金属材料高温疲劳-蠕变寿命预测方法研究进展

从线性累积损伤、应力参量控制模式、应变参量控制模式、损伤力学、断裂力学、多元统计以及神经网络等7个方面研讨了国内外金属材料在高温条件下疲劳-蠕变寿命预测方法的主要研究进展与成果。其中,线性累积损伤主要应用于高温蠕变——低周疲劳的寿命预测;应变控制模式的预测方法成功地把蠕变因素引入到疲劳寿命预测模型中;多元统计以及神经网络是金属材料进行寿命预测的新方法。     

Field derived accumulation and release kinetics of DDTs in plants

Vegetation plays an important role in influencing the air/surface exchange of semivolatile organic compounds (SOCs). In order to predict the capability of different plant species to capture chemicals from the air, plant-air partition coefficients and kinetic accumulation parameters must be defined. In this study, potted plants of three different species were transferred to the vicinity of a source point for DDT, namely a contaminated area around a former production plant in Italy. Leaves were constantly sampled in order to follow the uptake from air over time. Later, the potted plants were transported to a location characterized by background diffuse air concentrations for the release phase. Coupling the experimental results with a two-compartment accumulation model it was possible to derive the kinetics parameters and the plant-air partition coefficient K(PA) for p,p'-DDT. The logK(PA) (on a mass/volume basis) ranged between 1.7 and 2.2 for the different species. The uncertainties related to the different phenomena involved in a field uptake/release experiment are discussed.     

Fluoranthene, but not benzo[a]pyrene, interacts with hypoxia resulting in pericardial effusion and lordosis in developing zebrafish

Previous research has documented several PAHs that interact synergistically, causing severe teratogenicity in developing fish embryos. The coexposure of CYP1A inhibitors (e.g. FL or ANF) with AHR agonists (e.g. BaP or BNF) results in a synergistic increase in toxicity. As with chemical CYP1A inhibitors, it has also been shown that CYP1A morpholinos exacerbate BNF-induced embryotoxicity. We hypothesized that a hypoxia-induced reduction in CYP1A activity in BNF or BaP-exposed zebrafish embryos would similarly enhance pericardial effusion and other developmental abnormalities. BaP, BNF, ANF, and FL exposures, both individually and as BaP+FL or BNF+ANF combinations, were performed under hypoxia and normoxia. CYP1A activity in the BaP+hypoxia and BNF+hypoxia embryos was reduced by approximately 60% relative to normoxia embryos. Although CYP1A activity was significantly reduced, we did not observe any increase in pericardial effusion in either group. An unexpected yet particularly interesting result of these experiments was the observed interaction of both FL and ANF with hypoxia. Relatively high, yet environmentally relevant concentrations of FL (100-500 microg L(-1)) interact with moderate hypoxia (7.3% DO) through an unknown mechanism, resulting in pericardial effusion and severe lordosis. Additionally, ANF exposures (100 microg L(-1)) which are not normally teratogenic caused dramatic pericardial effusion, but not lordosis, when embryos were coexposed to hypoxia. These results suggest that reduced CYP1A activity may not exclusively underlie observed developmental toxicity, and that hypoxia may exacerbate the developmental toxicity of some PAH mixtures.     

地表水自动监测网数据自动审核的创新与实践

在地表水质量自动监测网络的质量保证管理中,山东省省、市两级监控中心使用计算机数据审核系统对监测数据进行实时监控和质量控制,创新地实现了对监测数据有效性的自动判别、监测网的运行情况自动评价等自动化质控措施。     

Calibration and validation of a dynamic water model in agricultural scenarios

A dynamic aquatic model (DynA model) was previously developed to predict the fate of a chemical in aquatic scenarios characterized by daily or periodic changes in several input parameters. DynA model is here calibrated with data obtained from the literature in specific unsteady state scenarios, such as those of rice fields. The results obtained for two herbicides (cinosulfuron and pretilachlor) in rice paddy scenarios revealed the capability of the model to accurately predict water and sediment concentrations, as shown by some statistical indicators. Modelling efficiency (EF) values of 0.86-0.99 for the water compartment and of 0.77-0.84 for sediment show the good agreement between predicted and measured concentrations. An "external validation" was performed using measured data for a different herbicide (molinate) applied in a Portuguese paddy rice scenario. A sensitivity analysis for this volatile chemical revealed the influence of some climatic parameters (e.g. temperature) to the model outcomes, such as water and sediment concentrations. This confirmed the capability of DynA model as an efficient tool for the pesticide risk assessment in dynamic scenarios.     

喀斯特高原石漠化治理示范区土壤和农作物重金属含量特征

通过采集贵州毕节撒拉溪石漠化治理示范区土壤和主要农作物样品,分析了土壤和农作物样品中重金属Cr,Co,Cu,Cd,Pb,Zn,As和Ni含量,采用富集因子评价了土壤中重金属的污染状况,并分别采用潜在生态风险指数(RI)和生物富集系数评价了示范区土壤重金属的潜在生态风险和农作物对重金属的富集特征.结果表明,示范区土壤中C...     

Comparison of membrane fouling during short-term filtration of aerobic granular sludge and activated sludge

Aerobic granular sludge was cultivated adopting internal-circulate sequencing batch airlift reactor.The contradistinctive experiment about short-term membrane fouling between aerobic granular sludge system and activated sludge system were investigated.The membrane foulants was also characterized by Fourier transform infrared(FTIR)spectroscopy technique.The results showed that the aerobic granular sludge had excellent denitrification ability;the removal efficiency of TN could reach 90%.The aerobic granular sludge could alleviate membrane fouling effectively.The steady membrane flux of aerobic granular sludge was twice as much as that of activated sludge system.In addition,it was found that the aerobic granular sludge could result in severe membrane pore-blocking, however,the activated sludge could cause severe cake fouling.The major components of the foulants were identified as comprising of proteins and polysaccharide materials.     

江苏省能耗结构优化及其节能与减排效应分析

综合考虑江苏省经济增长、能源节约与C02、SO2减排的目标,运用改善的GADS优化算法对江苏省能耗结构进行优化,并对比江苏省低碳发展的情景,测算了江苏省能源消费结构优化的节能减排效应.研究结果表明:①能耗结构优化主要表现为高碳能源低度化,低碳能源离度化的演变过程.煤炭仍占主导地位,且呈倒"U",型的发展趋势,2020峰值1.822×108 tce,而天然气与低碳能源在总量与结构上均呈上升趋势;②能源结构优化具有正负双向效应,一方面节能减排效应显著,2020年将节能2.244×108tce,CO2:减排1.275×108t,但难以实现2020年减排目标,还需其它方面的努力.另一方面由干能源成本等因素造成GDP较之于低碳情景将减少2.096×1012元;③以"低"代"商"的能源优化策略是转移环境压力的主要途径,但其先决条件是煤炭资源的清洁高效利用与新能源核心技术的突破.未来江苏省能源消费结构的优化应以煤炭资源的清洁、高效利用为主,同时加快风能、太阳能、生物质能等新能源资源的产业化、规模化发展.     

锚杆锚固段拉脱失效对基坑安全稳定性的影响研究

为了探究锚杆支护基坑工程中支护结构失稳的灾变机理,揭示锚固段拉脱失效对锚杆支护基坑安全稳定性的影响,依托某深基坑工程开展现场试验,布置分布式传感器监测桩锚支护结构锚杆内力和变形情况,结合数值计算分析,研究支护锚杆锚固段的拉脱失效区域形成原因及判定方法。结果表明,锚杆的轴向应力随基坑向下开挖深度增加逐渐变大,其中,锚杆自由段轴向应力变化最为明显,锚固段区域轴向应力沿长度方向逐渐减弱。对比分析现场试验数据曲线,判定因预应力张拉作用使基坑预应力锚杆在锚固段存在一定范围的拉脱失效区域,研究依托工程的拉脱失效区域为1.0～2.0 m。拉脱失效会使基坑侧壁边坡的剪应变增量区域形成滑移面,导致滑移趋势明显增大,进一步验证了拉脱失效区域对基坑稳定性会有显著影响。工程设计时不能忽略预应力锚杆锚固段拉脱失效区域的存在,深基坑锚杆设计必须增大安全储备,以保证基坑安全稳定性。     

秦皇岛地区地热资源开发利用方向

在研究大量地热地质资料的基础上,发现秦皇岛地区存在以断裂构造活动为主要特征的地下热水,区内地下热水的赋存受区域构造、断裂活动、盖层等因素的影响。根据地热资源分布及热储特征,提出秦皇岛地区地热资源开发利用可优先考虑的方向:抚宁县温泉堡、北戴河机场、卢龙县刘田各庄乡赵官庄、黄金海岸及北戴河新城七里海团组。