Xenobiotics removal by adsorption in the context of tertiary treatment: a mini review

Many xenobiotics, including several pharmaceuticals and pesticides, are poorly treated in domestic wastewater treatment plants. Adsorption processes, such as with activated carbons, could be a solution to curb their discharge into the aquatic environment. As adsorbent-like activated carbon is known to be expensive, identifying promising alternative adsorbent materials is a key challenge for efficient yet affordable xenobiotic removal from wastewaters. As part of the effort to address this challenge, we surveyed the literature on pharmaceutical and pesticide xenobiotics and built a database compiling data from 38 scientific publications covering 65 xenobiotics and 58 materials. Special focus was given to the relevance and comparability of the data to the characteristics of the adsorbent materials used and to the operating conditions of the batch tests inventoried. This paper gives an in-depth overview of the adsorption capacities of various adsorbents. The little data on alternative adsorbent materials, especially for the adsorption of pharmaceuticals, makes it difficult to single out any one activated carbon alternative capable of adsorbing pesticides and pharmaceuticals at the tertiary stage of treatment. There is a pressing need for further lab-scale experiments to investigate the tertiary treatment of discharged effluents. We conclude with recommendations on how future data should best be used and interpreted.     

Copolymerization of 2,4-dichlorophenol with humic substances by oxidative and photo-oxidative biomimetic catalysis

We evaluated the catalytic activity of a water-soluble iron-porphyrin in an oxidative coupling reaction to form covalent bonds between 2,4-dichlorophenol (2,4-DCP) and humic molecules. The biomimetic catalysis in the presence of H₂O₂ was tested in the dark and in daylight, and changes in reaction products were revealed by high-performance liquid chromatography (HPLC) and nuclear magnetic resonance (NMR) spectroscopy. In all conditions, iron-porphyrin was effective in promoting complete disappearance of 2,4-DCP, although catalyst activity was enhanced in daylight (with a maximum turnover number of 85.13). Further evidence of the occurred covalent coupling between 2,4-DCP and humic molecules was revealed by diffusion-ordered nuclear magnetic resonance (DOSY-NMR) spectroscopy that showed a reduced diffusivity of 2,4-DCP after the catalytic reaction. These findings indicate that iron-porphyrin is an efficient catalyst for the covalent binding of polyhalogenated phenols to humic molecules, thereby suggesting that the copolymerization reactions may become a useful technology to remediate soils and waters contaminated by halogenated phenols and their analogues.     

Effect of dung deposition on small-scale patch structure and seasonal vegetation dynamics in mountain pastures

Cattle activity greatly influences plant species composition and biomass production of grassland ecosystems. Dung deposition by cattle together with grazing and trampling can be considered as one of the important factors driving vegetation dynamics in pastures. The objective of this study was to investigate at 10-cm and 1-month resolution the plant community dynamics induced by dung deposition in two plant communities (a mesotrophic and an oligotrophic grassland) in a pasture of the Swiss Jura Mountains. Vegetation was sampled four or three times during the vegetation period in contiguous 10 cm × 10 cm quadrats from the centre of the dung pat to a distance of 60 cm. A lower grazing intensity near the dung pat was recorded for all observation periods. In the mesotrophic grassland the canopy was higher near the dung pat already one week after dung deposition. Vegetation around dung pats was submitted to two opposite fertilizing and grazing gradients, which induced changes in vegetation texture and structure at fine scale and short term. We observed a positive rank correlation between species turnover and distance to the dung for both communities, suggesting a seasonal stabilizing effect of dung on the plant composition of their direct surroundings (0–10 cm) likely due to cattle avoidance. Since dung pats are dropped every year in different locations, they create in the pasture a shifting mosaic of nutrient availability and grazing intensity inducing at seasonal scale micro-successions in plant communities.     

Four priorities for new links between conservation science and accounting research

Article impact statement: New collaborations with accounting research can improve conservation impact of ecosystem-based information systems.     

Amazonian Tree Mortality during the 1997 El Niño Drought

Abstract: In 1997, the Amazon Basin experienced an exceptionally severe El Niño drought. We assessed effects of this rare event on mortality rates of trees in intact rain forest based on data from permanent plots. Long-term (5- to 13-year) mortality rates averaged only 1.12% per year prior to the drought. During the drought year, annual mortality jumped to 1.91% but abruptly fell back to 1.23% in the year following El Niño. Trees dying during the drought did not differ significantly in size or species composition from those that died previously, and there was no detectable effect of soil texture on mortality rates. These results suggest that intact Amazonian rainforests are relatively resistant to severe El Niño events.     

A link between eumelanism and calcium physiology in the barn owl

In many animals, melanin-based coloration is strongly heritable and is largely insensitive to the environment and body condition. According to the handicap principle, such a trait may not reveal individual quality because the production of different melanin-based colorations often entails similar costs. However, a recent study showed that the production of eumelanin pigments requires relatively large amounts of calcium, potentially implying that melanin-based coloration is associated with physiological processes requiring calcium. If this is the case, eumelanism may be traded-off against other metabolic processes that require the same elements. We used a correlative approach to examine, for the first time, this proposition in the barn owl, a species in which individuals vary in the amount, size, and blackness of eumelanic spots. For this purpose, we measured calcium concentration in the left humerus of 85 dead owls. Results showed that the humeri of heavily spotted individuals had a higher concentration of calcium. This suggests either that plumage spottiness signals the ability to absorb calcium from the diet for both eumelanin production and storage in bones, or that lightly spotted individuals use more calcium for metabolic processes at the expense of calcium storage in bones. Our study supports the idea that eumelanin-based coloration is associated with a number of physiological processes requiring calcium.     

The effects of sport fishing growth on behavior of commercial fishermen in Balbina reservoir, Amazon, Brazil

An important alternative for sustainable use of tucunaré stocks and improvement in fishermen welfare in Balbina reservoir, Central Amazon, would be to train commercial fisherman to also become tourist guides for sport fishing. In this study, we modeled fishermen response to this question, in order to evaluate the acceptance of such an idea. Thus, we surveyed 47 fishermen, who currently comprise approximately 75% of the total fishermen population. This survey was implemented during December of 2001 and January of 2002. We used a probity analysis to run two models. The first model includes the variables: family size, school level, fishing time, residence time and boat ownership. On the other hand, the second model includes the number of children under and above eight years old but not the family size. Both models are significant and the most relevant variables are: fishing time (years of participation of fisherman is in the activity) and residence time (length of residency of particular fishermen live at the village nearby the reservoir).     

Indicators for sustainable energy development: Brazil's case study

This article summarizes the results of the project on indicators for sustainable energy development (ISED) in Brazil. The project's aim was to present energy related economic, social and environmental data to policy makers in a coherent and consistent form, showing interlinkages, time‐series and cross‐sectoral analyses and assess energy policy. Two priority areas assessed by these indicators, regarding the country's energy supply and demand, helped in the identification of a number of energy policy options that focused on specific aspects of the country's energy sector. On the supply side, these options include the development and stimulation of renewable energy, such as small‐scale hydroelectric, wind, solar photovoltaic power and bagasse cogeneration; stimulation of programmes for ethanol use as automotive fuel and sugarcane bagasse cogeneration; and implementation of natural gas‐fired, combined heat and power (CHP) plants. On the demand side, policy options include: the full implementation of the law on efficiency standards for appliances; expansion of utility investment in end‐use energy efficiency; adoption of targets and protocols to reduce energy intensity in the industrial sector; improvement of passenger transport efficiency; and the creation of a fund to improve energy affordability for the poor.     

SENSITWITY ANALYSIS OF SIMULATED CONTAMINATED SEDIMENT TRANSPORT1

ABSTRACT: A simulation analysis of contaminated sediment transport involves model selection, data collection, model calibration and verification, and evaluation of uncertainty in the results. Sensitivity analyses provide information to address these issues at several stages of the investigation. A sensitivity analysis of simulated contaminated sediment transport is used to identify the most sensitive output variables and the parameters most responsible for the output variable sensitivity. The output variables included are streamflow and the flux of sediment and Cs¹³⁷. The sensitivities of these variables are measured at the field and intermediate scales, for flood and normal flow conditions, using the HSPF computer model. A sensitivity index was used to summarize and compare the results of a large number of output variables and parameters. An extensive database was developed to calibrate the model and conduct the sensitivity analysis on a 6.2 mi² catchment in eastern Tennessee. The fluxes of sediment and Cs¹³⁷ were more sensitive than streamflow to changes in parameters for both flood and normal flow conditions. The relative significance of specific parameters on output variable sensitivity varied according to the type of flow condition and the location in the catchment. An implications section illustrates how sensitivity analysis results can help with model selection, planning data collection, calibration, and uncertainty analysis.     

PREDICTING TEMPORAL AND SPATIAL FLOOD DYNAMICS USING A PRECALIBRATED MODEL1

ABSTRACT: A large storm in December 1990 allowed the evaluation of flood predictions from a hydrologic model (TOPMODEL) that had been previously calibrated on the West Fork of Walker Branch Watershed, a gauged 37.5 ha catchment near Oak Ridge, Tennessee. The model predicts both hydrograph dynamics and the spatial distribution of overland flow using an index based on topography. Maximum extent of overland flow during the storm was determined from patterns of leaf litter removal from valley bottoms. Both the flood hydrograph and the extent of overland flow were accurately predicted using model parameters obtained from a three-month period of normal flow conditions during 1983.