Background Mercury Concentrations in River Water in Maine, U.S.A.

Mercury concentrations in 58 rivers in Maine was measured to range from below detection up to 7.01 ng L^-1 and averaged 1.80±1.29 ng L^-1. The concentration gradient for mercury in rivers across the state was not uniform. Mercury strongly correlated with dissolved organic carbon (DOC) and aluminum, and less strongly with copper, lead, and zinc. Mercuryexhibited significant differences in correlations with chemical variables and local geology when partitioned by flow state (high or low). Mercury concentrations were greatest in rivers flowingacross either wacke-type bedrock at low metamorphic grade, or glacial-till deposits. Elevated concentrations of mercury formed a locus in northern Maine under both high and low-flow states while in southwestern Maine a locus formed only during high-flowstates. These regional differences were statistically significantwhen compared by geographical location. We suggest that there is a bedrock source of mercury in northeastern Maine that is dilutedduring periods of high runoff. The elevated concentrations detected under high-flow states, as noted in southwestern Maine, may reflect mercury released from storage in association withDOC during periods of high runoff. The association of mercury with flow state indicates that watershed processes and local geology can modulate the concentration of mercury in rivers.     

Transport,deposition and biodegradation of particle bound polycyclic aromatic hydrocarbons in a tidal basin of an industrial watershed

Polycylic aromatic hydrocarbons (PAHs) are commoncontaminants in industrial watersheds. Their origin,transport and fate are important to scientists,environmental managers and citizens. The Philadelphia NavalReserve Basin (RB) is a small semi-enclosed embayment nearthe confluence of the Schuylkill and Delaware Rivers inPennsylvania (USA). We conducted a study at this site todetermine the tidal flux of particles and particle-boundcontaminants associated with the RB. Particle traps wereplaced at the mouth and inside the RB and in the Schuylkilland Delaware Rivers. There was net particle deposition intothe RB, which was determined for three seasons. Spring andfall depositions were highest (1740 and 1230 kg ofparticles, respectively) while winter deposition wasinsignificant. PAH concentrations on settling particlesindicated a net deposition of 12.7 g PAH in fall and 2.1 gPAH in spring over one tidal cycle. There was nosignificant PAH deposition in the winter. Biodegradationrates, calculated from ¹⁴C-labeled PAH substratemineralization, could attenuate only about 0.25% of the PAHdeposited during a tidal cycle in fall. However, in thespring, biodegradation could be responsible for degrading50% of the settling PAHs. The RB appears to be a sink forPAHs in this watershed.     

Key beliefs influencing young drivers’ engagement with social interactive technology on their smartphones: A qualitative study

Objective: The main aim of this study was to identify young drivers’ underlying beliefs (i.e., behavioral, normative, and control) regarding initiating, monitoring/reading, and responding to social interactive technology (i.e., functions on a Smartphone that allow the user to communicate with other people).

Method: This qualitative study was a beliefs elicitation study in accordance with the theory of planned behavior and sought to elicit young drivers’ behavioral (i.e., advantages, disadvantages), normative (i.e., who approves, who disapproves), and control beliefs (i.e., barriers, facilitators) that underpin social interactive technology use while driving. Young drivers (N = 26) aged 17 to 25 years took part in an interview or focus group discussion.

Results: Though differences emerged between the 3 behaviors of initiating, monitoring/reading, and responding for each of the behavioral, normative, and control belief categories, the strongest distinction was within the behavioral beliefs category (e.g., communicating with the person that they were on the way to meet was an advantage of initiating; being able to determine whether to respond was an advantage of monitoring/reading; and communicating with important people was an advantage of responding). Normative beliefs were similar for initiating and responding behaviors (e.g., friends and peers more likely to approve than other groups) and differences emerged for monitoring/reading (e.g., parents were more likely to approve of this behavior than initiating and responding). For control beliefs, there were differences between the beliefs regarding facilitators of these behaviors (e.g., familiar roads and conditions facilitated initiating; having audible notifications of an incoming communication facilitated monitoring/reading; and receiving a communication of immediate importance facilitated responding); however, the control beliefs that presented barriers were consistent across the 3 behaviors (e.g., difficult traffic/road conditions).

Conclusion: The current study provides an important addition to the extant literature and supports emerging research that suggests that initiating, monitoring/reading, and responding may indeed be distinct behaviors with different underlying motivations.     

Assessment of the Extreme Rainfall Event at Nashville,TN and the Surrounding Region on May 1–3, 2010

This paper analyzes the May 1–3, 2010 rainfall event that affected the south‐central United States, including parts of Mississippi, Tennessee, and Kentucky. The storm is evaluated in terms of its synoptic setting, along with the temporal distributions, and spatial patterns of the rainfall. In addition, the recurrence interval of the storm is assessed and the implications for hydrologic structure designs are discussed. The event was associated with an upper‐level trough and stationary frontal boundary to the west of the rainfall region, which remained quasi‐stationary for a period of 48 h. Heavy rainfall was produced by two slow‐moving mesoscale convective complexes, combined with abundant atmospheric moisture. Storm totals exceeding 330 mm occurred within a large elongated area extending from Memphis to Nashville. Isolated rainfall totals over 480 mm were reported in some areas, with NEXRAD weather radar rainfall estimates up to 501 mm. An extreme value analysis was performed for one‐ and two‐day rainfall totals at Nashville and Brownsville, Tennessee, as well as for gridded rainfall estimates for the entire region using the Storm Precipitation Analysis System. Results suggest maximum rainfall totals for some durations during the May 1–3, 2010 event exceeded the 1,000‐year rainfall values from National Oceanic and Atmospheric Administration Atlas 14 for a large portion of the region and reached up to 80% of the probable maximum precipitation values for some area sizes and durations.     

The rains are disappointing us: dynamic vulnerability and adaptation to multiple stressors in the Afram Plains, Ghana

This paper builds on work on the dynamics of vulnerability and multiple stressors through a case study in the Afram Plains of the Eastern region in Ghana. A vulnerability framework is applied in the community of Mimkyemfre to identify and explain the multiple underlying political, socioeconomic and environmental forces that influence the ways in which people are exposed and sensitive to climate, and their capacities to adapt to changing conditions. The results of the study indicate that the community experiences a range of biophysical and socioeconomic conditions that contribute to its vulnerability. Vulnerability was found to change over time and in some cases was cyclical, in that certain actions taken for the purposes of adaptation were found to exacerbate existing vulnerabilities. Processes of vulnerability were also found to occur at several scales and were experienced unevenly at the community level. The findings of this assessment have important implications for the design and implementation of successful adaptation initiatives, both in Africa and elsewhere. In particular, they demonstrate the need to understand the social, economic and institutional challenges to development as a basis for any contemplation of adaptation to climate change.     

Planning an Environmental Survey for a Nuclear Power Plant Site

Abstract

Subsequent to the 1997 promulgation of the Federal Reference Method (FRM) for monitoring fine particulate matter (PM_2.5) in ambient air, U.S. Environmental Protection Agency (EPA) received reports that the DOW 704 diffusion oil used in the method’s Well Impactor Ninety-Six (WINS) fractionator would occasionally crystallize during field use, particularly under wintertime conditions. Although the frequency of occurrence on a nationwide basis was low, uncertainties existed as to whether crystallization of the DOW 704 oil may adversely affect a sampling event’s data quality. In response to these concerns, EPA and the State of Connecticut Department of Environmental Protection jointly conducted a series of specialized tests to determine whether crystallized oil adversely affected the performance of the WINS fractionator. In the laboratory, an experimental setup used dry ice to artificially induce crystallization of the diffusion oil under controlled conditions. Using primary polystyrene latex calibration aerosols, standard size-selective performance tests of the WINS fractionator showed that neither the position nor the shape of the WINS particle size fractionation curve was substantially influenced by the crystallization of the DOW 704 oil. No large particle bounce from the crystallized impaction surface was observed. During wintertime field tests, crystallization of the DOW 704 oil did not adversely affect measured PM_2.5 concentrations. Regression of measurements with crystallized DOW 704 versus liquid dioctyl sebacate (DOS) oil produced slope, intercept, and R² values of 0.98, 0.1, and 0.997 μg/m³, respectively. Additional field tests validated the use of DOS as an effective impaction substrate. As a result of these laboratory and field tests, DOS oil has been approved by EPA as a substitute for DOW 704 oil. Since the field deployment of DOS oil in 2001, users of this alternative oil have not reported any operational problems associated with its use in the PM_2.5 FRM. Limited field evaluation of the BGI very sharp cut cyclone indicates that it provides a viable alternative to the WINS fractionator.     

The effects of cage-diving activities on the fine-scale swimming behaviour and space use of white sharks

Wildlife tourism has become increasingly popular and is one of the fastest growing sectors of the tourism industry. A radio-acoustic positioning system was deployed to monitor the fine-scale movements of 21 white sharks (Carcharodon carcharias) and investigate the effects of shark cage-diving activities on their swimming behaviour and space use. This study contributes towards improving our understanding of the complex relationship between wildlife tourism and its effects on sharks, and assesses how tourism targeting sharks affects behaviour at a finer spatial scale than previously investigated. Our study demonstrated that shark cage-diving operators (SCDO) influenced the fine-scale three-dimensional spatial distribution and the rate of movement of white sharks at the Neptune Islands. White sharks stayed more than 30 m away from the SCDO on 21 % of the days detected, but spent a significant amount of time in close proximity to the SCDO on the remaining days. Individual variation was detected, with some sharks behaviourally responding to SCDO more than others. The degree of variation between individual sharks and the different levels of interaction (e.g. presence, proximity to SCDO, and consumption of tethered bait) highlights the complexity of the relationships between SCDO and the effects on sharks. To improve our understanding of these relationships, future monitoring of shark cage-diving operations requires proximity to SCDO to be recorded in addition to the presence within the area. Further work is needed to assess whether the observed behavioural changes would affect individual fitness and ultimately population viability, which are critical information to unambiguously assess the potential impacts of wildlife tourism targeting sharks.     

THE EFFECTS OF CLIMATE CHANGE ON STREAM FLOW AND NUTRIENT LOADING'

ABSTRACT: This study assesses the potential impact of climate change on stream flow and nutrient loading in six watersheds of the Susquehanna River Basin using the Generalized Watershed Loading Function (GWLF). The model was used to simulate changes in stream flow and nutrient loads under a transient climate change scenario for each watershed. Under an assumption of no change in land cover and land management, the model was used to predict monthly changes in stream flow and nutrient loads for future climate conditions. Mean annual stream flow and nutrient loads increased for most watersheds, but decreased in one watershed that was intensively cultivated. Nutrient loading slightly decreased in April and late summer for several watersheds as a result of early snowmelt and increasing evapotranspiration. Spatial and temporal variability of stream flow and nutrient loads under the transient climate scenario indicates that different approaches for future water resource management may be useful.     

Biological and chemical analysis of the toxic potency of pesticides in rainwater.

A newly developed method for measuring the integrated esterase inhibiting potency of rainwater samples was applied in practice, and the results are compared to the toxic potency calculated from concentrations of 31 organophosphate (OP) and carbamate pesticides, out of a total of 66 chemically analyzed pesticides. In addition, the general toxic potency of the rainwater samples was evaluated in a microtiter luminescence assay with Vibrio fischeri bacteria. Rainwater samples were collected over four consecutive 14-day periods in both open and wet-only samplers. The esterase inhibiting potency of the open rainwater samples (expressed as ng dichlorvos-equivalents/l) corresponded well with the chemical analyses of the rainwater samples collected by both types of samplers (r = 0.83-0.86). By far, the highest esterase inhibiting potency was found in a sample collected in an area with intense horticultural activities in June, and was attributed to high concentrations of dichlorvos, mevinphos, pirimiphos-methyl and methiocarb. The esterase inhibiting potency of this sample was equivalent to a dichlorvos concentration of 1380 ng/l in the rainwater, which is almost 2000 times higher than the maximum permissible concentration (MPC) of dichlorvos set for surface water in Netherlands. Maximum individual concentrations of dichlorvos and pirimiphos-methyl even exceeded the EC50 for Daphnia, suggesting that pesticides in rainwater pose a risk for aquatic organisms. Not all responses of the luminescence-assay for general toxicity could be explained by the analyzed pesticide concentrations. The bio-assays enable a direct assessment the toxic potency of all individual compounds present in the complex mixture of rainwater pollutants, even if they are unknown or present at concentrations below the detection limit. Therefore, they are valuable tools for prescreening and hazard characterization purposes.