Historical contamination of the Anacostia River, Washington, D.C.

The tidal Anacostia River in Washington DC has long been impacted by various sources of chemical pollution over the past 200 years. To explore more recent inputs of various chemicals, six sediment cores were collected for dating and chemical analysis in the downstream section of the tidal Anacostia River. Profiles of contaminants in sediment cores can be useful in determining management direction and effectiveness of pollution controls over time. There were two main objectives for this investigation: (1) determine current sediment contaminant levels; (2) determine a historical perspective of the sediment changes in contamination using (137)Cs and (210)Pb dating. The determination of an age-depth relationship using (210)Pb and (137)Cs dating gave somewhat different results, suggesting that the assumptions of (210)Pb dating were not met. Using the (137)Cs horizon allowed an assignment of approximate sediment accumulation rates and hence an age-depth relationship to contaminant events in the upper portions of the cores. Total PAHs showed higher concentrations at depth and lower surface concentrations. In the upper sections, PAHs were a mixture of combustion and petrogenic sources, while at depth the signature appeared to be of natural origins. Total PCBs, DDTs and chlordane concentrations showed a maximum in recent sediments, decreasing towards the surface. PCBs had lower molecular weight congeners near the surface and higher molecular weights at depth. A phthalate ester, DEHP, appeared in the mid 1940-1950s, and decreased towards the surface. Trace elements fell roughly into three groups. Fe, Mn, and As were in approximately constant proportion to Al, except in some deeper, sandy sediments, where they showed enrichments linked to redox conditions. Ag, Cd, Cu, Hg, Pb, and Zn had low concentrations in the deepest sediments, high concentrations at mid-depths, and declines to intermediate levels at the surface. Ni and Cr followed neither of these patterns closely. We observed that many contaminants appeared in the Anacostia sediments at various times, and reached relatively high concentrations in the past, but are now showing declines in loadings. In some cases, such as PCBs, DDT, chlordane, and Pb from leaded gasoline, these declines can be clearly linked to the discontinuation of their use for environmental reasons. For other contaminants (e.g., PAHs, DEHP, selected metals) these declines are more likely the result of changes in production, usage and waste control.     

Mortality Risk in Pediatric Motor Vehicle Crash Occupants: Accounting for Developmental Stage and Challenging Abbreviated Injury Scale Metrics

Objective: Survival risk ratios (SRRs) and their probabilistic counterpart, mortality risk ratios (MRRs), have been shown to be at odds with Abbreviated Injury Scale (AIS) severity scores for particular injuries in adults. SRRs have been validated for pediatrics but have not been studied within the context of pediatric age stratifications. We hypothesized that children with similar motor vehicle crash (MVC) injuries may have different mortality risks (MR) based upon developmental stage and that these MRs may not correlate with AIS severity.

Methods: The NASS-CDS 2000–2011 was used to define the top 95% most common AIS 2+ injuries among MVC occupants in 4 age groups: 0–4, 5–9, 10–14, and 15–18 years. Next, the National Trauma Databank 2002–2011 was used to calculate the MR (proportion of those dying with an injury to those sustaining the injury) and the co-injury-adjusted MR (MR_MAIS) for each injury within 6 age groups: 0–4, 5–9, 10–14, 15–18, 0–18, and 19+ years. MR differences were evaluated between age groups aggregately, between age groups based upon anatomic injury patterns and between age groups on an individual injury level using nonparametric Wilcoxon tests and chi-square or Fisher's exact tests as appropriate. Correlation between AIS and MR within each age group was also evaluated.

Results: MR and MR_MAIS distributions of the most common AIS 2+ injuries were right skewed. Aggregate MR of these most common injuries varied between the age groups, with 5- to 9-year-old and 10- to 14-year-old children having the lowest MRs and 0- to 4-year-old and 15- to 18-year-old children and adults having the highest MRs (all P <.05). Head and thoracic injuries imparted the greatest mortality risk in all age groups with median MR_MAIS ranging from 0 to 6% and 0 to 4.5%, respectively. Injuries to particular body regions also varied with respect to MR based upon age. For example, thoracic injuries in adults had significantly higher MR_MAIS than such injuries among 5- to 9-year-olds and 10- to 14-year-olds (P =.04; P <.01). Furthermore, though AIS was positively correlated with MR within each age group, less correlation was seen for children than for adults. Large MR variations were seen within each AIS grade, with some lower AIS severity injuries demonstrating greater MRs than higher AIS severity injuries. As an example, MR_MAIS in 0- to 18-year-olds was 0.4% for an AIS 3 radius fracture versus 1.4% for an AIS 2 vault fracture.

Conclusions: Trauma severity metrics are important for outcome prediction models and can be used in pediatric triage algorithms and other injury research. Trauma severity may vary for similar injuries based upon developmental stage, and this difference should be reflected in severity metrics. The MR-based data-driven determination of injury severity in pediatric occupants of different age cohorts provides a supplement or an alternative to AIS severity classification for pediatric occupants in MVCs.     

Age- and Sex-Specific Thorax Finite Element Model Development and Simulation

Objective: The shape, size, bone density, and cortical thickness of the thoracic skeleton vary significantly with age and sex, which can affect the injury tolerance, especially in at-risk populations such as the elderly. Computational modeling has emerged as a powerful and versatile tool to assess injury risk. However, current computational models only represent certain ages and sexes in the population. The purpose of this study was to morph an existing finite element (FE) model of the thorax to depict thorax morphology for males and females of ages 30 and 70 years old (YO) and to investigate the effect on injury risk.

Methods: Age- and sex-specific FE models were developed using thin-plate spline interpolation. In order to execute the thin-plate spline interpolation, homologous landmarks on the reference, target, and FE model are required. An image segmentation and registration algorithm was used to collect homologous rib and sternum landmark data from males and females aged 0–100 years. The Generalized Procrustes Analysis was applied to the homologous landmark data to quantify age- and sex-specific isolated shape changes in the thorax. The Global Human Body Models Consortium (GHBMC) 50th percentile male occupant model was morphed to create age- and sex-specific thoracic shape change models (scaled to a 50th percentile male size). To evaluate the thoracic response, 2 loading cases (frontal hub impact and lateral impact) were simulated to assess the importance of geometric and material property changes with age and sex.

Results: Due to the geometric and material property changes with age and sex, there were observed differences in the response of the thorax in both the frontal and lateral impacts. Material property changes alone had little to no effect on the maximum thoracic force or the maximum percent compression. With age, the thorax becomes stiffer due to superior rotation of the ribs, which can result in increased bone strain that can increase the risk of fracture. For the 70-YO models, the simulations predicted a higher number of rib fractures in comparison to the 30-YO models. The male models experienced more superior rotation of the ribs in comparison to the female models, which resulted in a higher number of rib fractures for the males.

Conclusion: In this study, age- and sex-specific thoracic models were developed and the biomechanical response was studied using frontal and lateral impact simulations. The development of these age- and sex-specific FE models of the thorax will lead to an improved understanding of the complex relationship between thoracic geometry, age, sex, and injury risk.     

Options for Managing Hypoxic Blackwater in River Systems: Case Studies and Framework

Hypoxic blackwater events occur when large amounts of organic material are leached into a water body (e.g., during floodplain inundation) and rapid metabolism of this carbon depletes oxygen from the water column, often with catastrophic effects on the aquatic environment. River regulation may have increased the frequency and severity of hypoxic blackwater events in lowland river systems, necessitating management intervention to mitigate the impacts of these events on aquatic biota. We examine the effectiveness of a range of mitigation interventions that have been used during large-scale hypoxic blackwater events in the Murray–Darling Basin, Australia and that may be applicable in other environments at risk from hypoxic blackwater. Strategies for hypoxia mitigation include: delivery of dilution flows; enhancement of physical re-aeration rates by increasing surface turbulence; and diversion of blackwater into shallow off-channel storages. We show that the impact of dilution water delivery is determined by relative volumes and water quality and can be predicted using simple models. At the dilution water inflow point, localized oxygenated plumes may also act as refuges. Physical re-aeration strategies generally result in only a small increase in dissolved oxygen but may be beneficial for local refuge protection. Dilution and natural re-aeration processes in large, shallow lake systems can be sufficient to compensate for hypoxic inflows and water processed in off-channel lakes may be able to be returned to the river channel as dilution flows. We provide a set of predictive models (as electronic supplementary material) for estimation of the re-aeration potential of intervention activities and a framework to guide the adaptive management of future hypoxic blackwater events.     

Definitions and organizational practice of sustainability in the for-profit sector of Nova Scotia

The term “sustainability” has been a part of local, national, and international environmental discussions for well over a decade. First legitimized by the United Nations in 1987 with the release of the Brundtland Commission and Our Common Future (WCED, 1987), the term “sustainability” is now often used in more mainstream contexts. However, given our continued global ecological decline (Millennium Ecosystem Assessment, 2005), the question remains: do decision makers within organizations really have a clear idea of what sustainability is? Further, are they able to communicate that vision in such a way as it can be operationalized within their organizations?Organizations are faced with a high degree of uncertainty when attempting to move towards sustainability. The immense amount of literature and information available about the concept is daunting, especially for harried managers of small businesses who must respond to many competing needs and interests. Although many concepts, frameworks, and tools are available for business executives to use, there have been relatively less attempts to develop a rigorous, applied definition of sustainability that can be clearly understood, implemented, and measured within and across organizations. Given the abundance of concepts, frameworks, and tools, with the corresponding dearth of overarching frameworks, one may wonder what are executives learning from all this literature, and how it is being diffused into strategy, planning, and operations? This study aims to gain insight into executives’ thinking around definitions and the implementation of sustainability practices in Nova Scotia. The findings of this study indicate that there are three key relationships of significance in this area including: type of definition and ease of articulation; type of definition and type of experience; and type of definition, type of experience, and integration of strategic and operational planning.     

Evaluating the “Catch‐Can” Test for Measuring Lawn Sprinkler Application Rates1

Abstract: The effectiveness of measuring lawn sprinkler application rates using the catch‐can test was evaluated. A survey of sources recommending the catch‐can test for measuring application rates show that catch‐can test procedures differ in the collector type, collector placement, number of collectors, and test duration. Analyses of catch‐can tests were performed to address these procedural differences, with emphasis on the type and number of collectors required to provide a reasonable level of confidence in test results. The accuracy of the catch‐can test generally improves as the number of randomly placed collectors increases. In order to achieve an accuracy of ±25% for 90 out of 100 catch‐can tests, the number of randomly placed collectors required ranged from 6 to over 50 for hand‐move systems, while for in‐ground systems, the number of randomly placed collectors required ranged from 2 to 8, depending on the pressure and percent overlap of the water distribution pattern. As long as a reasonable number of collectors were used when performing a catch‐can test, no consistent differences were observed in catch‐can test results due to type of collectors when using tuna fish cans, soup cans, or coffee mugs.     

A method for predicting the performance of packed columns operating with a reactive scrubbing liquid that control gaseous air pollutants

A method for predicting the performance of packed columns that control gaseous air pollutants has been developed that exploits the advances in both computer software and hardware commonly used by practicing engineers. The solution of the simultaneous partial differential equations that describe the absorption process in packed columns that occurs in the presence of chemical reaction is obtained by converting the partial differential equations to systems of ordinary differential equations. These systems of ordinary differential equations are then solved using the method of lines along with a variable step, variable order numerical method. The method is applicable to systems in which there are multiple reactions within the liquid phase. The reactions can be of any order and can be reversible. The programming is simple and the machine running time is minimal. The method is illustrated here with an example.     

CALIBRATION OF SNYDER COEFFICIENTS FOR PENNSYLVANIA1

ABSTRACT Unit hydrograph theory is one of the most widely used techniques to predict surface runoff. The present study is concerned with the Snyder unit hydrograph and the calibration of the Snyder coefficients for Pennsylvania. Twenty-seven study basins were selected, located randomly across the state. With the rainfall and runoff recorded for several events for each basin (more than 500 events were analyzed) unit hydrographs were calculated and the Snyder coefficients determined. A map of the coefficients was drawn to illustrate the variability in the coefficients and two equations using multiple regression theory were developed. The unexplained variability of the coefficients suggests that upper and lower bounds on the peak flow might be placed on storm hydrographs developed for ungaged watersheds.     

Convergence and emergence in organizations: An integrative framework and review

In reaction to the growing attention to connecting individual‐level and unit‐level constructs, we first briefly review emergence terminology and theories that address the dynamic process by which a higher‐level phenomenon emerges from lower‐level elements. Next, we review the extant theory and research on emergence and convergence in organization science using an organizing framework that simultaneously considers the content area of lower‐level elements, the emergent factors, and the target of the emergent property. In addition to organizing and bridging current literature on emergence and convergence, gaps of existing research and new directions for future research, including compilation and divergence, are identified. Copyright © 2015 John Wiley & Sons, Ltd.