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11.
Ashok Kumar Pandey Shri Dhar Pandey Virendra Misra P. N. Viswanathan 《Chemistry and Ecology》1999,16(4):269-282
In order to investigate the role of functional groups present in humic acid(s) (HA) during complex formation, water soluble complexes between HA isolated from soil and metals (Pb, Ca, As, Ni, Cr, Co, Cu, Cd, Fe, Mn, Mg and Zn) were prepared and subjected to infrared (IR) spectroscopy. the IR data revealed the involvement of the - OH group of humic acid in complex formation with all metals except copper and arsenic, whereas the - COOH group of HA was found to be the preferred site of binding for all the metals. the significance of findings in relation to detoxification of environmental pollutants is discussed in this paper. 相似文献
12.
Shubha Nigam Krishna Gopal Padma S. Vankar 《Environmental science and pollution research international》2013,20(6):4000-4008
To evaluate the biosorption efficacy of submerged aquatic plant Hydrilla verticilata for arsenic uptake from drinking water. H. verticillata, a submerged aquatic plant was utilized successfully for arsenic uptake from aqueous solution. Batch studies with various parameters viz. pH, sorbent dose, contact time, initial metal ion concentration, and temperature were carried out. Data were utilized to plot Lagergren graph along with pseudo-second-order graphs for kinetic studies to estimate the removal efficacy and to determine the nature of reaction. Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) have been performed for characterization of metals on biomass. The study showed 96.35 % maximum absorption of arsenic by H. verticilata at initial concentration of 100 ppb with 0.5 g of biomass/100 ml for 5 h contact time at pH?6.0 with 150 rpm agitation rate. Data followed Langmuir isotherm showing sorption to be monolayer on homogeneous surface of biosorbent. The negative values of ΔG° indicated spontaneous nature; whereas ΔH° indicates exothermic nature of system and negative value of ?S° entropy change correspond to a decrease in the degree of freedom to the adsorbed species followed by pseudo-second-order adsorption kinetics. FTIR and SEM results showed apparent changes in functional group regions after metal chelation and the changes in surface morphology of biosorbent. This is a comparatively more effective, economic, easily available, and environmentally safe source for arsenic uptake from solution due to its high biosorption efficacy than other biosorbents already used. 相似文献
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14.
Ashok K. Alva 《Environmental management》1992,16(6):769-776
Extremely sandy soils and poorly distributed high annual rainfall in the state of Florida contribute to significant leaching
losses of nutrients from routine fertilization practices. A leaching column experiment was conducted to evaluate the leaching
losses of nutrients when using currently available N, P, K blend fertilizers for young citrus tree fertilization. Fertilizer
blends included NH4NO3, Ca(NO3)2, IBDU, IBDU plus Escote, Nutralene, Osmocote, and Meister. Following leaching of 1000 ml of water through soil columns, which
simulates leaching conditions with 26 cm of rainfall, the amount of NO3 and NH4 recovered in the leachate from soil columns amended with an NH4NO3 blend accounted for 37% and 88% of the respective nutrients contained in the quantity of blend per column. The corresponding
values for soil columns amended with a Ca(NO3)2 blend were 48% and 100%. Leraching losses of both NO3 (<3%) and NH4 (<4%) were drastically decreased when using controlled-release fertilizers. The recoveries of P and K in 1000 ml of leachate
were 1.3% and 8%, respectively, of the nutrients added as Osmocote, which contained coated P and K sources. In the case of
the rest of fertilizer blends, the recoveries of P and K in 1000 ml of leachate were as high as 52%–100% and 28%–100%, respectively.
Therefore, controlled-release technology offers an important capability for minimizing leaching losses of nutrients. 相似文献
15.
S K Kashyap S K Nigam R C Gupta A B Karnik S K Chatterjee 《Journal of environmental science and health. Part. B》1979,14(3):305-318
Inbred Swiss mice were treated with technical BHC (1) orally with the diet or by intubation and (2) by skin painting. The total duration of the experiment was 80 weeks. There was no difference in body growth and mortality between the experimental and control groups. Symptoms of intoxication in the form of convulsions and tendency of circling in one direction with drooping ears were observed alongwith corneal opacity 40 weeks after the experiment. Oral BHC treatment resulted in a significant increase in the incidence of liver tumours and tumours of lymphoreticular tissue. Males and females were equally susceptible. Skin painting of mice did not significantly increase the incidence of tumour. 相似文献
16.
Ashok Khosla 《生态毒理学报》2003,25(2):15-18
法人社会责任概念的发展,已经超出了简单的慈善事业和遵从法律的范畴,而包括了对优秀法人公民的经商和行为举止更广泛的伦理解释 .这种演变的下一个阶段,可能要由扩大市场盈利商业活动来推动,这一点过去被大大忽视了 .只要提供的商品和服务能够满足贫苦人群的基本需求--同时也提高了当地经济的购买力--就可以既获得利润,又尽到了社会责任 . 相似文献
17.
Nigam R Srivastava S Prakash S Srivastava MM 《Journal of environmental biology / Academy of Environmental Biology, India》2002,23(2):175-180
The present communication reports the effect of various carboxylic and amino acids on the uptake and translocation of root-absorbed Cd by maize (Zea mays). Statistically significant increases in Cd accumulation in various plant tissues with increasing supplementation of organic acids suggested the existence of Cd-organic acid interaction in soil-rhizosphere environment of the plant. The potentiality of phytochelators (organic acids) to form plant available organically bound Cd is discussed. 相似文献
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19.
The fluorescence spectroscopic behavior of bromadiolone (anticoagulant rodenticide), a substituted 4-hydroxycoumarin derivative, was investigated in water and in organized media like micelles and cyclodextrins. A detailed study on various photophysical parameters like fluorescence intensity (IF), quantum yield (), lifetime (τ) and steady state fluorescence anisotropy (r) of bromadiolone in aqueous and in organized media was carried out. Bromadiolone in aqueous solution was observed to be in an aggregated state, thereby showing weak emission due to self-quenching. Marked enhancement of fluorescence intensity was observed in organized media like micelles and β-cyclodextrin. A preliminary investigation has been done to find out whether this enhancement of fluorescence can be used to develop a sensitive analytical method for determination of bromadialone in aqueous media. A linear relationship between the fluorescence intensity and concentration of bromadiolone was observed in the range of 0.15–7.9 μg ml−1 in cetyltrimethylammonium bromide (CTAB) and 0.5–26.4 μg ml−1 in β-cyclodextrin medium. The lower detection limit was found to be 37 ng ml−1 in presence of CTAB and 23 ng ml−1 in β-cyclodextrin. Comparison with 4-hydroxycoumarin, an unsubstituted analogue, was made. 相似文献
20.
Nidhi A. Shah Savita A. Rairikar Shyam Ashok Parag K. Sancheti 《International journal of occupational safety and ergonomics》2016,22(3):422-425
Background. Playing guitar can cause adoption of asymmetric postures and affect the shoulder's stability. Objective. To assess the presence of scapular dysfunction in professional guitar players. Method. A lateral scapular slide test was performed at the level of the spine of the scapula and at the inferior angle of the scapula in 20 professional guitar players (age: 18–40 years) and was compared with 20 age-matched non-players at angles of 0°, 45° and 90° of shoulder abduction with both limbs loaded with 0.5-kg weights. Analysis was done by unpaired t test. Results. Scapular dysfunction in guitar players was seen in the form of asymmetric scapula at rest in 25% and dyskinetic scapula in 20% of players. 100% of non-players had normal scapular positioning. Comparison at the level of the spine of the scapula showed no significant difference (p?>?0.05), but the inferior angle showed a significant difference at 0° (1.37?cm), 45° (1.93?cm) and 90° (2.15?cm) which was more in the player's category (p?0.05). Conclusion. There exists a marked dysfunction of scapular stabilizers in professional guitar players at the level of the inferior angle of the scapula. 相似文献