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381.
Andrey S. Neroda Vasily F. Mishukov Vladimir A. Goryachev Denis V. Simonenkov Anna A. Goncharova 《Environmental science and pollution research international》2014,21(8):5669-5677
Artificial radionuclides, such as iodine-131 (131I), cesium-134 (134Cs), and cesium-137 (137Cs), as well as natural isotopes of beryllium-7 (7Be) and potassium-40 (40K) have been registered in atmospheric aerosols over Vladivostok selected from 11 March to 17 June 2011. Additionally, 134Cs and 137Cs were detected in atmospheric aerosols over Tomsk selected from 16 March to 17 June 2011. Artificial radionuclides were also discovered in atmospheric wet depositions sampled in Vladivostok from 3 to 17 May 2011. Moreover, these radionuclides have been registered in atmospheric aerosols over the sea surface of the Sea of Japan selected from 3 to 31 May 2011 during an expedition of the “Nadezhda” sailing ship. From 18 March to 15 April, an increase in concentrations of atmospheric aerosols over Vladivostok from 108.8 to 321.5 μg/m3 has been registered. It was accompanied by increased activity concentrations of 134Cs, 137Cs, and the 131I. During the period from 18 March to 15 April, activity concentrations of 137Cs and 134Cs in atmospheric aerosols increased 100 times compared with the minimum detectable concentration (MDC) level and peaked in the weekly sample gathered from 8 to 15 April (145.0 and 105.3 μBq/m3, respectively). Variability of concentrations of natural isotopes of 7Be and 40K was not greater than 1 order of magnitude throughout the sampling period. Maximal values of 137Cs and 134Cs concentrations (1,281.5?±?141 and 384.4?±?42.3 μBq/m3, respectively) in Tomsk were reached in samples taken from 1 to 2 April. For the atmospheric aerosol samples from the Sea of Japan, the largest concentration of 131I (392.3?±?215.7 μBq/m3) was detected from 13 to 19 May, while all other samples had much lower concentration values. Synoptic analysis of back trajectories movement of air masses showed that the radioactive cloud came to Vladivostok from the regions of Siberia and northeastern part of China. Synoptic analysis for Tomsk showed that during the period of maximal activity concentrations (1–9 April), air masses were arriving from the European part of Russia and north of Kazakhstan. 相似文献
382.
Hanna Barchanska Anna Kowalska Barbara Poloczek 《Environmental science and pollution research international》2014,21(6):4751-4758
Simple and effective extraction methods based on matrix solid-phase dispersion (MSPD), dispersive liquid–liquid microextraction (DLLME), and solid-phase extraction (SPE) coupled with high-performance liquid chromatography with diode array detector (HPLC-DAD) were developed to determine triketone herbicides—sulcotrione (SUL), mesotrione (MES), tembotrione (TEMB), and their degradation products—in plant tissues and water samples. The extraction procedures were employed to enable quantification of the accumulation of selected triketone herbicides and their degradation products in a model aquatic plant, Egeria densa. To obtain comprehensive information about the triketones' influence on an aquatic plant, changes in chlorophyll concentration in plants exposed to these triketones were monitored. The average recovery ranged from 58 to 115 % (coefficients of variation 7–12 %) for plant tissues and from 52 to 96 % (coefficients of variation 8–20 %) for water samples. The limit of detection (LOD) for the MSPD–HPLC-DAD procedure was in the range of 0.06–0.23 μg/g, whereas for DLLME–HPLC-DAD and SPE–HPLC-DAD, LOD was in the range of 0.06–0.26 μg/mL. Symptoms of the phytotoxicity of sulcotrione, mesotrione, tembotrione, and their degradation products (decrease of chlorophyll concentration in plant sprouts) were observed for E. densa cultivated in water with herbicide concentrations of 100 μg/L. Moreover, the tembotrione degradation product exhibited a high level of accumulation and low metabolism in plant tissues in comparison to the other triketones and their degradation products. 相似文献
383.
B. S. Sant’Anna D. M. Santos M. R. R. Marchi F. J. Zara A. Turra 《Environmental science and pollution research international》2014,21(10):6516-6524
Butyltin (BT) contamination was evaluated in hermit crabs from 25 estuaries and in sediments from 13 of these estuaries along about 2,000 km of the Brazilian coast. BT contamination in hermit crabs ranged from 2.22 to 1,746 ng Sn g-1 of DBT and 1.32 to 318 ng Sn g-1 of TBT. In sediment samples, the concentration also varied widely, from 25 to 1,304 ng Sn g-1 of MBT, from 7 to 158 ng Sn g-1 of DBT, and from 8 to 565 ng Sn g-1 of TBT. BTs are still being found in surface sediments and biota of the estuaries after the international and Brazilian bans, showing heterogeneous distribution among and within estuaries. Although hermit crabs were previously tested as an indicator of recent BT contamination, the results indicate the presence of contamination, probably from resuspension of BTs from deeper water of the estuary. Figure
Contamination of the environment and biota continues after the ban 相似文献
384.
Nikolopoulos D Petraki E Marousaki A Potirakis SM Koulouras G Nomicos C Panagiotaras D Stonham J Louizi A 《Journal of environmental monitoring : JEM》2012,14(2):564-578
This paper focuses on the environmental monitoring of radon in soil as a potential trace gas in the search of earthquake precursors. The paper reports the following: (a) Pre-monitoring experiments. (b) Set-up of methods and devices. (c) Active and passive monitoring results concentrating on two extremely-strong radon anomalies (~ 500 kBq m(-3)). (e) Discussion regarding the employed ± 2σ technique for identifying radon disturbances. (f) Application of wavelet-power-spectrum fractal analysis for detecting power-law behaviour. The strong anomalies exhibited anti-persistent power-law-beta-values (b = (1.8 ± 0.2), b = (1.8 ± 0.3)) significantly higher than those of the baseline. Persistent b-values were also detected. The findings comply with a self-organised-critical pre-earthquake state. (h) Discussion on models that interpret the radon anomalies focusing on the recently-proposed asperity-model. (i) Application of a recent technique which showed that the two strong disturbances were proportional to the strain change. It was concluded that the strong radon disturbances may be linked to the strong earthquake of 8/6/2008, M = 6.5, occurred 29 km away from the installed instrumentation. 相似文献
385.
Corona P Agrimi M Baffetta F Barbati A Chiriacò MV Fattorini L Pompei E Valentini R Mattioli W 《Environmental monitoring and assessment》2012,184(3):1409-1422
Urban areas are continuously expanding today, extending their influence on an increasingly large proportion of woods and trees
located in or nearby urban and urbanizing areas, the so-called urban forests. Although these forests have the potential for
significantly improving the quality the urban environment and the well-being of the urban population, data to quantify the
extent and characteristics of urban forests are still lacking or fragmentary on a large scale. In this regard, an expansion
of the domain of multipurpose forest inventories like National Forest Inventories (NFIs) towards urban forests would be required.
To this end, it would be convenient to exploit the same sampling scheme applied in NFIs to assess the basic features of urban
forests. This paper considers approximately unbiased estimators of abundance and coverage of urban forests, together with
estimators of the corresponding variances, which can be achieved from the first phase of most large-scale forest inventories.
A simulation study is carried out in order to check the performance of the considered estimators under various situations
involving the spatial distribution of the urban forests over the study area. An application is worked out on the data from
the Italian NFI. 相似文献
386.
Małgorzata Loga Anna Wierzchołowska-Dziedzic 《Environmental monitoring and assessment》2017,189(12):647
Measurement uncertainties are inherent to assessment of biological indices of water bodies. The effect of these uncertainties on the probability of misclassification of ecological status is the subject of this paper. Four Monte-Carlo (M-C) models were applied to simulate the occurrence of random errors in the measurements of metrics corresponding to four biological elements of surface waters: macrophytes, phytoplankton, phytobenthos, and benthic macroinvertebrates. Long series of error-prone measurement values of these metrics, generated by M-C models, were used to identify cases in which values of any of the four biological indices lay outside of the “true” water body class, i.e., outside the class assigned from the actual physical measurements. Fraction of such cases in the M-C generated series was used to estimate the probability of misclassification. The method is particularly useful for estimating the probability of misclassification of the ecological status of surface water bodies in the case of short sequences of measurements of biological indices. The results of the Monte-Carlo simulations show a relatively high sensitivity of this probability to measurement errors of the river macrophyte index (MIR) and high robustness to measurement errors of the benthic macroinvertebrate index (MMI). The proposed method of using Monte-Carlo models to estimate the probability of misclassification has significant potential for assessing the uncertainty of water body status reported to the EC by the EU member countries according to WFD. The method can be readily applied also in risk assessment of water management decisions before adopting the status dependent corrective actions. 相似文献
387.
Giuseppa Grazia Aprile Mina Di Salvatore Giovanna Carratù Antonio Mingo Anna Maria Carafa 《Environmental monitoring and assessment》2010,162(1-4):291-299
We compared the capacity to accumulate airborne heavy metals of two lichens (Flavoparmelia caperata and Parmotrema chinense) and one higher plant (Nerium oleander) at a very densely populated urban site near Naples. After 15, 45, 75, and 120 days of exposure at four sites with different levels of air pollution, equal portions of thalli and 20 leaves were collected, and four environmentally significant elements, Fe, Cu, Zn, and Pb, were measured by inductively coupled plasma analysis. To compare the accumulation rates of lichens and the vascular plant, we determined an index of relative accumulation rate of pollutants during time and the ratio between the concentrations of each element in exposed samples to that of control samples (exposed-to-control ratio). Our data indicate F. caperata as being the most suitable bioaccumulator, followed by P. chinense. N. oleander was also found to be a useful heavy metal biomonitor though not suitable as a bioaccumulator. 相似文献
388.
389.
Pernilla Christensen Anna Hedström Ringvall 《Environmental monitoring and assessment》2013,185(9):7279-7293
The National Inventory of Landscapes in Sweden (NILS) is a large-scale, sample-based monitoring program that combines aerial photointerpretation with field inventory to follow landscape-scale biophysical conditions and changes. A statistical power analysis was conducted before the NILS program began in 2003 with the aim to determine an appropriate sampling effort and compare some design alternatives. The chosen sampling effort was then evaluated in a second power analysis conducted just before the first 5-year re-inventory rotation started. The latter power analysis revealed which magnitude of actual change might be detected within the future for different central monitoring variables. This article reports results from these power analyses and discusses our experiences in using power analysis as a tool for designing large-scale monitoring programs. The results showed that even quite small changes in the more common variables, such as land cover types and more common plant species, can be detected on the national scale. However, on the regional scale, or for less common variables, changes will be more difficult to detect. The power analyses have revealed the size level of changes that will be possible to detect. The results have also generated incentives for further improvements of NILS, e.g., input to the modification and revision of the variable content, flow and hierarchy, and incentives for launching other complementary monitoring programs connected to NILS. They have also created a basis for a better and more user-oriented communication of results from NILS to different stakeholders. 相似文献
390.
Plant uptake of trace elements on a Swiss military shooting range: uptake pathways and land management implications 总被引:1,自引:0,他引:1
Robinson BH Bischofberger S Stoll A Schroer D Furrer G Roulier S Gruenwald A Attinger W Schulin R 《Environmental pollution (Barking, Essex : 1987)》2008,153(3):668-676
Over 400tons of Pb enters Swiss soils annually at some 2000 military shooting ranges (MSRs). We measured elements in the leaves of 10 plant species and associated rhizospheric soil on the stop butt of a disused MSR. The geometric mean concentrations of Pb, Sb, Cu, Ni in rhizospheric soils were 10,171mg/kg, 5067mg/kg, 4125mg/kg and 917mg/kg. Some species contained Pb, Cu and Ni, above concentrations (30mg/kg, 25mg/kg and 50mg/kg) shown to be toxic to livestock. Most contaminants in leaves resulted from surface deposition. However, at soil Pb concentrations >60,000mg/kg, Equisetum arvense and Tussilago farfara took up >1000mg/kg Pb into the leaves. These plants are not hyperaccumulators, having <100mg/kg Pb in leaves at lower soil concentrations. Removal of soil with more than 30,000 Pb, from which one could smelt this metal to offset remediation costs, followed by revegetation, would minimise dust and hence leaf-borne contaminants. 相似文献