCH and Lindane production became a contemporary topic of global relevance. This article wants to briefly summarise the outcomes of the Stockholm Convention process and make an estimation of the amount of HCH waste generated and dumped in the former Lindane/HCH-producing countries.

Results

In a preliminary assessment, the countries and the respective amount of HCH residues stored and deposited from Lindane production are estimated. Between 4 and 7 million tonnes of wastes of toxic, persistent and bioaccumulative residues (largely consisting of alpha- (approx. 80%) and beta-HCH) are estimated to have been produced and discarded around the globe during 60 years of Lindane production. For approximately 1.9 million tonnes, information is available regarding deposition. Countries are: Austria, Brazil, China, Czech Republic, France, Germany, Hungary, India, Italy, Japan, Macedonia, Nigeria, Poland, Romania, Slovakia, South Africa, Spain, Switzerland, Turkey, The Netherlands, UK, USA, and former USSR. The paper highlights the environmental relevance of deposited HCH wastes and the related POPs?? contaminated sites and provides suggestions for further steps to address the challenge of the legacy of HCH/Lindane production.

Conclusion

It can be expected that most locations where HCH waste was discarded/stockpiled are not secured and that critical environmental impacts are resulting from leaching and volatilisation. As parties to the Stockholm Convention are legally required to take action to stop further POPs pollution, identification and evaluation of such sites are necessary.     

Molecular characterization of conjugative plasmids in pesticide tolerant and multi-resistant bacterial isolates from contaminated alluvial soil

A total of 35 bacteria from contaminated soil (cultivated fields) near pesticide industry from Chinhat, Lucknow, (India) were isolated and tested for their tolerance/resistance to pesticides, heavy metals and antibiotics. Bacterial isolates were identified by 16S rDNA sequencing. Gas Chromatography analysis of the soil samples revealed the presence of lindane at a concentration of 547 ng g⁻¹ and α-endosulfan and β-endosulfan of 422 ng g⁻¹ and 421 ng g⁻¹ respectively. Atomic Absorption Spectrophotometry analysis of the test sample was done and Cr, Zn, Ni, Fe, Cu and Cd were detected at concentrations of 36.2, 42.5, 43.2, 241, 13.3 and 11.20 mg kg⁻¹ respectively. Minimum inhibitory concentrations of all the isolates were determined for pesticides and heavy metals. All the multi-resistant/tolerant bacterial isolates were also tested for the presence of incompatibility (Inc) group IncP, IncN, IncW, IncQ plasmids and for rolling circle plasmids of the pMV158-family by PCR. Total community DNA was extracted from pesticide contaminated soil. PCR amplification of the bacterial isolates and soil DNA revealed the presence of IncP-specific sequences (trfA2 and oriT) which was confirmed by dot blot hybridization with RP4-derived DIG-labelled probes. Plasmids belonging to IncN, IncW and IncQ group were neither detected in the bacterial isolates nor in total soil DNA. The presence of conjugative or mobilizable IncP plasmids in the isolates indicate that these bacteria have gene transfer capacity with implications for dissemination of heavy metal and antibiotic resistance genes. We propose that IncP plasmids are mainly responsible for the spread of multi-resistant bacteria in the contaminated soils.     

Hybrid Composites Made from Oil Palm Empty Fruit Bunches/Jute Fibres: Water Absorption,Thickness Swelling and Density Behaviours

In this research, hybrid composite materials were prepared from combination of oil palm Empty fruit bunches (EFB) fibre and jute fibre as reinforcement, epoxy as polymer matrix. This study intended to investigate the effect of jute fiber hybridization and different layering pattern on the physical properties of oil palm EFB-Epoxy composites. Water absorption and thickness swelling test reveal that hybrid composite shows a moderate water absorption which is 11.20% for hybrid EFB/Jute/EFB composite and 6.08% for hybrid Jute/EFB/Jute composite. The thickness swelling and water absorption of the hybrid composites slightly increased as the layering pattern of hybrid composites changed. Hybrid composites are more water resistance and dimensional stable compare to the pure EFB composites. This is attributed to the more hydrophilic nature of EFB composites. Hybridization of oil palm EFB composites with jute fibres can improve the dimensional stability and density of pure EFB and Jute fibre reinforced composites has higher density of 1.2 g/cm³ compared to all other composites.     

Removal of antibiotics from aqueous solutions by nanoparticles: a systematic review and meta-analysis

Environmental Science and Pollution Research - Antibiotics, as one of the emerging pollutants, are non-biodegradable compounds and long-term exposure to them may affect endocrine, hormonal, and...     

The effects of using reprocessable material on the durability and mechanical properties of landfill leachate collection HDPE pipes

This paper investigated the durability and mechanical properties of landfill leachate collection HDPE pipes which had been made of different weight percent amounts of virgin and reprocessable HDPE compounds (VC and RC). Durability is reported base on the chemical properties, obtained through oxidative induction time (OIT) and melt flow index (MFI) measurements, at the temperature of 50 °C and over a period of 12 months immersion in a synthetic leachate. Mechanical properties are also described according to tensile and pressure tests which had been conducted on the pipes samples. All of the factors were examined had been affected by the addition of RC, but for the special combination the antioxidant depletion was significantly affected by the experimental aging condition and no important changes had been observed in the other pipe properties. The results from OIT tests indicate that the rate of antioxidant depletion is reduced by an increase in the weight percent amounts of RC, during the experimental aging condition. This reduction is probably attributed to the extraction of antioxidants from RC in their recovery process. Finally, although these results are related to the particular HDPE compound, antioxidant formulation and condition examined, but it can be said that the use of clean own reprocessable material for the production of landfill leachate pipes shall be permitted without limitations.     

Preparation and Fundamental Characterization of Cellulose Nanocrystal from Oil Palm Fronds Biomass

The objective of this work was to isolate cellulose nanocrystal (CNC) from oil palm fronds (Elaeis guineensis) and its subsequent characterization. Isolation involves sodium hydroxide/anthraquinone pulping with mechanical refining followed by total chlorine free bleaching (includes oxygen delignification, hydrogen peroxide oxidation and peracetic acid treatment) before acid hydrolysis. Bleaching significantly decreased kappa number and increased α-cellulose percentage of fibers as confirmed by Technical Association of the Pulp and Paper Industry standards. Transmission electron microscopy (TEM), X-ray diffraction, Fourier transform infrared spectroscopy and thermogravimetric analysis revealed that acid hydrolysis along with bleaching improved crystallinity index and thermal stability of the extracted nanocrystals. It was observed that CNC maintained its cellulose 1 polymorph despite hydrolysis treatment. Mean diameter as observed by TEM and average fiber aspect ratio of obtained CNC was 7.44 ± 0.17 nm and 16.53 ± 3.52, respectively making it suitable as a reinforcing material for nanocomposite.     

Optimal temporal scale for the correlation of AOD and ground measurements of PM2.5 in a real-time air quality estimation system

Aerosol optical depth (AOD), an indirect estimate of particulate matter using satellite observations, has shown great promise in improving estimates of PM_2.5 (particulate matter with aerodynamic diameter less than or equal to 2.5 μm) surface. Currently, few studies have been conducted to explore the optimal way to apply AOD data to improve the model accuracy of PM_2.5 in a real-time air quality system. We believe that two major aspects may be worthy of consideration in that area: 1) an approach that integrates satellite measurements with ground measurements in the estimates of pollutants and 2) identification of an optimal temporal scale to calculate the correlation of AOD and ground measurements. This paper is focused on the second aspect, identifying the optimal temporal scale to correlate AOD with PM_2.5. Five following different temporal scales were chosen to evaluate their impact on the model performance: 1) within the last 3 days, 2) within the last 10 days, 3) within the last 30 days, 4) within the last 90 days, and 5) the time period with the highest correlation in a year. The model performance is evaluated for its accuracy, bias, and errors based on the following selected statistics: the Mean Bias, the Normalized Mean Bias, the Root Mean Square Error, Normalized Mean Error, and the Index of Agreement. This research shows that the model with the temporal scale: within the last 30 days, displays the best model performance in a southern multi-state area centered in Mississippi using 2004 and 2005 data sets.     

Fluoride removal by a continuous flow electrocoagulation reactor

Long-term consumption of water containing excessive fluoride can lead to fluorosis of the teeth and bones. Electrocoagulation (EC) is an electrochemical technique, in which a variety of unwanted dissolved particles and suspended matter can be effectively removed from an aqueous solution by electrolysis. Continuous flow experiments with monopolar aluminium electrodes for fluoride removal were undertaken to investigate the effects of the different parameters such as: current density (12.5-50A/m(2)), flow rate (150-400 mL/min), initial pH (4-8), and initial fluoride concentration (5-25mg/L). The highest treatment efficiency was obtained for the largest current and the removal efficiency was found to be dependent on the current density, the flow rate and the initial fluoride concentration when the final pH ranged between 6 and 8. The composition of the sludge produced was analysed using the X-ray diffraction (XRD) spectrum. The strong presence of the aluminium hydroxide [Al(OH)(3)] in the above pH range, which maximizes the formation of aluminium fluoride hydroxide complex [Al(n)F(m)(OH)(3n-m)], is the main reason for defluoridation by electrocoagulation. The results obtained showed that the continuous flow electrocoagulation technology is an effective process for defluoridation of potable water supplies and could also be utilized for the defluoridation of industrial wastewater.     

On-line production of ferrate with an electrochemical method and its potential application for wastewater treatment – A review

A number of studies on the oxidation of various organic/inorganic contaminants by ferrate(VI) were reported in the 1980s and 1990s. The exploration of the use of ferrate(VI) for water and wastewater treatment has been well addressed recently. However, challenges have existed for the implementation of ferrate(VI) technology in practice due to the instability of a ferrate solution or high production cost of solid ferrate products. The research has been carried out aiming at the generation and application of ferrate(VI) in situ. This paper thus reviews ferrate chemistry and its overall performance as a water treatment chemical, discusses the factors affecting the ferrate yield efficiency using the electrochemical method, and finally, summarises the work on the production and use of ferrate in situ which is currently under study.