Full-Scale Evaluation of the Thermal Stability-Based Hazardous Organic Waste Incinerability Ranking

De nombreuses études épidémiologiques ont observé dans des contextes différents une faible relation à court terme entre les particules et la mortalité cardio-pulmonaire, même quand les normes de qualité de l'air n'étaient pas dépassées. La causalité de cette relation est un enjeu de santé publique en raison de l'importance de la population exposée. Notre objectif est de faire l'inventaire critique des arguments utilisés dans 15 revues de la littérature publiées.

Nous expliquons l'importance de distinguer la validité de la causalité et analysons de façon systématique les différents critères de jugement dans le contexte des études écologiques temporelles. Notre conclusion est que la relation observée est valide et que la plupart des critères de causalité sont respectés. Diminuer le niveau d'exposition des populations aux particules est souhaitable. En Europe, en agissant à la source, notamment sur les émissions Diesel, on diminuera aussi d'autres polluants qui peuvent jouer un rôle sanitaire. Aux États-Unis, la situation est plus complexe car les particules sont surtout secondaires.

Il est également indispensable de poursuivre les recherches pour mieux connaître les déterminants des expositions globales des individus et mieux comprendre le rôle toxique des différents facteurs physico-chimiques des particules.     

Comparison of specific versus literature species sensitivity distributions for herbicides risk assessment

Species sensitivity distributions (SSDs) are an important predictive tool in risk assessment. Usually, literature data are used to build SSDs that are mostly based on planktonic species. But, to get adequate protective thresholds for environmental communities, one could argue that SSD should be built on ecotoxicological data obtained from species found in the ecosystem that should be protected. This is particularly true when benthic algae are of concern. Due to the lack of literature data, building SSD on benthic microalgae is difficult. This paper aims in comparing SSDs, and thus protective thresholds (hazardous concentration that affects 5 % of the species of a community, HC₅), built on ecotoxicological data obtained (1) from literature and (2) with specific bioassays on benthic diatoms from a lake. Thresholds were derived for protection against four herbicides separately and for a mixture of them. Sensitivity data obtained from literature were statistically lower than the specific data for all herbicides: Species tested in the literature were usually more sensitive (mainly chlorophytes), leading to more protective lower HC₅. The HC₅ thresholds (literature or specific) derived for protection against the mixture were also compared to the observed sensitivity of an assemblage of benthic diatom species exposed to an increasing range of herbicide mixture concentrations. We observed that one species within the assemblage (Fragilaria rumpens) was affected at a concentration below both the literature and the specific HC₅ thresholds.     

Modeling Past and Future Acidification of Swedish Lakes

Decades of acid deposition have caused acidification of lakes in Sweden. Here we use data for 3000 lakes to run the acidification model MAGIC and estimate historical and future acidification. The results indicate that beginning in about 1920 a progressively larger number of lakes in Sweden fell into the category of “not naturally acidified” (∆pH > 0.4). The peak in acidification was reached about 1985; since then many lakes have recovered in response to lower levels of acid deposition. Further recovery from acidification will occur by the year 2030 given implementation of agreed legislation for emissions of sulphur (S) and nitrogen (N) in Europe. But the number of catchments with soils being depleted in base cations will increase slightly. MAGIC-reconstructed history of acidification of lakes in Sweden agrees well with information on fish populations. Future acidification of Swedish lakes can be influenced by climate change as well as changes in forest harvest practices.     

The progress and challenges in sustainable forestry development in China

Forestry development in China has undergone a series of reforms over the past six decades. This article examines temporal changes in forest resources and policies, the current status of forestry, and future challenges toward sustainable forest management in China. Excessive logging in the 1950s to 1980s badly damaged the nation’s forests, but the adoption of enlightened forest policies in the late 1990s has led to increases in China’s total forest area and growing stock. Forest degradation was ecologically and economically costly, and rehabilitation processes have become increasingly more expensive. The low quality and young age of forest resources, loss of natural forests, and more difficulties in afforestation and reforestation pose severe challenges for China’s sustainable forestry. It is critically important for China to enhance forest productivity through intensive management, strengthen enforcement, and educational programs for protecting and restoring natural forests, narrow the gap between domestic timber supply and rapidly expanding consumption, improve coordinating networks for management, finance, and technology transfer, and accelerate efforts to clarify and stabilize tenure arrangements for non-state forests. China’s experience and lessons in forestry may be helpful for other developing countries that are seeking to achieve the goal of sustainable forest management.     

Meta-Modeling to Assess the Possible Future of Paris Agreement

In the meta-modeling approach, one builds a numerically tractable dynamic optimization or game model in which the parameters are identified through statistical emulation of a detailed large scale numerical simulation model. In this paper, we show how this approach can be used to assess the economic impacts of possible climate policies compatible with the Paris Agreement. One indicates why it is appropriate to assume that an international carbon market, with emission rights given to different groups of countries will exist. One discusses the approach to evaluate correctly abatement costs and welfare losses incurred by different groups of countries when implementing climate policies. Finally, using a recently proposed meta-model of game with a coupled constraint on a cumulative CO₂ emissions budget, we assess several new scenarios for possible fair burden sharing in climate policies compatible with the Paris Agreement.     

Marine dredged sediments as new materials resource for road construction

Large volumes of sediments are dredged each year in Europe in order to maintain harbour activities. With the new European Union directives, harbour managers are encouraged to find environmentally sound solutions for these materials. This paper investigates the potential uses of Dunkirk marine dredged sediment as a new material resource for road building. The mineralogical composition of sediments is evaluated using X-ray diffraction and microscopy analysis. Since sediments contain a high amount of water, a dewatering treatment has been used. Different suitable mixtures, checking specific geotechnical criteria as required in French standards, are identified. The mixtures are then optimized for an economical reuse. The mechanical tests conducted on these mixtures are compaction, bearing capacity, compression and tensile tests. The experimental results show the feasibility of the beneficial use of Dunkirk marine dredged sand and sediments as a new material for the construction of foundation and base layers for roads. Further research is now needed to prove the resistance of this new material to various environmental impacts (e.g., frost damage).     

Bacteriological safety assessment,hygienic habits and cross-contamination risks in a Nigerian urban sample of household kitchen environment

Urban household kitchen environment was assessed for safety by determining their levels of indicator bacteria, hygienic habits and risk of cross-contamination. Household kitchens (60) were selected in Warri Town, Nigeria, by the multi-stage sampling technique. Contact surfaces, water and indoor kitchen air were analysed for aerobic plate counts, total and faecal coliforms using Nutrient and McConkey media by swab/rinse method, membrane filtration and sedimentation methods, respectively. Hygienic habits and risk of cross-contamination were assessed with structured questionnaire which included socio-demographic variables. On the basis of median counts, the prevalence of high counts (log cfu/cm²/m³/100 mL) of aerobic plate counts (>3.0), total coliforms (>1.0) and faecal coliforms (>0) on contact surfaces and air was high (58.0–92.0%), but low in water (30.0–40.0%). Pots, plates and cutleries were the contact surfaces with low counts. Prevalence of poor hygienic habits and high risk of cross-contamination was 38.6 and 67.5%, respectively. Education, occupation and kitchen type were associated with cross-contamination risk (P = 0.002–0.022), while only education was associated with hygienic habits (P = 0.03). Cross-contamination risk was related (P = 0.01–0.05) to aerobic plate counts (OR 2.30; CL 1.30–3.17), total coliforms (OR 5.63; CL 2.76–8.25) and faecal coliforms (OR 4.24; CL 2.87–6.24), while hygienic habit was not. It can be concluded that urban household kitchens in the Nigerian setting are vulnerable to pathogens likely to cause food-borne infections.     

Statistical method for the determination of the ignition energy of dust cloud-experimental validation

Powdery materials such as metallic or polymer powders play a considerable role in many industrial processes. Their use requires the introduction of preventive safeguard to control the plants safety. The mitigation of an explosion hazard, according to the ATEX 137 Directive (1999/92/EU), requires, among other things, the assessment of the dust ignition sensitivity. PRISME laboratory (University of Orléans) has developed an experimental set-up and methodology, using the Langlie test, for the quick determination of the explosion sensitivity of dusts. This method requires only 20 shots and ignition sensitivity is evaluated through the E₅₀ (energy with an ignition probability of 0.5). A Hartmann tube, with a volume of 1.3 l, was designed and built. Many results on the energy ignition thresholds of partially oxidised aluminium were obtained using this experimental device (Baudry, 2007) and compared to literature. E₅₀ evolution is the same as MIE but their respective values are different and MIE is lower than E₅₀ however the link between E₅₀ and MIE has not been elucidated.In this paper, the Langlie method is explained in detail for the determination of the parameters (mean value E₅₀ and standard deviation σ) of the associated statistic law. The ignition probability versus applied energy is firstly measured for Lycopodium in order to validate the method. A comparison between the normal and the lognormal law was achieved and the best fit was obtained with the lognormal law.In a second part, the Langlie test was performed on different dusts such as aluminium, cornstarch, lycopodium, coal, and PA12 in order to determine E₅₀ and σ for each dust. The energies E₀₅ and E₁₀ corresponding respectively to an ignition probability of 0.05 and 0.1 are determined with the lognormal law and compared to MIE find in literature. E₀₅ and E₁₀ values of ignition energy were found to be very close and were in good agreement with MIE in the literature.     

Quantification of bisphenol A, 353-nonylphenol and their chlorinated derivatives in drinking water treatment plants

Bisphenol A (BPA) and nonylphenols (NP) are of major concern to public health due to their high potential for human exposure and to their demonstrated toxicity (endocrine disruptor effect). A limited number of studies have shown that BPA and NP are present in drinking water. The chlorinated derivatives that may be formed during the chlorination step in drinking water treatment plants (DWTP) exhibit a higher level of estrogenic activity than their parent compounds. The aim of this study was to investigate BPA, 353NP, and their chlorinated derivative concentrations using an accurate and reproducible method of quantification. This method was applied to both surface and treated water samples from eight French DWTPs producing from surface water. Solid-phase extraction followed by liquid chromatography?Ctandem mass spectrometry was developed in order to quantify target compounds from water samples. The limits of detection ranged from 0.3 to 2.3?ng/L for BPA and chlorinated BPA and from 1.4 to 63.0?ng/L for 353NP and chlorinated 353NP. BPA and 353NP were found in most analyzed water samples, at a level ranging from 2.0 to 29.7?ng/L and from 0 to 124.9?ng/L, respectively. In most of DWTPs a decrease of BPA and 353NP was observed between surface water and treated water (36.6 to 78.9?% and 2.2 to 100.0?% for BPA and 353NP, respectively). Neither chlorinated BPA nor chlorinated 353NP was detected. Even though BPA and 353NP have been largely removed in the DWTPs studied, they have not been completely eliminated, and drinking water may consequently remain a source of human exposure.