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排序方式: 共有219条查询结果,搜索用时 15 毫秒
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Liu P Zhu D Zhang H Shi X Sun H Dang F 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):1053-1060
Improved predictions on the fate of organic pollutants in surface environments require a better understanding of the underlying sorption mechanisms that control their uptake by soils. In this study, we monitored sorption of nine aromatic compounds with varying physicochemical properties (hydrophobicity, electron-donor/acceptor ability and polarity), including two polycyclic aromatic hydrocarbons, two chlorobenzenes, two nitroaromatic compounds, dichlobenil, carbaryl and 2,4-dichlorophenol in aqueous suspension of four surface soils of eastern China. The tested soils were characterized with respect to organic carbon (OC) content, black carbon content, mineralogy, morphology and size fraction to assess the role of the diverse soil characteristics in sorption. The results of this study show that not only the solute hydrophobicity and the OC content of soil are important to the retention of organic pollutants, but also the solute molecular structure and the soil nature. 相似文献
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本文以成都客车厂生产的CDK6964型团体客车为对象,通过对车内声、振动特性的测试和分析,针对该车结构声严重,发动机罩壳隔声能力差等缺陷,主要采取了自由阻尼和约束阻尼改进结构,使该车车内平均噪声级在60km/h匀速下由原来的86.4dB(A)降至改进后的73.2dB(A),取得显著成效。 相似文献
55.
Sorption of tylosin and sulfamethazine on solid humic acid 总被引:3,自引:0,他引:3
Tylosin(TYL) and sulfamethazine(SMT) are ionizable and polar antimicrobial compounds,which have seeped into the environment in substantial amounts via fertilizing land with manure or sewage. Sorption of TYL and SMT onto humic acid(HA) may affect their environmental fate. In this study, the sorption of TYL and SMT on HA at different conditions(pH, ionic strength) was investigated. All sorption isotherms fitted well to the Henry and Freundlich models and they were highly nonlinear with values of n between 0.5 and 0.8, which suggested that the HA had high heterogeneity. The sorption of TYL and SMT on HA decreased with increasing p H(2.0–7.5), implying that the primary sorption mechanism could be due to cation exchange interactions between TYL~+/SMT~+ species and the functional groups of HA.Increasing ionic strength resulted in a considerable reduction in the K_d values of TYL and SMT,hinting that interactions between H bonds and π–π EDA might be an important factor in the sorption of TYL and SMT on HA. Results of Fourier transform infrared(FT-IR) and ~13C-nuclear magnetic resonance(NMR) analysis further demonstrated that carboxyl groups and O-alkyl structures in the HA could interact with TYL and SMT via ionic interactions and H bonds,respectively. Overall, this work gives new insights into the mechanisms of sorption of TYL and SMT on HA and hence aids us in assessing the environmental risk of TYL and SMT under diverse conditions. 相似文献
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Hanh Pham Thi Minh Nghi Duong Thanh Lan Tran Dinh Van Quan Nguyen Ba Dang The Viet Pham Hung 《Environmental geochemistry and health》2019,41(1):381-390
Environmental Geochemistry and Health - Polychlorinated biphenyls (PCBs), well-known as an important scientific achievement, are now considered as one of the most persistent organic pollutants... 相似文献
57.
Tran Son H. Dang Huyen T.T. Dao Dung A. Nguyen Viet-Anh Nguyen Lien T. Nguyen Viet-Anh Han Mooyoung 《Environmental science and pollution research international》2021,28(10):11928-11941
Environmental Science and Pollution Research - This study assessed the performance of rainwater-harvesting systems installed for selected public utilities in the northern provinces of Vietnam where... 相似文献
58.
采用危险与可操作性(HAZOP)方法分析了石脑油储罐废气排放系统工艺变更的危害因素,特别对废气排放系统的控制参数,给出了逆流、超温、超压、低压/真空等偏差的HAZOP分析结果,并针对高风险的偏差提出了相应的建议措施. 相似文献
59.
建设项目竣工环境保护验收监测报告是检验建设方落实环保“三同时”制度的技术手段,也是环保部门依法管理的技术支撑和依据,竣工验收监测报告除遵循行业技术规范要求外,建设内容变更、环保设施落实、污染物排放及总量、环境质量影响等成为不可或缺的重要内容,需要逐一阐述明确。 相似文献
60.
一株耐镉细菌的分离及其富集Cd的机理 总被引:4,自引:0,他引:4
从重金属镉污染土壤中筛选到一株对镉具有较强抗性和富集能力的细菌RC。经形态学观察和生理生化鉴定以及16SrDNA序列分析,RC为蜡状芽孢杆菌(Bacillus cereus)。在不同镉浓度液体培养条件下研究了菌体的生长曲线,并探讨了RC菌株对Zn、Cu的抗性,结果显示RC对不同重金属的抗性机制存在一定的差异。利用扫描电镜、透射电镜观察了镉在RC胞内外的沉积作用及分布情况,结果表明,在镉浓度为150 mg/L时菌体细胞壁及其内部可见大量的高电子密度颗粒,同时在菌体表面也有沉淀物附着。因此,胞内外沉积作用可能是该菌对高浓度镉的抗性和富集作用的重要途径。通过红外光谱探讨了RC积累镉前后细胞壁表面化学基团的变化情况,结果发现RC的细胞壁上参与积累作用的化学官能团主要有—OH、—NH、—CO和—CO—NH—等。 相似文献