Carbonaceous aerosol emissions from India

Budget estimate for carbonaceous aerosols including black carbon (BC) and organic carbon, emitted from the combustion of various fuels, is very important for regional climate studies. Emission factors for carbonaceous aerosols from bio-fuels and soft coke were determined in a controlled combustion study. The emission factors thus obtained along with those available for other fossil fuels consumed in different sectors have been applied to assess the budget for carbonaceous aerosols from India. Preliminary calculations give a range of 1.6–1.8 Tg of carbonaceous aerosols that include 0.4–1.4 Tg of BC. A major (80%) portion of carbonaceous aerosols emitted from India is found to originate from the use of biomass for energy as 70–80% of energy requirement in rural India is met by combustion of traditional bio-fuels.     

Chapter two: methodologies for characterisation of combustion sources and for quantification of their emissions

Emissions from the combustion of biomass and fossil fuels result in generation of a large number of particle and gaseous products in outdoor and/or indoor air, which create health and environmental risks. Of particular importance are the very small particles that are emitted in large quantities from all the combustion sources, and that could be potentially more significant in terms of their impact on health and the environment than larger particles. It is important to quantify particle emissions from combustion sources for regulatory and control purposes in relation to air quality. This paper is a review of particle characteristics that are used as source signatures, their general advantages and limitations, as well as a review of source signatures of the most common combustion pollution sources including road transport, industrial facilities, small household combustion devices, environmental tobacco smoke, and vegetation burning. The current methods for measuring particle physical characteristics (mass and number concentrations) and principles of methodologies for measuring emission factors are discussed in the paper as well. Finally, the paper presents the recommendations for the future techniques for measurements of combustion products.     

Global gene expression and Ingenuity biological functions analysis on PCBs 153 and 138 induced human PBMC in vitro reveals differential mode(s) of action in developing toxicities

Several reports have indicated that low level of polychlorinated biphenyl (PCB) exposure can adversely affect a multitude of physiological disorders and diseases in in vitro, in vivo, and as reported in epidemiological studies. This investigation is focused on the possible contribution of two most prevalent PCB congeners in vitro in developing toxicities. We used PCBs 138 and 153 at the human equivalence level as model agents to test their specificity in developing toxicities. We chose a global approach using oligonucleotide microarray technology to investigate modulated gene expression for biological effects, upon exposure of PCBs, followed by Ingenuity Pathway Analysis (IPA), to understand the underlying consequence in developing disease and disorders. We performed in vitro studies with human peripheral blood mononuclear cells (PBMC), where PBMC cells were exposed to respective PCBs for 48 h. Overall, our observation on gene expression indicated that PCB produces a unique signature affecting different pathways, specific for each congener. While analyzing these data through IPA, the prominent and interesting disease and disorders were neurological disease, cancer, cardiovascular disease, respiratory disease, as well as endocrine system disorders, genetic disorders, and reproductive system disease. They showed strong resemblances with in vitro, in vivo, and in the epidemiological studies. A distinct difference was observed in renal and urological diseases, organisimal injury and abnormalities, dental disease, ophthalmic disease, and psychological disorders, which are only revealed by PCB 138 exposure, but not in PCB 153. The present study emphasizes the challenges of global gene expression in vitro and was correlated with the results of exposed human population. The microarray results give a molecular mechanistic insight and functional effects, following PCB exposure. The extent of changes in genes related to several possible mode(s) of action highlights the changes in cellular functions and signaling pathways that play major roles. In addition to understanding the pathways related to mode of action for chemicals, these data could lead to the identification of genomic signatures that could be used for screening of chemicals for their potential to cause disease and developmental disorders.     

Impact of COVID-19 lockdown on the elemental profile of PM10 present in the ambient aerosol of an educational institute in Kolkata,India

Reduction in air pollution level was prime observation during COVID-19 lockdown globally. Here, the study was conducted to assess the impact of lockdown on the elemental profile of PM₁₀ in ambient aerosol to quantify the elemental variation. To quantify the variation, phase-wise sampling of air pollutants was carried out using the gravimetric method for PM₁₀, while NO₂ and SO₂ were estimated through the chemiluminescence and fluorescent spectrometric method respectively. The elemental constituents of PM₁₀ were carried out using an Inductively Coupled Plasma Optical Emission Spectrometer and their source apportionment was carried out using the Positive Matrix Factorization model. The results showed that PM₁₀, NO₂ and SO₂ reduced by 86.97%, 83.38%, and 88.60% respectively during the lockdown sampling phase. The highest mean elemental concentration reduction was found in Mn (97.47%) during the lockdown. The inter-correlation among the pollutants exhibited a significant association indicating that they originate from the same source. The metals like Mn and Cu were found at a higher concentration during the lockdown phase corresponding to vehicular emissions. The comparative analysis of the elemental profile of PM₁₀ concluded that the lockdown effectuated in reduction of the majority of elements present in an aerosol enveloping metropolitan like Kolkata.     

Sediment quality,elemental bioaccumulation and antimicrobial properties of mangroves of Indian Sundarban

Environmental Geochemistry and Health - Mangroves have wide applications in traditional medicines due to their several therapeutic properties. Potentially toxic elements (PTEs), in mangrove...     

Role of Crosslinker on the Biodegradation Behavior of Starch/Polyvinylalcohol Blend Films

The effect of crosslinkers on the biodegradation behavior of starch/polyvinyl alcohol (PVA) blend films was investigated by weight loss study, Scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). Starch/PVA films were prepared by solution casting method and 5 weight% of four different crosslinking agents like epichlorohydrin, formaldehyde, zinc oxide and borax were used in four different sets to crosslink the films. These crosslinked starch/PVA films were biodegraded in compost. Weight loss study showed that crosslinking retarded the biodegradation of the films in the first 15?days, but after that, there was a significant increase in weight loss. The DSC analysis revealed that the consumption of starch and consequent rearrangement of the PVA molecules were distinctly different in the crosslinked films due to the effect of different crosslinking agents.     

Evaluation of disinfectants in order to eliminate fungal contamination in computer keyboards of an integrated health center in Piauí, Brazil

This quantitative and qualitative study aimed to evaluate the level of fungal contamination in computer keyboards from an Integrated Health Center (IHC) at Piauí, Brazil, and to evaluate the efficacy of 50% sodium bicarbonate and 50% alcoholic vinegar solutions to eliminate these microorganisms. Ten keyboards from six sectors of the IHC were chosen randomly, and the collection was performed in three situations: (i) before of disinfection, (ii) after disinfection with solution of sodium bicarbonate, and (iii) after disinfection with solution of alcoholic vinegar. Samples were inoculated in Petri dishes with dextrose agar potato plus chloramphenicol and incubated at room temperature for 72 h. All keyboards were contaminated with opportunistic fungi, with Cladosporium cladosporioides (29.4%) being the most frequent species, followed by Curvularia lunata (17.6%) and Aspergillus niger, Alternaria alternata, and Curvularia clavata with 11.8% each. The two solutions were proven to be efficient in eliminating fungal contamination; however, the sodium bicarbonate solution caused esthetic damages in keyboards. In addition, this study is the first report of the antifungal activity of alcoholic vinegar in filamentous fungi. Based on our findings, we suggest a daily disinfection of keyboards with a 50% vinegar solution plus adequate hygiene from the hands of professionals before and after the use of the computer and its annexes, as key actions to reduce nosocomial infections, particularly in economically disadvantaged countries.     

Simultaneous derivatization and extraction of nitrophenols in soil and rain samples using modified hollow-fiber liquid-phase microextraction followed by gas chromatography–mass spectrometry

A simple and sensitive method based on a modified hollow-fiber liquid-phase microextraction followed by gas chromatography–mass spectrometry has been successfully developed for the extraction and simultaneous derivatization of some nitrophenols (NPs) in soil and rain samples. Microwave-assisted solvent extraction was used for the extraction of NPs from the soil, while the rain sample was directly applied to the previously mentioned method. Briefly, in this method, the analytes were extracted from aqueous samples into a thin layer of organic solvent (dodecane?+?10 % tri-n-octylphosphine oxide) sustained in the pores of a porous hollow fiber. Then, they were back-extracted using a small volume of organic acceptor solution (25 μl; 10 mg/L N-methyl-N-(trimethylsilyl)trifluoroacetamide, as derivatization reagent, in acetonitrile) that was located inside the lumen of the hollow fiber. Under the optimized extraction conditions, enrichment factors of 255 to 280 and limits of detection of 0.1 to 0.2 μg/L (S/N?=?3) with dynamic linear ranges of 1–100 μg/L were obtained for the analytes. The accuracy of the approach was tested by the relative recovery experiments on spiked samples, with results ranging from 93 to 113 %. The method was shown to be rapid, cost-effective, and potentially interesting for screening purposes.     

Analysis of cost–benefit in life-cycle of plastic solid waste: combining waste flow analysis and life cycle cost as a decision support tool to the selection of optimum scenario

Millions of tons of plastic are consumed annually in the world due to its significant characteristics such as durability, flexibility, and low weight. High consumption has made plastic one of the most important municipal solid waste compounds, the quantity of which has increased in recent decades. Plastic solid wastes are known as a threat to the environment, and its efficient management in various aspects such as cost–benefit requires decision-making tools. This study was assessing the cost–benefit of plastic solid waste management by development of an economic model, and definition of different scenarios to change plastic solid waste management status. The results showed that 8971 tons of plastic solid waste were generated annually in the studied city. The plastic solid wastes were finally transferred to either recycling or landfilling site through 5 identified routes. 83 percent of the total recycled plastic solid waste was due to post-separation routes, and only 7.7 percent of the total plastic solid waste was recycled from the source separation route. The economic comparison of scenarios showed that with the aggregation of post-separation routes, the net revenue of plastic solid waste management increases by 334,000 euro per year while increasing the public participation and the ratio of source separation route raises net revenue by 875,000 euro per year, which was the best economic condition among the scenarios. Using life cycle cost method and it’s respected developed economic model truly satisfied the conditions of both, the current plastic solid waste management and the alternative scenarios, and hence can be adopted as a tool for decision-making.