Water and solute movement in soil as influenced by macropore characteristics: 2. Macropore tortuosity

The paper describes the results of a laboratory study on the effects of macropore tortuosity on breakthrough curves BTCs and solute distribution in a Forman loam (fine loamy-mixed Udic Haploborolls) soil. BTC were obtained using 2-D columns (slab) containing artificial macropores of five different tortuosity levels. The BTCs were run under a constant hydraulic head of 0.08 m over an initially air dry soil. The input solutions contained 1190 mg l⁻¹ of potassium bromide, 10 mg l⁻¹ of Rhodamine WT, and 100 mg l⁻¹ of FD&C Blue #1. A soil column without macropores served as a control. The displacement of a non-adsorbed tracer was not affected by the tortuosity level. An increase in macropore tortuosity progressively increased the breakthrough time, increased the apparent retardation coefficient (R′), decreased the depth to the center of mass of a given adsorbed tracer, and increased the anisotropy in tracer distribution profile. The relative importance of macropore tortuosity increased with an increase in the adsorption coefficient of the tracer. Compared to macropore continuity, the macropore tortuosity had greater impact on solute distribution profile than in its leaching.     

Tillage and nutrient source effects on water quality and corn grain yield from a flat landscape

Beneficial effects of leaving residue at the soil surface are well documented for steep lands, but not for flat lands that are drained with surface inlets and tile lines. This study quantified the effects of tillage and nutrient source on tile line and surface inlet water quality under continuous corn (Zea mays L.) from relatively flat lands (<3%). Tillage treatments were either fall chisel or moldboard plow. Nutrient sources were either fall injected liquid hog manure or spring incorporated urea. The experiment was on a Webster-Canisteo clay loam (Typic Endoaquolls) at Lamberton, MN. Surface inlet runoff was analyzed for flow, total solids, NO(3)-N, NH(4)-N, dissolved P, and total P. Tile line effluent was analyzed for flow, NO(3)-N, and NH(4)-N. In four years of rainstorm and snowmelt events there were few significant differences (p < 0.10) in water quality of surface inlet or tile drainage between treatments. Residue cover minimally reduced soil erosion during both snowmelt and rainfall runoff events. There was a slight reduction in mineral N losses via surface inlets from manure treatments. There was also a slight decrease (p = 0.025) in corn grain yield from chisel-plow plots (9.7 Mg ha(-1)) compared with moldboard-plow plots (10.1 Mg ha(-1)). Chisel plowing (approximately 30% residue cover) alone is not sufficient to reduce nonpoint source sediment pollution from these poorly drained flat lands to the extent (40% reduction) desired by regulatory agencies.     

RESERVOIR OPERATION ANI EVALUATION OF DOWNSTREAM FLOW AUGMENTATION1

ABSTRACT: Operation of a storage‐based reservoir modifies the downstream flow usually to a value higher than that of natural flow in dry season. This could be important for irrigation, water supply, or power production as it is like an additional downstream benefit without any additional investment. This study addresses the operation of two proposed reservoirs and the downstream flow augmentation at an irrigation project located at the outlet of the Gandaki River basin in Nepal. The optimal operating policies of the reservoirs were determined using a Stochastic Dynamic Programming (SDP) model considering the maximization of power production. The modified flows downstream of the reservoirs were simulated by a simulation model using the optimal operating policy (for power maximization) and a synthetic long‐term inflow series. Comparing the existing flow (flow in river without reservoir operation) and the modified flow (flow after reservoir operation) at the irrigation project, the additional amount of flow was calculated. The reliability analysis indicated that the supply of irrigation could be increased by 25 to 100 percent of the existing supply over the dry season (January to April) with a reliability of more than 80 percent.     

The influence of hydroxyl volatile organic compounds on the oxidation of aqueous sulfur dioxide by oxygen

Although the effect of volatile organic compounds (VOCs) on the oxidation of dissolved sulfur dioxide by oxygen has been the subject of many investigations, this is the first study which examines the effect of a large number of precisely 16 hydroxy compounds. The kinetics both in the absence and the presence of VOCs was defined by rate laws (A and B): A $$ \hbox{-} \mathrm{d}\left[\mathrm{S}\left(\mathrm{IV}\right)\right]/\mathrm{dt}={R}_o={k}_o\left[\mathrm{S}\left(\mathrm{IV}\right)\right] $$ B $$ \hbox{-} \mathrm{d}\left[\mathrm{S}\left(\mathrm{IV}\right)\right]/\mathrm{dt}={R}_i={k}_i\left[\mathrm{S}\left(\mathrm{IV}\right)\right] $$ where R _o and k _o are the initial rate and first-order rate constant, respectively, in the absence of VOCs, R _i , and k _i are the initial rate and the first-order rate constant, respectively, in the presence of VOCs, and [S(IV)] is the concentration of dissolved sulfur dioxide, sulfur(IV). The nature of the dependence of k _i on the concentration of inhibitor, [Inh], was defined by Eq. (C). C $$ {k}_i={k}_0/\left(1+B\left[\mathrm{Inh}\right]\right) $$ where B is an empirical inhibition parameter. The values of B have been determined from the plots of 1/k _i versus [Inh]. Among aliphatic and aromatic hydroxy compounds studied, t-butyl alcohol and pinacol were without any inhibition effect due to the absence of secondary or tertiary hydrogen. The values of inhibition parameter, B, were related to k _inh , the rate constant for the reaction of SO₄ ^? radical with the inhibitor, by Eq. (D). D $$ B=\left(9\pm 2\right)\times 1{0}^{-4}\times {k}_{inh} $$ Equation (D) may be used to calculate the values of either of B or k _inh provided that the other is known. The extent of inhibition depends on the value of the composite term, B[Inh]. However, in accordance with Eq. (C), the extent of inhibition would be sizeable and measurable when B[Inh]?>?0.1 and oxidation of S(IV) would be almost completely stopped when B[Inh]?≥?10. B[Inh] value can be used as a guide whether the reaction step: SO₄ ^??+?organics? \( \overset{k_{inh}}{\to } \) ?SO₄ ^2??+?non-chain products: should be included in the multiphase models or not.     

Assessment of mechanical,durability and microstructural properties of geopolymer concrete containing ceramic tile waste

Journal of Material Cycles and Waste Management - The amount of ceramic waste being generated is increasing day by day, and ceramic waste management is one of the most challenging issues for many...     

Optimal sizing of different configuration of photovoltaic,fuel cell,and biomass-based hybrid energy system

Environmental Science and Pollution Research - The need for power is rising on a daily basis all across the world. Due to the finite supply of fossil fuels, it is critical to develop innovative...     

Correction to: Method development,validation, monitoring,seasonal effect and risk assessment of multiclass multi pesticide residues in surface and ground water of new alluvial zone in eastern India

Environmental Science and Pollution Research -     

Water toxicants: a comprehension on their health concerns,detection, and remediation

Environmental Science and Pollution Research - Water is an essential moiety for the human use since a long time. Availability of good-quality water is very essential, as it is used in almost all...     

Optimization of process parameters using response surface methodology for maximum liquid yield during thermal pyrolysis of blend of virgin and waste high-density polyethylene

Journal of Material Cycles and Waste Management - The pyrolytic fuel generated by high-density polyethylene (HDPE) has the potential to replace fossil fuels as a primary source of energy. Thermal...     

Micronutrient seed priming: new insights in ameliorating heavy metal stress

Plants need to survive with changing environmental conditions, be it different accessibility to water or nutrients, or attack by insects or pathogens. Few of these changes, especially heavy metal stress, can become more stressful and needed strong countermeasures to ensure survival of plants. Priming, a pre-sowing hydration treatment, involves pre-exposure of plants to an eliciting component which enhance the plant’s tolerance to later stress events. By considering the role of micronutrients in aiding plants to cope up under adverse conditions, this review addresses various aspects of micronutrient seed priming in attenuating heavy metal stress. Priming using micronutrients is an adaptive strategy that boosts the defensive capacity of the plant by accumulating several active or inactive signaling proteins, which hold considerable importance in signal amplification against the triggered stimulus. Priming induced ‘defence memory’ persists in both present generation and its progeny. Therefore, it is considered a promising approach by seed technologist for commercial seed lots to enhance the vigour in terms of seed germination potential, productivity and strengthening resistance response against metalloid stress. The present review provides an overview regarding the potency of priming with micronutrient to ameliorate harmful effects of heavy metal stress, possible mechanism how attenuation is accomplished, role of priming in enhancing crop productivity and inducing defence memory against the metalloid stress stimulus.