The challenges in the identification of Escherichia coli from environmental samples and their genetic characterization

Environmental Science and Pollution Research - Escherichia coli bacteria are an essential indicator in evaluations of environmental pollution, which is why they must be correctly identified. This...     

Synthesis,characterization, and application of 2D/2D TiO2-GO-ZnFe2O4 obtained by the fluorine-free lyophilization method for solar light-driven photocatalytic degradation of ibuprofen

Environmental Science and Pollution Research - In this study, we report the potential of 2D/2D TiO2-GO-ZnFe2O4 photocatalyst obtained using the fluorine-free lyophilization technique for the...     

Can a key boreal Calanus copepod species now complete its life-cycle in the Arctic? Evidence and implications for Arctic food-webs

The changing Arctic environment is affecting zooplankton that support its abundant wildlife. We examined how these changes are influencing a key zooplankton species, Calanus finmarchicus, principally found in the North Atlantic but expatriated to the Arctic. Close to the ice-edge in the Fram Strait, we identified areas that, since the 1980s, are increasingly favourable to C. finmarchicus. Field-sampling revealed part of the population there to be capable of amassing enough reserves to overwinter. Early developmental stages were also present in early summer, suggesting successful local recruitment. This extension to suitable C. finmarchicus habitat is most likely facilitated by the long-term retreat of the ice-edge, allowing phytoplankton to bloom earlier and for longer and through higher temperatures increasing copepod developmental rates. The increased capacity for this species to complete its life-cycle and prosper in the Fram Strait can change community structure, with large consequences to regional food-webs.Supplementary InformationThe online version contains supplementary material available at 10.1007/s13280-021-01667-y.     

Embryo/larval toxicity and transcriptional effects in zebrafish (Danio rerio) exposed to endocrine active riverbed sediments

Environmental Science and Pollution Research - Sediment toxicity plays a fundamental role in the health of inland fish communities; however, the assessment of the hazard potential of contaminated...     

Ambient monitoring of asbestos in selected Italian living areas

This paper presents the results of an intensive monitoring activity of the particulate, fall-out and soil of selected living areas in Italy with the aim to detect the asbestos concentration in air and subsequent risk of exposure for the population in ambient living environments, and to assess the nature of the other mineral phases composing the particulate matrix. Some areas were sorted out because of the presence of asbestos containing materials on site whereas others were used as blank spots in the attempt to detect the background environmental concentration of asbestos in air. Because the concentration of asbestos in ambient environments is presumably very low, and it is well known that conventional low–medium flow sampling systems with filters of small diameter (25 mm) may collect only a very small fraction of particulate over a short period, for the first time here, an intense monitoring activity was conducted with a high flow sampling system. The high flow system requires the use of large cellulose filters with the advantage that, increasing the amount of collected dust, the probability to collect asbestos fibers increases. Both the protocol of monitoring and analysis are novel and prompted by the need to increase the sensitivity towards the small number of expected fibers. With this goal, the collection of fall-out samples (the particulate falling into a collector filled with distilled water during the monitoring shift) and soil samples was also accomplished. The analytical protocol of the matrix particulate included preliminary X-ray powder diffraction (XRPD), optical microscopy and quantitative electron microscopy (SEM and TEM). Correlations with climatic trends and PM10 concentration data were also attempted.The surprising outcome of this work is that, despite the nature of the investigated site, the amount of dispersed asbestos fibers is very low and invariably lower than the theoretical method detection limits of the SEM and TEM techniques for identification and counting of asbestos fibers. The results are compared to the literature data worldwide and an updated model for asbestos fibers dispersion in ambient environments is proposed.     

Transport of organic contaminants through salinity stratified water masses. A microcosm experiment

A salt-wedge stratified microcosm, spiked with 31 target analytes, including PCBs, organochlorine and organophosphorous pesticides, triazines, organophosphate flame retardants and caffeine (an urban wastewater molecular marker), was setup. Compound behaviour was monitored during a four week period, by sampling at six different levels of the water column, in order to understand the transport and loss processes of the different classes of chemical substances. Compound transport from one water body to the other has been positively correlated with diffusion via their molar volume. Target analytes loss has been positively correlated with evaporation via their K(H) and with degradation via their halve-lives. From these two processes, evaporation was found to be predominant using a multiparametric regression.     

The negative rejection of H+ in NF of carbonate solution and its influences on membrane performance

Nanofiltration (NF) experiments were conducted with simulated solution containing bicarbonate hardness and with three membranes: NF90, NF270 and NF-. The operating pressure was kept at 1.0 MPa, the water sample temperature was kept at 25 degrees C, the velocity on membrane surface was approximately 1 m s(-1) and the feeding pH values were 6.0, 6.5, 7.0, 7.5 and 8.0. Except for sampling, both the concentrate and the permeate were cycled to the feeding tank in order to keep the concentration constant. Experimental results demonstrated that the flux of NF90 membrane was slightly affected by the feeding pH, while the flux of NF270 and NF membranes was augmented when the feeding was acidified. The permeate pH of each membrane was always lower than the concentrate pH, indicating that the H(+) was negative rejected. This phenomenon was observed not only in the filtration of carbonate solution, but also in the filtration of the NaCl solution and the tap water. It is assumed that the small positive H(+) can easily permeate the NF membranes having negative charges. The more charges the membrane has, the more H(+) is negative rejected. High permeability of H(+) can speed decomposition of HCO(3)(-) into CO(3)(2-) and then accelerate CaCO(3) crystallization on membrane surface, which is unfavorable for membrane performances. In NF processes, it is better to considerate the membrane's selection and the feeding's pretreatment simultaneously, and it is beneficial for preventing scaling when selecting the membranes with less negative charges if only the water qualify can meet the demands.     

High concern chemicals in top layer sediments of the northern Adriatic seabed as markers of old waste dumpings

The results are presented of a survey planned to assess the presence of high concern chemicals in sediments collected in a northern sector of the Adriatic sea neighboring the Venice lagoon. For the assessment, persistent marker chemicals were selected from the families of polycyclic aromatic hydrocarbons, polychlorobiphenyls, polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs), and chlorinated pesticides. Based on the chemical-specific concentrations and PCDD+PCDF profiles determined in the sediments analyzed, dumping zones appear to have existed approximately 5-6km away from lagoon shoreline. Contamination levels exceed the quality criteria established by the pertinent Italian national regulation at many sampling sites, eventually reflecting ("fingerprinting") industrial activities once performed in the industrial settlement of Porto Marghera within the Venice lagoon. In coastal samples, concentration levels appear to be lower than those determined at offshore sampling sites.     

Nickel induced alteration of hen body weight, egg production and egg quality after an experimental peroral administration

In this study the effects of nickel (NiCl2) administered in drinking water (0.02; 0.2 and 2.0 mg NiCl2/L for 28 days) on laying hen body weight, egg production and egg quality is reported. Growth parameters during the experiment were significantly decreased mainly in the group with the highest nickel concentration. In total egg production dose-dependent decrease in all experimental groups was found. Egg weight was mainly affected in the group with the highest nickel concentration. Specific egg weight was not altered. Albumen weight and albumen content was significantly decreased in groups with the highest nickel concentration in comparison with the control group. Egg yolk analysis detected significantly decreased yolk weight in the group with the highest nickel experimental level. In yolk color a significant difference was detected between the group receiving 0.02 and 0.2 mg NiCl2/mL. Eggshell compactness was increased in all experimental groups what could be induced by altered mineralization of eggshell. Results of this study clearly report a negative effect of nickel as an environmental pollutant on laying hen body weight, egg production as well as egg quality.