Atmospheric trace element concentrations in total suspended particles near Paris,France

To evaluate today’s trace element atmospheric concentrations in large urban areas, an atmospheric survey was carried out for 18 months, from March 2002 to September 2003, in Saclay, nearby Paris. The total suspended particulate matter (TSP) was collected continuously on quartz fibre filters. The TSP contents were determined for 36 elements (including Ag, Bi, Mo and Sb) using two analytical methods: Instrumental Neutron Activation Analysis (INAA) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS). The measured concentrations were in agreement within the uncertainties with the certified values for the polycarbonate reference material filter SRM-2783 (National Institute for Standard Technology NIST, USA). The measured concentrations were significantly lower than the recommended atmospheric concentrations. In 2003, the Pb atmospheric level at Saclay was 15 ng/m³, compared to the 500 ng/m³ guideline level and to the 200 ng/m³ observed value in 1994. The typical urban background TSP values of 1–2, 0.2–1, 4–6, 10–30 and 3–5 ng/m³ for As, Co, Cr, Cu and Sb, respectively, were inferred from this study and were compared with the literature data. The typical urban background TSP concentrations could not be realised for Cd, Pb and Zn, since these air concentrations are highly influenced by local features. The Zn concentrations and Zn/Pb ratio observed in Saclay represented a characteristic fingerprint of the exceptionally large extent of zinc-made roofs in Paris and its suburbs. The traffic-related origin of Ba, Cr, Cu, Pb and Sb was demonstrated, while the atmospheric source(s) of Ag was not identified.     

Mainstreaming sustainability into biodiversity conservation in Lesotho

Biodiversity conservation is critical for the continued supply of ecosystem services to secure the sustainability of livelihoods, especially for poor rural people in developing countries. Current rates of biodiversity loss need to be curbed by using effective interventions and decision-making that again require timely information. Undertaking a community sustainability assessment to generate and structure this information for grassroots levels is critical for decision-making and actions. This paper presents insights from a community sustainability assessment initiative undertaken in Lesotho within a trans-boundary project area known as the Maloti-Drakensberg Transfrontier Project. A qualitative case study approach was employed through a combination of several data collection techniques, including a literature review, field observations, key informant interviews, group discussions and key informant workshops. Study participants consisted of members of the community conservation forums from three districts that had been established by the project. Regarding progress towards the sustainability of biodiversity in the study area, the results indicated that current practices are unsustainable, more from the point of view of the socio-ecological components than the socio-cultural and spiritual or the socio-economic components. Consequently, there is a need to raise awareness at the community level and implement action plans to realize changes that support the sustainability of biodiversity in the long term.     

Soil bioassays as tools for sludge compost quality assessment

Composting is a waste management technology that is becoming more widespread as a response to the increasing production of sewage sludge and the pressure for its reuse in soil. In this study, different bioassays (plant germination, earthworm survival, biomass and reproduction, and collembolan survival and reproduction) were assessed for their usefulness in the compost quality assessment.Compost samples, from two different composting plants, were taken along the composting process, which were characterized and submitted to bioassays (plant germination and collembolan and earthworm performance). Results from our study indicate that the noxious effects of some of the compost samples observed in bioassays are related to the low organic matter stability of composts and the enhanced release of decomposition endproducts, with the exception of earthworms, which are favored. Plant germination and collembolan reproduction inhibition was generally associated with uncomposted sludge, while earthworm total biomass and reproduction were enhanced by these materials. On the other hand, earthworm and collembolan survival were unaffected by the degree of composting of the wastes. However, this pattern was clear in one of the composting procedures assessed, but less in the other, where the release of decomposition endproducts was lower due to its higher stability, indicating the sensitivity and usefulness of bioassays for the quality assessment of composts.     

Aktuelle und künftige Emissionen treibhauswirksamer fluorierter Verbindungen in Deutschland

The fluorinated compounds sulphur hexafluoride (SF₆), perfluorocarbons (CF₄, C₂F₆) and hydrofluorocarbons (HFCs) are atmospheric trace gases with extremely high global warming potentials (GWP). The study examines the real emissions of these compounds in Germany between 1990 and 1995, and develops projections for the years up to 2020. These projections indicate that annual perfluorocarbon releases will drop between the years 1990 and 2000 from 335 t/34 t to 100 t/10 t due to automation measures at the main source (aluminium smelting). Sulphur hexafluoride emissions, however, will remain in the range between 200 and 300 t per annum until the year 2020. By far the largest emitters are car tyres and sound-insulation glazing, non-electrical swithgear, the latter being relatively well sealed and linked to management and reprocessing concepts for used gas. As concerns hydrofluorocarbons which have only been used since 1990 with the specific intention of substituting chlorofluorocarbons (CFCs), an increasing degree of CFC substitution in stationary and mobile refrigeration technology, in canned PUR foams and in asthma sprays must be expected to lead to steeply rising emissions to levels exceeding 9,700 t/a from the year 2007 onwards, if halogen-free alternatives are not used more strongly. Assuming these trends, the cumulative emissions of the stated fluorinated compounds will correspond to a global warming impact of 25 million t CO₂ (GWP time horizon: 100 years) by the year 2020.     

Serial polygyny and colony genetic structure in the monogynous queenless ant Diacamma cyaneiventre

Serial polygyny, defined as the temporal succession of several reproductive females in a colony, occurs in some monogynous social insects and has so far attracted little attention. Diacamma cyaneiventre is a queenless ponerine ant found in the south of India. Colonies are headed by one singly mated worker, the gamergate. After the death of the gamergate or her absence following colony fission, the gamergate is replaced by a newly eclosed nestmate worker. After a replacement, colonies go through short-lived periods in which two matrilines of sisters co-occur. This is a situation which can be described as serial polygyny. To measure the consequences of serial polygyny, a genetic analysis was performed on 449 workers from 46 colonies of D. cyaneiventre using five microsatellite loci. The presence of more than one matriline among workers of the same nest was detected in 19% of colonies, indicating a recent change of gamergate. The average genetic relatedness among nestmate workers was 0.751 and did not significantly differ from the theoretical expectation under strict monogyny and monandry (0.75). A simple analytical model of the temporal dynamics of serial polygyny was developed in order to interpret these results. We show that the rate of gamergate turnover relative to the rate of worker turnover is the crucial parameter determining the level of serial polygyny and its effect on the genetic structure of colonies. This parameter, estimated from our data, confirms that serial polygyny occurs in D. cyaneiventre but is not strong enough to influence significantly the average genetic relatedness among workers.     

Environmental and Ecological Aspects in the Overall Assessment of Bioeconomy

Bioeconomy solutions potentially reduce the utilization demand of natural resources, and therefore, represent steps towards circular economy, but are not per se equivalent to sustainability. Thus, production may remain to be achieved against losses in natural resources or at other environmental costs, and materials produced by bioeconomy are not necessarily biodegradable. As a consequence, the assumption that emerging bioeconomy by itself provides an environmentally sustainable economy is not justified, as technologies do not necessarily become sustainable merely through their conversion to using renewable resources for their production. A source of the above assumption is that the utility of bioeconomy is mostly assessed in interaction between technology developers and economists, resulting in biased assessment with private commercial technology benefits being included, but environmental costs, especially longer term ones, not being sufficiently considered in the economic models. A possible solution to this conceptual contradiction may come from bioethics, as a strong concept in environmental ethics is that no technological intervention can be imposed on nature beyond its receptive capacity. To achieve a better balanced analysis of bioeconomy, environmental and ecological, as well as non-economic social aspects, need to be included in the overall assessment.     

Controls on hourly variations in urban background air pollutant concentrations

Average 21st century concentrations of urban air pollutants linked to cardiorespiratory disease are not declining, and commonly exceed legal limits. Even below such limits, health effects are being observed and may be related to transient daytime peaks in pollutant concentrations. With this in mind, we analyse >52,000 hourly urban background readings of PM₁₀ and pollutant gases throughout 2007 at a European town with legal annual average concentrations of common pollutants, but with a documented air pollution-related cardiorespiratory health problem, and demonstrate the hourly variations in PM₁₀, SO₂, NO_x, CO and O₃. Back-trajectory analysis was applied to track the arrival of exotic PM₁₀ intrusions, the main controls on air pollutants were identified, and the typical hourly pattern on ambient concentrations during 2007 was profiled. Emphasis was placed on “worst case” data (>90th percentile), when health effects are likely to be greatest. The data show marked daytime variations in pollutants result from rush-hour traffic-related pollution spikes, midday industrial SO₂ maxima, and afternoon O₃ peaks. African dust intrusions enhance PM₁₀ levels at whatever hour, whereas European PM incursions produce pronounced evening peaks due to their transport direction (across an industrial traffic corridor). Transient peak profiling moves us closer to the reality of personal outdoor exposure to inhalable pollutants in a given urban area. We argue that such an approach to monitoring data potentially offers more to air pollution health effect studies than using only 24 h or annual averages.     

Metabolic responses of Eisenia fetida after sub-lethal exposure to organic contaminants with different toxic modes of action

Nuclear magnetic resonance (NMR) - based metabolomics has the potential to identify toxic responses of contaminants within a mixture in contaminated soil. This study evaluated the metabolic response of Eisenia fetida after exposure to an array of organic compounds to determine whether contaminant-specific responses could be identified. The compounds investigated in contact tests included: two pesticides (carbaryl and chlorpyrifos), three pharmaceuticals (carbamazephine, estrone and caffeine), two persistent organohalogens (Aroclor 1254 and PBDE 209) and two industrial compounds (nonylphenol and dimethyl phthalate). Control and contaminant-exposed metabolic profiles were distinguished using principal component analysis and potential contaminant-specific biomarkers of exposure were found for several contaminants. These results suggest that NMR-based metabolomics offers considerable promise for differentiating between the different toxic modes of action (MOA) associated with sub-lethal toxicity to earthworms.     

Organic matter compounds as source indicators and tracers for marine pollution in a western Mediterranean coastal zone

Introduction  

Complex organic compounds found in oil and sediments linked with a particular source (such as algae, bacteria or vascular plants) are defined as biomarkers and are useful dating indicators in organic geochemistry.