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411.
412.
413.
Determination of malic acid and other C4 dicarboxylic acids in atmospheric aerosol samples 总被引:2,自引:0,他引:2
An ion chromatographic method was developed which is able to separate five unsubstituted and hydroxy C4 dicarboxylic acids, succinic, malic, tartaric, maleic and fumaric acid, besides the other unsubstituted C2-C5 dicarboxylic acids, oxalic, malonic and glutaric acids, as well as inorganic ions in samples extracted from atmospheric particulate matter. By the application of this method it was found for both rural and urban sites and for various types of air masses that in the summer-time malic acid is the most prominent C4 diacid (64 ng m(-3) by average), exceeding succinic acid concentration (28 ng m(-3) by average) considerably. In winter-time considerably less, a factor of 4-15, C4 acids occurred and succinic acid was more concentrated than malic acid. Tartaric, fumaric and maleic acids were less concentrated (5.1, 5.0 and 4.5 ng m(-3) by average, respectively). Tartaric acid was observed for the first time in ambient air. The results indicate that in particular anthropogenic sources are important for the precursors of succinic, maleic and fumaric acids. Biogenic sources seem to influence the occurrence of malic acid significantly. 相似文献
414.
Variation of nutrient and metal concentrations in aquatic macrophytes along the Rio Cachoeira in Bahia (Brazil) 总被引:6,自引:0,他引:6
The use of cuprous fungicides in cocoa production in the southern part of the state of Bahia (Brazil) for decades has caused an accumulation of copper in various components of the cocoa plantations, and a contamination of regional freshwater ecosystems is suspected. Urban and industrial sources are supposed to contribute to water pollution and eutrophication of the Rio Cachoeira, the main river in this region. In order to study the metal contamination and nutritional status of this freshwater ecosystem, samples of the aquatic macrophytes Eichhornia crassipes and Pistia stratiotes were collected at seven sites along the river course. The samples were analysed for their copper, aluminium, chromium, nitrogen and phosphorus concentrations. The levels of heavy metals increased in the downstream direction, particularly in the roots of water hyacinth. A dramatic increase of nitrogen and phosphorus concentrations in water as well as in plant tissues was found in samples collected downstream from the city of Itabuna. Metal input and eutrophication were attributed to agricultural, industrial and urban sources in the region. Biomonitoring of the water quality using aquatic macrophytes as accumulative indicator plants is recommended in addition to chemical water analyses. 相似文献
415.
Andreas Kemna Andrew Binley Frederick Day-Lewis Andreas Englert Bülent Tezkan et al. 《Environmental geochemistry and health》1991,13(3):152
The Society for Environmental Geochemistry and Health Tenth European MeetingUniversity of Edinburgh April 12–15, 1992 相似文献
416.
417.
Lekkas T Kolokythas G Nikolaou A Kostopoulou M Kotrikla A Gatidou G Thomaidis NS Golfinopoulos S Makri C Babos D Vagi M Stasinakis A Petsas A Lekkas DF 《Environment international》2004,30(8):995-1007
The pollution of the surface waters of Greece from the priority compounds of 76/464/EEC Directive was evaluated. The occurrence of 92 toxic compounds, 64 of which belong to priority compounds of List II, candidates for List I, of 76/464/EEC Directive, was studied in surface waters and wastewater through the developed network of 62 sampling stations, which covers the whole Greek territory. The analytical determination was performed by Purge and Trap-Gas chromatography-Mass spectrometry for volatile and semivolatile organic compounds (VOCs), Gas Chromatography-Electron Capture Detection for organochlorine insecticides, Gas Chromatography-Nitrogen Phosphorous Detection for organophosphorous insecticides, High Performance Liquid Chromatography-Photodiode Array Detection for herbicides, and Electrothermal Atomic Absorption Spectrophotometry and Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) for metals and the toluene extractable organotin compounds. The concentrations of VOCs and insecticides detected in the surface waters of Greece were very low, whereas the concentrations of herbicides and metals ranged generally at moderate levels. VOCs were detected almost exclusively in the rivers and very rarely in the lakes, while the frequency of occurrence of insecticides, herbicides and metals was similar for rivers and lakes. Water quality objectives (WQO) and emission limit values (ELV) have been laid down in national legal framework for a number of compounds detected in the samples, in order to safeguard the quality of surface waters from any future deterioration. 相似文献
418.
Strongly decreasing atmospheric emissions and acidic deposition during the 1990s have initiated chemical reversal from acidification
in several drinking-water reservoirs of the Erzgebirge, SE Germany. We studied responses of phytoplankton, zooplankton and
fish stocks in five reservoirs and at enclosure scale after experimental neutralization of 1,200 m3 of lake water. About 4 months after this treatment, diatoms and cryptomonads replaced the predominating chrysophytes and
dinoflagellates. The colonization by acid-sensitive species of green algae, cryptomonads, rotifers and Cladocera (e.g. Bosmina longirostris) is explained by the occurrence of dormant stages or by survival of individuals in very low abundances. Analogous to the
enclosure experiment, three reservoirs showed significantly (p < 0.01) falling trends of chlorophyll a and phytoplankton biovolume, mainly due to the decline of dinoflagellates. Picoplankton and diatoms increased slightly in
two reservoirs. The zooplankton communities were dominated by rotifers and small Cladocera. Representatives of the genus Daphnia were lacking. Two reservoirs were re-colonized by zooplanktivorous fish populations of either perch (Perca fluviatilis) or sunbleak (Leucaspius delineatus). The latter exhibited extremely high fluctuating abundance and biomass and even suffered from a population crash. This natural
mortality was caused by a limited food supply. Hence, severe top-down control may delay the recovery of larger zooplankton
species like daphnids. Fishery management comprising the introduction of predatory fishes can help to control zooplanktivorous
fish populations and to prevent their mass mortality. 相似文献
419.
This paper reports the findings of a study that investigated the relationship between different kinds of career management activities, the psychological contract, and outcomes of psychological contract fulfillment. The study tested a series of linked hypotheses which propose that individual career management behavior is associated with the experience of organizational career management help, which is related to fulfillment of the psychological contract. Fulfillment of the psychological contract in turn is linked to organizational commitment and is associated with behaviors at work, including absenteeism, turnover, and independent ratings of job performance. The findings provide some support for these proposed links. As a result, the paper makes four contributions to the psychological contract and careers literature: first, it shows that both individual and organizational career management behaviors are linked to psychological contract fulfillment; second, organizational career management help is associated with affective commitment and job performance; third, psychological contract fulfillment plays a key role in mediating the relationship between career management help and such attitudes and behaviors; and fourth, organizational commitment may mediate between psychological contract fulfillment and individual career management behavior aimed at furthering the career outside the organization. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
420.
Eleni Nanou Vassilis Tsiafakis E. Kapareliotis Charalabos Papageorgiou Andreas Rabavilas Christos Capsalis 《The Environmentalist》2005,25(2-4):173-179
Summary The effects of electromagnetic fields (EMF) emitted by cellular phones on human electroencephalogram (EEG) were studied during
an auditory memory task. The experimental method and the experimental setup are introduced as a credible measurement method
of EEG. 19 normal subjects (10 women and 9 men) performed the memory task both with and without exposure to a 900 MHz signal,
emitted by a dipole antenna placed near the subjects' head. The energy of the EEG signals was calculated at the time domain.
A Fourier transform of the EEG signals was done and the EEG energy was also calculated at the frequency domain. As the Parseval's
theorem anticipates the energies were identical. The EEG energy was found concentrated at the four basic bands (α (8–13 Hz),
β(14–30 Hz), δ (0–4 Hz) and θ(5–7 Hz)). The primary concern of the present study was the gender related influence of EMF on
the spectral energy of EEG. The results show evidence of a strong gender—radiation interaction effect on the EEG energy and
on the peak amplitudes within each of the four rhythms. Without radiation the spectral power of males is greater than of females,
while under exposure the situation is reversed. Under the influence of EMF the spectral power of the males EEG is decreased
while that of the females is increased. In conclusion both the baseline EEG and the changes effected to the EEG power spectrum
under the influence of EMF seem to be gender dependent. 相似文献