Bioremediation of TCE in a fractured limestone aquifer using a novel horizontal passive biobarrier

This article discusses a project demonstrating the successful use of a novel horizontal biobarrier approach to protect a fractured limestone aquifer from continuing contamination while passive bioremediation of the overlying clay till source area is in progress. The emplacement of the biobarrier has significantly reduced the concentrations of chlorinated ethenes and dechlorination activity in the limestone aquifer, promoting complete reductive dechlorination of the trichloroethene plume. The biobarrier strategy has thus met the challenge of protecting the limestone from the overlying overburden. Direct GeoProbe injections performed in the source area, which consist of a clay till overburden, have also reduced the contaminant concentrations in the clay till due to enhanced dechlorination activity; however, repeat injections may be required to address the areas of the till in which the injectate has not yet been distributed. The time frame for remediating the source area in the till is expected to be on the order of a decade. © 2010 Wiley Periodicals, Inc.     

Twenty years of elemental analysis of marine biota within the German Environmental Specimen Bank—a thorough look at the data

Purpose  

As one component of the German ecological environment observation, the Environmental Specimen Bank program was initiated in the mid-1980s. Under the program, representative specimens of marine, fresh water, and terrestrial ecosystems are sampled regularly and archived under chemically stable conditions. An initial characterization of the samples provides data regarding the status quo of the respective ecosystems. The aim of the present publication is to give insight into these real-time monitoring data, which have been generated for the last 10 to 20 years. This is done exemplarily for the heavy metals cadmium (Cd), mercury (Hg), and lead (Pb) in marine specimens of the Baltic and the North Sea.     

Strategies and methods for investigation of airborne biological agents from work environments in Germany.

In 2004/2005, a European Twinning Project was carried out to support Polish occupational safety and health institutions in putting into practice Directive 2000/54/EC regarding the protection of workers from risks related to exposure to biological agents at work. Information on and training in sampling and analysing biological agents of people responsible for bioaerosol measurements and the assessment of measuring results from the workplace atmosphere were part of the project. This paper is an extract of the authors' activities within the project and can be used as a tool for comparable activities in future projects with other European Union candidates. It gives information on working standards for bioaerosol measurements worked out and commonly used in Germany within the frame of European guidelines for bioaerosol measurements in the workplace atmosphere. Additionally it summarizes the authors' long practical experience in carrying out bioaerosol measurements in the atmosphere of various workplaces.     

Better estimates of soil carbon from geographical data: a revised global approach

Mitigation and Adaptation Strategies for Global Change - Soils hold the largest pool of organic carbon (C) on Earth; yet, soil organic carbon (SOC) reservoirs are not well represented in climate...     

How contamination sources and soil properties can influence the Cd and Pb bioavailability to snails

To better understand the fate of metals in the environment, numerous parameters must be studied, such as the soil properties and the different sources of contamination for the organisms. Among bioindicators of soil quality, the garden snail (Cantareus aspersus) integrates multiple sources (e.g. soil, plant) and routes (e.g. digestive, cutaneous) of contamination. However, the contribution of each source on metal bioavailability and how soil properties influence these contributions have never been studied when considering the dynamic process of bioavailability. Using accumulation kinetics, this study showed that the main assimilation source of Cd was lettuce (68 %), whereas the main source of Pb was the soil (90 %). The plant contribution increased in response to a 2-unit soil pH decrease. Unexpectedly, an increase in the soil contribution to metal assimilation accompanied an increase in the organic matter (OM) content of the soil. For both metals, no significant excretion and influence of source on excretion have been modelled either during exposure or depuration. This study highlights how the contribution of different sources to metal bioavailability changes based on changes in soil parameters, such as pH and OM, and the complexity of the processes that modulate metal bioavailability.     

Does Soil Carbon Loss in Biomass Production Systems Negate the Greenhouse Benefits of Bioenergy?

Interest in bioenergy is growing across the Western world in response to mounting concerns about climate change. There is a risk of depletion of soil carbon stocks in biomass production systems, because a higher proportion of the organic matter and nutrients are removed from the site, compared with conventional agricultural and forestry systems. This paper reviews the factors that influence soil carbon dynamics in bioenergy systems, and utilises the model FullCAM to investigate the likely magnitude of soil carbon change where bioenergy systems replace conventional land uses. Environmental and management factors govern the magnitude and direction of change. Soil C losses are most likely where soil C is initially high, such as where improved pasture is converted to biomass production. Bioenergy systems are likely to enhance soil C where these replace conventional cropping, as intensively cropped soils are generally depleted in soil C. Measures that enhance soil C include maintenance of productivity through application of fertilisers, inclusion of legumes, and retention of nutrient-rich foliage on-site. Modelling results demonstrate that loss of soil carbon in bioenergy systems is associated with declines in the resistant plant matter and humified soil C pools. However, published experimental data and modelling results indicate that total soil C loss in bioenergy systems is generally small. Thus, although there may be some decline in soil carbon associated with biomass production, this is negligible in comparison with the contribution of bioenergy systems towards greenhouse mitigation through avoided fossil fuel emissions.     

Impact of biogenic terpene emissions from <Emphasis Type="Italic">Brassica napus</Emphasis> on tropospheric ozone over saxony (Germany)

INTRODUCTION: The role of biogenic emissions in tropospheric ozone production is currently under discussion and major aspects are not well understood yet. This study aims towards the estimation of the influence of biogenic emissions on tropospheric ozone concentrations over Saxony in general and of biogenic emissions from brassica napus in special. MODELLING TOOLS: The studies are performed by utilizing a coupled numerical modelling system consisting of the meteorological model METRAS and the chemistry transport model MUSCAT. For the chemical part, the Euro-RADM algorithm is used. EMISSIONS: Anthropogenic and biogenic emissions are taken into account. The anthropogenic emissions are introduced by an emission inventory. Biogenic emissions, VOC and NO, are calculated within the chemical transport model MUSCAT at each time step and in each grid cell depending on land use type and on the temperature. The emissions of hydrocarbons from forest areas as well as biogenic NO especially from agricultural grounds are considered. Also terpene emissions from brassica napus fields are estimated. SIMULATION SETUP AND METEOROLOGICAL CONDITIONS: The simulations were performed over an area with an extension of 160 x 140 km2 which covers the main parts of Saxony and neighboring areas of Brandenburg, Sachsen-Anhalt and Thuringia. Summer smog with high ozone concentrations can be expected during high pressure conditions on hot summer days. Typical meteorological conditions for such cases were introduced in an conceptual way. RESULTS: It is estimated that biogenic emissions change tropospheric ozone concentrations in a noticeable way (up to 15% to 20%) and, therefore, should not be neglected in studies about tropospheric ozone. Emissions from brassica napus do have a moderate potential to enhance tropospheric ozone concentrations, but emissions are still under consideration and, therefore, results vary to a high degree. CONCLUSIONS: Summing up, the effect of brassica napus terpene emissions on ozone concentrations is noticeable, but not too pronounced. The results give a preliminary estimate on what the effect due to brassica napus emissions could be until better parameterizations can be derived from measurements.