Importance of heterocylic aromatic compounds in monitored natural attenuation for coal tar contaminated aquifers: A review

NSO heterocycles (HET) are typical constituents of coal tars. However, HET are not yet routinely monitored, although HET are relatively toxic coal tar constituents. The main objectives of the study is therefore to review previous studies and to analyse HET at coal tar polluted sites in order to assess the relevance of HET as part of monitored natural attenuation (MNA) or any other long-term monitoring programme. Hence, natural attenuation of typical HET (indole, quinoline, carbazole, acridine, methylquinolines, thiophene, benzothiophene, dibenzothiophene, benzofuran, dibenzofuran, methylbenzofurans, dimethylbenzofurans and xanthene) were studied at three different field sites in Germany. Compound-specific plume lengths were determined for all main contaminant groups (BTEX, PAH and HET). The results show that the observed plume lengths are site-specific and are above 250m, but less than 1000m. The latter, i.e. the upper limit, however mainly depends on the level of investigation, the considered compound, the lowest measured concentration and/or the achieved compound-specific detection limit and therefore cannot be unequivocally defined. All downstream contaminant plumes exhibited HET concentrations above typical PAH concentrations indicating that some HET are generally persistent towards biodegradation compared to other coal tar constituents, which results in comparatively increased field-derived half-lives of HET. Additionally, this study provides a review on physicochemical and toxicological parameters of HET. For three well investigated sites in Germany, the biodegradation of HET is quantified using the centre line method (CLM) for the evaluation of bulk attenuation rate constants. The results of the present and previous studies suggest that implementation of a comprehensive monitoring programme for heterocyclic aromatic compounds is relevant at sites, if MNA is considered in risk assessment and for remediation.     

Responses of a soil bacterium, Pseudomonas chlororaphis O6 to commercial metal oxide nanoparticles compared with responses to metal ions

The toxicity of commercially-available CuO and ZnO nanoparticles (NPs) to pathogenic bacteria was compared for a beneficial rhizosphere isolate, Pseudomonas chlororaphis O6. The NPs aggregated, released ions to different extents under the conditions used for bacterial exposure, and associated with bacterial cell surface. Bacterial surface charge was neutralized by NPs, dependent on pH. The CuO NPs were more toxic than the ZnO NPs. The negative surface charge on colloids of extracellular polymeric substances (EPS) was reduced by Cu ions but not by CuO NPs; the EPS protected cells from CuO NPs-toxicity. CuO NPs-toxicity was eliminated by a Cu ion chelator, suggesting that ion release was involved. Neither NPs released alkaline phosphatase from the cells’ periplasm, indicating minimal outer membrane damage. Accumulation of intracellular reactive oxygen species was correlated with CuO NPs lethality. Environmental deposition of NPs could create niches for ion release, with impacts on susceptible soil microbes.     

Comparison of EDTA-enhanced phytoextraction and phytostabilisation strategies with Lolium perenne on a heavy metal contaminated soil

Phytoremediation is a promising and cost-effective strategy to manage heavy metal polluted sites. In this experiment, we compared simultaneously phytoextraction and phytostabilisation techniques on a Cd and Zn contaminated soil, through monitoring of plant accumulation and leaching. Lolium perenne plants were cultivated for 2 months under controlled environmental conditions in a 27.6 dm³-pot experiment allowing the collect of leachates. The heavy metal phytoextraction was promoted by adding Na-EDTA (0.5 g kg⁻¹ of soil) in watering solution. Phytostabilisation was assessed by mixing soil with steel shots (1%) before L. perenne sowing. Presence of plants exacerbated heavy metal leaching, by improving soil hydraulic conductivity. Use of EDTA for phytoextraction led to higher concentration of heavy metal in shoots. However, this higher heavy metal extraction was insufficient to satisfactory reduce the heavy metal content in soil, and led to important heavy metal leaching induced by EDTA. On the other hand, addition of steel shots efficiently decreased both Cd and Zn mobility, according to 0.01 M CaCl₂ extraction, and leaching. However, improvement of growth conditions by steel shots led to higher heavy metal mass in shoot tissues. Therefore, soil heavy metal mobility and plant metal uptake are not systematically positively correlated.     

Framing the flood: a media analysis of themes of resilience in the 2011 Brisbane flood

In the wake of the flood that affected Brisbane, Australia, in January 2011, public attention turned to the causes of the event and lessons for minimizing the impacts of future floods. The news media was an important vehicle for understanding and internalizing the 2011 Brisbane flood. Examining how the flood was framed in the media is, therefore, useful to understand broad public perception of floods. We undertook a systematic newspaper analysis during a one-year period to explore media framings of the flood, focused on learning as an aspect of resilience in relation to two themes: (1) perceived links between the flood and climate change and (2) perceived roles of government in managing the flood. We show that media coverage of the flood reinforces aspects of resilience by acknowledging community spirit, self-reliance and the importance of sharing experiences for learning; articulating the risk of extreme events in a changing climate; and highlighting regional management trade-offs. Much of the discourse is likely to inhibit resilience, however, by casting the flood in terms of blame and political opportunity and paying inadequate attention to longer-term aspects of regional resilience. The limited learning observed to date may highlight a need for other mechanisms and actors to lead learning processes. As policy related to the 2011 Brisbane flood, and extreme events more generally, is influenced by the public discourse, it is important to understand the nuances of communication around these events and the media’s role in reinforcing or changing perceptions.     

Community engagement as a component of revitalization: Lessons learned from the Technical Outreach Services to Communities programme

Community involvement has been identified as an important factor in the successful redevelopment of contaminated land, and access to technical resources has been a barrier for some communities. This paper describes how the US Environmental Protection Agency funded Technical Outreach Services to Communities programme was used to support four communities involved in land revitalization. The four New England case studies were used to retrospectively draw lessons learned that could be useful to others interested in similar community work. We suggest that the broad lessons point to four factors for success, namely, where there is: (1) a common vision in the community; (2) a cohesive community; (3) an opportunity for co-learning; and (4) a commitment among the parties for long-term engagement. We conclude that technical support can serve as a useful framework for developing trustful and long-term relationships with communities.     

ADJUSTMENT OF STREAM CHANNEL CAPACITY FOLLOWING DAM CLOSURE,YEGUA CREEK,TEXAS1

ABSTRACT: In Yegua Creek, a principal tributary of the Brazos River in Texas, surveys of a 19 km channel reach downstream of Somerville Dam show that channel capacity decreased by an average of 65 percent in a 34 year period following dam closure. The decrease corresponds with an approximately 85 percent reduction in annual flood peaks. Channel depth has changed the most, decreasing by an average of 61 percent. Channel width remained stable with an average decrease of only 9 percent, reflecting cohesive bank materials along with the growth of riparian vegetation resulting from increased low flows during dry summer months. Although large changes in stream channel geometry are not uncommon downstream of dams, such pronounced reductions in channel capacity could have long‐term implications for sediment delivery through the system.     

DEVELOPMENT OF WATERSIIED MODELS FOR TWO SIERRA NEVADA BASINS USING A GEOGRAPHIC INFORMATION SYSTEM1

ABSTRACT: Techniques were developed using vector and raster data in a geographic information system (GIS) to define the spatial variability of watershed characteristics in the north-central Sierra Nevada of California and Nevada and to assist in computing model input parameters. The U.S. Geological Survey's Precipitation-Runoff Modeling System, a physically based, distributed-parameter watershed model, simulates runoff for a basin by partitioning a watershed into areas that each have a homogeneous hydrologic response to precipitation or snowmelt. These land units, known as hydrologic-response units (HRU's), are characterized according to physical properties, such as altitude, slope, aspect, land cover, soils, and geology, and climate patterns. Digital data were used to develop a GIS data base and HRIJ classification for the American River and Carson River basins. The following criteria are used in delineating HRU's: (1) Data layers are hydrologically significant and have a resolution appropriate to the watershed's natural spatial variability, (2) the technique for delineating HRU's accommodates different classification criteria and is reproducible, and (3) HRU's are not limited by hydrographic-subbasin boundaries. HRU's so defined are spatially noncontiguous. The result is an objective, efficient methodology for characterizing a watershed and for delineating HRU's. Also, digital data can be analyzed and transformed to assist in defining parameters and in calibrating the model.     

Evaluation of Material Biodegradability in Real Conditions–Development of a Burial Test and an Analysis Methodology Based on Numerical Vision

This work validated a burial protocol for in situ testing and presents a robust, repeatable and time-saving technique to measure degraded areas in the sample, i.e. an image analysis method. 1440 specimens of degraded samples have been compiled in a data base. To this end, twenty samples presenting different levels of biodegradability (i.e. PHBV/HV, PLA, PCL, PCL-Starch, paper, PE, PE-Starch) were buried at 4 different locations and then disinterred at 4, 6, 9, 12, 18, and 24-month intervals. The biodegradation levels of these samples were determined by computing weight and area loss. Weight loss was measured after careful cleaning, whereas area loss was quantified using image analysis. Image analysis gives reliable information on visual pollution while only requiring a rudimentary and thus quicker cleaning of the samples.