Metal mobility during in situ chemical oxidation of TCE by KMnO4

The potential for trace-metal contamination of aquifers as a side effect of In Situ Chemical Oxidation (ISCO) of chlorinated solvent contamination by KMnO(4) is investigated with column experiments. The experiments investigate metal mobility during in situ chemical oxidation of TCE by KMnO(4) under conditions where pH, flow rate, KMnO(4), TCE, and trace-metal concentrations were controlled. During ISCO, the injection of MnO(4) creates oxidizing conditions, and acidity released by the reactions causes a tendency toward low pH in aquifers. In order to evaluate the role of pH buffering on metal mobility, duplicate columns were constructed, one packed with pure silica sand, and one with a mixture of silica sand and calcite. Aqueous solutions of TCE and KMnO(4) (with 1 mg/L Cu, Pb, Zn, Mo, Ni, and Cr(VI)) were allowed to mix at the inlet to the columns. After the completion of the experiments, samples of Mn oxide were removed from the columns and analyzed by analytical scanning and transmission electron microscopy. In order to relate the results of the laboratory experiments to field settings, the analyses of Mn-oxide samples from the lab experiments were compared to samples of Mn oxide collected from a field-scale chemical-oxidation experiment that were also analyzed by analytical electron microscopy as well as time-of-flight secondary-ion mass spectroscopy. The pH ranged from 2.40 in the silica sand column to 6.25 in the calcite-containing column. The data indicate that aqueous Mo, Pb, Cu and Ni concentrations are attenuated almost completely within the columns. In contrast, Zn concentrations are not significantly attenuated and Cr(VI) is transported conservatively. The results indicate that within the range 2.40 to 6.25, metal mobility is not affected by pH. Comparison of analyses of Mn-oxide from the lab and field demonstrate that a variety of metals are sequestered from solution by Mn oxide.     

Pharmaceutical compound removal efficiency by a small constructed wetland located in south Brazil

Environmental Science and Pollution Research - The fate of pharmaceuticals during the treatment of effluents is of major concern since they are not completely degraded and because of their...     

MATHEMATICAL MODELING OF VEGETATIVE IMPACTS FROM FLUCTUATING FLOOD POOLS1

ABSTRACT: A flood control reservoir protects valuable developments on the downstream flood plain by storing flood waters and releasing them at a rate that will reduce the downstream damage. The water surface level of the flood pool behind the dam can fluctuate considerably during the occurrence of a large magnitude flood causing severe impacts on shoreline vegetation and water based recreation facilities located in the flood pool. A mathematical simulation model describing shoreline vegetative succession in response to flooding is presented. Plant species are grouped into ecologically similar compartments. Differential equations describing compartment intrinsic growth, intraspecies competition, interspecies competition, and other growth limiting factors are solved numerically. The model is used to evaluate the impacts of various operating policies on plant succession for a new reservoir in Central Iowa.     

Managing post-conflict demolition wastes in Gaza Strip: a case study on May 2021 conflict

Gaza Strip is considered as one of the armed conflicts prone areas in Middle East. Several intensive conflicts occurred in Gaza Strip in 2008, 2012, 2014 and 2021. These conflicts caused massive destroying the infrastructures, facilities, and buildings, which affected all services and activities in Gaza Strip. One of the major post-conflict issues in Gaza strip is the management of resulted demolition waste including its removal, sorting, recycling, and material recovery. In May 2021, over than 370,000 tons of demolition waste composed of rubbles and debris was generated during 11 days of armed conflict. The accumulated previous experience of rubbles and debris removal and recycling in Gaza Strip supported to perform a quick management approach for safe removal of the post-conflict demolition waste and reuse/recycle the resulted waste materials in various applications. The sorting and transporting process of concreate and non-concreate rubble elements of the waste were carried out in cooperation between local and international agencies as emergency recovery-funded projects. The most proportion of rubbles are concrete aggregates, thus, the material recovery was conducted through crushing process for concrete rubbles and then reusing it for road rehabilitation or producing concrete building blocks. The large concrete blocks reused to be placed for shoreline protection for specific area along Gaza beach. The recycling of post-conflict demolition waste management projects in Gaza Strip brought economic and social benefits through the reuse and recycle of resources and creation of job opportunities. In conclusion, although the post-conflict demolition waste management is quite different from municipal/industrial waste management in Gaza Strip, it is conducted through applying similar techniques of disaster waste management in waste removal, and those of construction and demolition (C&D) waste management in sorting, crushing, and sieving for recycling.

     

PVC and PET microplastics in caddisfly (Lepidostoma basale) cases reduce case stability

Environmental Science and Pollution Research - Caddisfly larvae occur in streams and rivers, and many caddisfly species build protective cases using material from their habitat such as sand grains....     

Comparing the Adoption of Contaminated Land Remediation Technologies in the United States,United Kingdom,and China

In many locations across the world, land contamination poses a serious threat to human health and the wider environment. For instance, a report published on April 17, 2014, revealed that China now has 16.1 percent of its land contaminated by various organic and inorganic contaminants, posing a range of challenges from human health risk to food security. The innovation and adoption of suitable remediation technologies is critical for solving land contamination issues. However, little is known about the pattern of remediation technology adoption, as well as its determining factors. This study uses a questionnaire survey in the United States, United Kingdom, and China to examine the spatial variation of remediation technology adoption. It further explores the temporal trend of remediation technology adoption using secondary data from the U.S. Superfund program. The study identified significant differences in remediation technology adoption among these countries, which are attributed to the different environmental, social, economic, and regulatory contexts. It is argued that the full implications of remediation technology adoption to sustainable development should be further studied, and policy instruments should be designed accordingly to promote those remediation technologies that align the best with long‐term sustainability. Technology developers may also use these implications to adjust their research and development priorities. © 2014 Wiley Periodicals, Inc.     

Zinc and cobalt phytoextraction by different plant species

Plant species sorghum (Sorghum vulgar L.), clover (Trifolium pratense L.), panikum (Panicum antidotal), and canola (Brassica napus) were tested to determine their phytoremediation potential. After a period of about 90 days, plant samples (shoots and roots) and soil samples (before and after cultivation) were collected for zinc and cobalt analyses using atomic absorption spectrometry. The highest zinc uptake was observed in canola, while panikum grass showed a high zinc accumulation affinity compared to sorghum and clover. Calculation of the recovery percentage, based on the amount of zinc removed from the soil after cultivation, ranged between 12.8 and 36.3 percent of the total initial zinc. Canola shoots exhibited the highest cobalt uptake compared to the other plant species. Calculation of the recovery percentage based on cobalt removed from the soil after cultivation ranged between 10.1 and 40.7 percent of the total initial cobalt concentration. © 2007 Wiley Periodicals, Inc. *

1 This article is a U.S. Government work and, as such, is in the public domain of the United States of America.

     

Standardising and mapping open-source information for crisis regions: the case of post-conflict Iraq

Painting an accurate picture of the situation on the ground in countries in crisis is vital for the efficiency of humanitarian aid and reconstruction agencies. This study describes a method for standardising and mapping the plethora of open-source information. The test site for the study is post-conflict Iraq. Important information on aid distribution, reconstruction and security in Iraq can be derived from the reports of humanitarian aid agencies and the media, before being formatted, inserted into a database and mapped. The product is a visual, cartographic structure of otherwise random information, showing which organisations are working in the country, which thematic and geographic areas are being prioritized in the field, and which areas most frequently experience security events. This type of mapping not only highlights the overall working environment within different parts of the country, but it may also serve as a decision-making tool for donors and humanitarian aid agencies planning to deploy personnel.