Effects of TiO2 nanoparticles on the aquatic plant Spirodela polyrrhiza: Evaluation of growth parameters, pigment contents and antioxidant enzyme activities

Plants are essential components of all ecosystems and play a critical role in environmental fate of nanoparticles. However, the toxicological impacts of nanoparticles on plants are not well documented. Titanium dioxide nanoparticles (TiO₂-NPs) are produced worldwide in large quantities for a wide range of purposes. In the present study, the uptake of TiO₂-NPs by the aquatic plant Spirodela polyrrhiza and the consequent effects on the plant were evaluated. Initially, structural and morphological characteristics of the used TiO₂-NPs were determined using XRD, SEM, TEM and BET techniques. As a result, an anatase structure with the average crystalline size of 8nm was confirmed for the synthesized TiO₂-NPs. Subsequently, entrance of TiO₂-NP_S to plant roots was verified by fluorescence microscopic images. Activity of a number of antioxidant enzymes, as well as, changes in growth parameters and photosynthetic pigment contents as physiological indices were assessed to investigate the effects of TiO₂-NPs on S. polyrrhiza. The increasing concentration of TiO₂-NPs led to the significant decrease in all of the growth parameters and changes in antioxidant enzyme activities. The activity of superoxide dismutase enhanced significantly by the increasing concentration of TiO₂-NPs. Enhancement of superoxide dismutase activity could be explained as promoting antioxidant system to scavenging the reactive oxygen species. In contrast, the activity of peroxidase was notably decreased in the treated plants. Reduced peroxidase activity could be attributed to either direct effect of these particles on the molecular structure of the enzyme or plant defense system damage due to reactive oxygen species.     

The effect of diazinon on blood glucose homeostasis: a systematic and meta-analysis study

Environmental Science and Pollution Research - Though evidence exists on the association between diazinon (DZN), an organophosphate pesticide, with hyperglycemia, contrasting reports also exist....     

Three-dimensional analysis of coherent turbulent flow structure around a single circular bridge pier

The coherent turbulent flow around a single circular bridge pier and its effects on the bed scouring pattern is investigated in this study. The coherent turbulent flow and associated shear stresses play a major role in sediment entrainment from the bed particularly around a bridge pier where complex vortex structures exist. The conventional two-dimensional quadrant analysis of the bursting process is unable to define sediment entrainment, particularly where fully three-dimensional flow structures exist. In this paper, three-dimensional octant analysis was used to improve understanding of the role of bursting events in the process of particle entrainment. In this study, the three-dimensional velocity of flow was measured at 102 points near the bed of an open channel using an Acoustic Doppler Velocity meter (Micro-ADV). The pattern of bed scouring was measured during the experiment. The velocity data were analysed using the Markov process to investigate the sequential occurrence of bursting events and to determine the transition probability of the bursting events. The results showed that external sweep and internal ejection events were an effective mechanism for sediment entrainment around a single circular bridge pier. The results are useful in understanding scour patterns around bridge piers.     

Spatial patterns of heavy metals in soil under different geological structures and land uses for assessing metal enrichments

One hundred and thirty composite soil samples were collected from Hamedan county, Iran to characterize the spatial distribution and trace the sources of heavy metals including As, Cd, Co, Cr, Cu, Ni, Pb, V, Zn, and Fe. The multivariate gap statistical analysis was used; for interrelation of spatial patterns of pollution, the disjunctive kriging and geoenrichment factor (EF_G) techniques were applied. Heavy metals and soil properties were grouped using agglomerative hierarchical clustering and gap statistic. Principal component analysis was used for identification of the source of metals in a set of data. Geostatistics was used for the geospatial data processing. Based on the comparison between the original data and background values of the ten metals, the disjunctive kriging and EF_G techniques were used to quantify their geospatial patterns and assess the contamination levels of the heavy metals. The spatial distribution map combined with the statistical analysis showed that the main source of Cr, Co, Ni, Zn, Pb, and V in group A land use (agriculture, rocky, and urban) was geogenic; the origin of As, Cd, and Cu was industrial and agricultural activities (anthropogenic sources). In group B land use (rangeland and orchards), the origin of metals (Cr, Co, Ni, Zn, and V) was mainly controlled by natural factors and As, Cd, Cu, and Pb had been added by organic factors. In group C land use (water), the origin of most heavy metals is natural without anthropogenic sources. The Cd and As pollution was relatively more serious in different land use. The EF_G technique used confirmed the anthropogenic influence of heavy metal pollution. All metals showed concentrations substantially higher than their background values, suggesting anthropogenic pollution.     

The detection of SARS-CoV-2 RNA in indoor air of dental clinics during the COVID-19 pandemic

Environmental Science and Pollution Research - In the indoor environment of dental clinics, dental personnel and patients are exposed to a risk of infection because of the transmission of...     

Development of Cellulose Aerogel as a New Material for the Reduction of Harmful Substances in Cigarette Smoke

The current study proposes a novel and improved cigarette filtration design comprising cellulose nanofibers (CNFs) and powdered activated carbons (PACs) with different dry matter contents. The proposed filter samples were primarily analyzed to verify their applicability as cigarette filters via measurements and standard tests, such as SEM, BET, DSC, and airflow permeability analysis. The results were compared with the cellulose acetate (CA) sample used as a conventional cigarette filter. The preliminary results indicated noticeable improvement compared to the reference CA. Also, the cigarettes were tested using a smoking machine, and the filtered smoke was analyzed using GC–MS to evaluate the filters' performance in reducing the harmful substances present in the smoke. The results showed that the filters made of CNF and PAC significantly decreased the toxic substances compared with the reference but did not affect the nicotine substantially and therefore will not negatively impact the trance level of smokers.

     

A Comparative Study on the Mechanical and Physical Properties of Plywood Panels Prepared by Chitosan as Bio-Adhesive

Journal of Polymers and the Environment - This study aims to make environment-friendly plywood panels acceptable in terms of both mechanical and physical properties using chitosan as a natural...     

Evaluation of Aspergillus niger and Penicillium simplicissimum for their ability to leach Zn–Ni–Cu from waste mobile phone printed circuit boards

Journal of Material Cycles and Waste Management - In this research, Zn, Ni, and Cu recovery from mobile phone printed circuit boards was investigated. The initial pH and pulp density using...     

The boosted activity of AgI/BiOI nanocatalyst: a RSM study towards Eriochrome Black T photodegradation

Environmental Science and Pollution Research - Nowadays, critical environmental pollution needs some novel, simple, effective, and cost-effective catalysts with high efficiency in the visible...