Studies on bound 14C-prometryn residues in soil and plants

A high-temperature distillation technique was developed for determining and chemically identifying the bound (nonextractable) residues of ¹⁴C-prometryn in an organic soil and plants. A considerable portion of the bound ¹⁴C residues in the incubated organic soil was identified as prometryn. These residues were absorbed by plants grown in the soil. Hono-and di-$\text{N}$-dealkylated metabolites of prometryn were present in the plant bound ¹⁴C residues and a major portion of bound residues as associated with lignin. Soil-bound ¹⁴C residues were also released from soil by microbes. The bound ¹⁴C residues in soil were associated with humin, humic acid, and fulvic acid fractions. Thermoanalytical methods were used to obtained information on the nature and location of ¹⁴C bound residues in soil and humic materials.     

Lipid peroxidation and antioxidant enzyme activity in different organs of mice exposed to low level of mercury

The effects of mercuric chloride (Hg) on lipid peroxidation (LPO), glutathione reductase (GR), glutathione peroxidase (GPx), superoxide dismutase (SOD) and glutathione (GSH) levels in different organs of mice (CD-1) were evaluated. Mice were exposed (2 days/week) to 0.0 (control), 0.8 (low) and 8.0 (mid) and 80.0 (high) gHg/kg/day for 2 weeks. The high dose group was excluded from the study due to high mortality. LPO levels in kidney, testis and epididymus at low and mid doses; GR and GPx levels in testis at mid dose; SOD levels in brain and testis at both doses, liver and epididymus at mid dose; GSH levels in testis at both doses were significantly increased compared to their controls. However, the GR levels in kidney at both doses and in epididymus at mid dose; GPx levels in kidney and epididymus and SOD levels in kidney at both the doses; GSH levels in epididymus at mid dose were significantly decreased compared to their control. Body weight gain and food efficiency were significantly reduced (p<0.05) in mid dose. These results indicated that Hg treatment enhanced LPO in all tissues, but showed significant enhancement only in kidney, testis and epididymus suggesting that these organs were more susceptible to Hg toxicity. The increase in antioxidant enzyme levels in testis could be a mechanism protecting the cells against reactive oxygen species.     

Dissolution characteristics of 226Ra from phosphogypsum

The paper presents the results of the dissolution characteristics of 226Ra from phosphogypsum, a by-product from phosphate fertilizer industries. Leachability of 226Ra in distilled water and rainwater have been examined under different leaching conditions such as contact time, solid:liquid ratio and simulating natural conditions. The concentration of 226Ra activity in the leachates ranged from 0.07 to 0.53 Bq l(-1). Study indicated that leaching of radium may be slow in field conditions near the phosphogypsum stock piles.     

DETERMINATION OF AQUIFER PARAMETERS USING REGRESSION ANALYSIS1

ABSTRACT: Transmissivity and storativity of an aquifer are usually determined by analysis of steady or nonsteady pumping test data. The classical methods of nonsteady pumping test analysis are mostly graphical in nature and are, therefore, subject to errors of judgment in curve fitting, interpolating, and reading graphs and charts. A method is described here which does not require construction of graphs or use of charts and tables. The transmissivity and the storativity are calculated using regression analysis of the nonsteady time drawdown field data. The calculations can readily be performed on a hand held calculator. The procedure is described using four examples, and the results are compared with those obtained from graphical techniques. It is shown that the method is a viable alternative to the type curve solution of Theis or Straight line solution of Jacob for nonleaky artesian aquifers. However, the regression method poses problem in the cases of leaky artesian and water table aquifers.     

Flammability Properties of Virgin and Recycled Polycarbonate (PC) and Acrylonitrile–Butadiene–Styrene (ABS) Recovered from End-of-Life Electronics

Acrylonitrile–Butadiene–Styrene (ABS), Polycarbonate (PC) and their alloys are widely used in automotive industry, computer and equipment housings. With increasing disposal of end-of-life electronic equipment, there is also an increased demand for recycling of these materials so that they do not pose environmental challenge as solid waste. One of the recycling approaches is mechanical recycling of these thermoplastics where recycled plastic is melt blended with virgin materials to obtain a high quality product. Besides obtaining desirable mechanical properties, such blends should also conform to fire safety standards. In this work, a series of blends were prepared using PC and ABS recovered from discarded computers and virgin materials using a twin-screw extruder. Their flammability properties were evaluated using burner flammability tests and Ohio State University (OSU) release rate tests. It was found that the extinguishing time, burning extent and weight loss appears to progressively decrease with the addition of both virgin or recycled PC to virgin or recycled ABS. It was also seen that the addition of the 70% of PC, virgin or recycled, to ABS virgin or recycled, appears to significantly decrease heat release and smoke evolution. The results of this study indicate that recycled polycarbonate can be used as an additive for virgin or recycled ABS, as a means of giving flame resistance to ABS in high-value applications. This result is significant when related to the result obtained by a separate study indicating that up to 25% of recycled material can be used without degradation of mechanical properties in the presence of 15% short glass fiber reinforcement.     

Conceptualizing Sustainability: Simulating Concrete Possibilities in an Imperfect World

This paper uses a cultural model approach to interpret and analyse the impact of an interactive computer simulation tool (GB-Quest) on the possibility of fostering dialogue about sustainability in southwestern British Columbia, Canada. We define cultural models theory, compare cultural models to mental models and illustrate some basic features of cultural models. We then describe the research process in which participants engaged in conversation, guided and facilitated by GB-Quest, about sustainability. Findings suggest that the use of cultural models frameworks reinforces participants' understanding of sustainability. In reflecting on their prior models of sustainability, we argue that study participants can elucidate how cognitive conceptual resources reflect publicly shared knowledge (Turner, 2004).     

Effects of Rainfall and Ground‐Water Pumping on Streamflow in Mākaha,O’ahu,Hawai’i1

Abstract: Land‐use/land‐cover changes in Mākaha valley have included the development of agriculture, residential dwellings, golf courses, potable water supply facilities, and the introduction of alien species. The impact of these changes on surface water and ground water resources in the valley is of concern. In this study, streamflow, rainfall, and ground‐water pumping data for the upper part of the Mākaha valley watershed were evaluated to identify corresponding trends and relationships. The results of this study indicate that streamflow declined during the ground‐water pumping period. Mean and median annual streamflow have declined by 42% (135 mm) and 56% (175 mm), respectively, and the mean number of dry stream days per year has increased from 8 to 125. Rainfall across the study area appears to have also declined though it is not clear whether the reduction in rainfall is responsible for all or part of the observed streamflow decline. Mean annual rainfall at one location in the study area declined by 14% (179 mm) and increased by 2% (48 mm) at a second location. Further study is needed to assess the effect of ground‐water pumping and to characterize the hydrologic cycle with respect to rainfall, infiltration, ground‐water recharge and flow in the study area, and stream base flow and storm flow.     

Shifting regime shifted policy—interplay of interests in sustainability discourses of forest land use

This study investigates the influence of policy interests on resource sustainability. Information on ‘colonial interest’ of the British regime and the ‘commercial interest’ of the post-colonial regimes on forest land use of Bangladesh have been drawn on to show the interplay of interests on sustainability impacts. The findings show that both colonial and commercial interests have caused intensification of forest land use for production of economic crops like teak (Tectona grandis) and cash crops like tea (Camellia sinensis), cotton (Gossypium herbaceum and G. arboreum) and tobacco (Nicotiana tabacum). The ‘colonial interest’ has also initiated the dispute of ownership, rights and tenure of forest land and resources. The post-colonial regimes have utilized colonial legacy as the privilege for implementing ‘commercial interests’. In both the cases traditional interests of people were disregarded. As a result, peoples’ participation in forestry was discouraged and the sustainability of forest land use was impeded.     

Water resources management strategy for adaptation to droughts in China

Water Scarcity and drought are recurrent phenomena in China. In the context of environmental change, an increasing tendency in drought frequency and severity is observed in China in recent years. Therefore, it is imperative to take necessary initiatives to reduce the impacts of drought. In this paper, an attempt is made to identify the best water management strategies to cope with droughts. For this objective the records of historical droughts and their impacts in China over the period of 1950?C2009 are analyzed. It is observed that the drought affected area has increased nearly by 12 folds and the drought damaged area has increased by about 22 times in China in last 60?years. Over 87,000 reservoirs were built with a total water storage capacity of about 7,064 billion m³ to cope with droughts. However, this structural supply-based management strategy was not enough to meet the increasing water demand caused by rapid economic development and population growth. A typical relationship between socio-economic development and water resources management strategy to attain sustainability in water management is developed in this study. The relationship shows that the demand-side water management strategies can be the best option to meet the challenges posed by increased severity of drought, population growth, economic development and possible climate change. The concept is later verified through the analysis of changing pattern of water consumptions by different sectors in last 60?years.     

Biochemical and histopathological ultrastructural changes caused by ZnO nanoparticles in mice

Five week-old mice were divided into a vehicle control group, and groups exposed to ZnO nanoparticles at low (0.5 g/kg), middle (1 g/kg), high (3 g/kg), and exceptionally high-dose (5 g/kg). After the first, second, third, and fourth weeks’ of exposure, blood biochemistry, histopathology, and electron microscopic ultrastructural changes in liver, kidney and spleen were investigated. Increased alkaline phosphatase activities were observed in all treated mice being statistically significant at higher dose. No changes were observed in the serum glutamic pyruvic transaminase, serum glutamic oxaloacetic transaminase, creatinine, blood urea nitrogen, and lipid levels. During the first and second weeks of the treatment, effects on the cytoarchitecture of liver, kidney, and spleen were not perceived while during the third and fouth weeks of treatment sporadic mild effects were seen. Ultrastructural electron microscopic changes in liver, kidney, and spleen were not observed for the low-dose group on the first, second, third, and fourth weeks, suggesting that exposure to ZnO nanoparticles at low dose is safe. Long-term (i.e., more than 28 days) exposure to the exceptionally high-dose resulted in sporadic changes in nuclear chromatin condensation, irregular nuclear membrane, polymorphic mitochondria, mitochondrial swelling, and vacuolation. ZnO nanoparticles could be well tolerated and no death occurred in any group of treated mice.