Individual and simultaneous degradation of brominated high impact polystyrene and brominated acrylonitrile-butadiene-styrene and removal of heteroelements (Br,N, and O) from degradation oil by multiphase catalytic systems

Brominated high-impact polystyrene (HIPS-Br), which contained decabromodiphenyl ether flame retardant, and brominated acrylonitrile butadiene styrene (ABS-Br), which contained bromine-containing epoxy-type flame retardant, were degraded at 450°C individually and in a 1/1 mixture by a thermal and catalytic procedure using folded sheet mesoporous (FSM) and ZSM-5 zeolite in liquid phase contact mode. The two polymers produced similar degradation oils but at a higher yield for HIPS-Br. However, the composition and distribution of Br-, N-, and O-containing compounds depended on the type of flame retardant in HIPS-Br and ABS-Br. Multiphase catalytic systems consisting of FSM in liquid phase contact mode and various CaH-, FeO-, CoMo-, and NiMo-based catalysts, or combinations of these catalysts, in vapor phase contact mode were used to decrease the amount of heteroatoms (Br, N, and O) in the degradation oils. Each system gave particular results in terms of mass balance and concentrations of heteroatoms. A FSM (liquid phase contact)/CaHC (vapor phase contact) combination was the best catalytic system to remove Br-, N-, and O-containing compounds from degradation oils.     

应用卫星图像评价尼泊尔的创造性森林经营策略

现迫切需要确定那些对森林覆盖率变化有显著影响的森林经营制度.这个研究提出了初步的"概念依据"方法论,它把毁林理论与卫星图像变化分析结合起来鉴定理论上也许不存在的林区.通过对尼泊尔Chitwan地区陆地卫星TM图像时间分析,结合道路地理信息系统以及对地形的目视估计,鉴定出10个这样的森林异相.再通过快速野外调查,确定哪一个异相出现有用的创新性森林经营.根据这个信息,选择了一个实地作详细的野外调查.通过这一项分析,我们发现这是一个重要的社区林和生态旅游的项目.此前我们并不知其存在.文章对这种方法在监测森林覆盖变化的应用的价值和局限进行了描述.     

Net primary productivity of some aquatic macrophytes in sewage-sullage mixture

Sewage-sullage mixture from Raipur city is spread over a vast area surrounding the city. This mixture has a pH always above neutrality with high turbidity. Transparency was nil with the absence of phenolphthalein alkalinity and dissolved oxygen. Hardness was high with low nitrogen and phosphorus concentration. Human consumable. acquatic macrophytes are cultivated in such waste water. Net primary productivity of three macrophytes: Ipomoea aquatica, Marsilea quadrifolia and Nelumbo nucifera were evaluated while being cultivated in such sewage-sullage mixture. Productivity was determined either with periodic biomass removal (I. aquatica and M. quadrifolia) or through removing the biomass only once at the time of growing season (N. nucifera). Growing season productivity of up to 27.48. 19.81 and 9.49 g m(-2) and day(-1) and extrapolated productivity of up to 100.30, 72.31 and 34.64 mt. ha(-1) yr(-1) was recorded for I. aquatica. M. quadrifolia and N. nucifera respectively. Thus, these macrophytes are yielding a high amount of human consumable biomass from an area which neither be a useless wetland.     

Toxins and bioactive compounds from cyanobacteria and their implications on human health

Many species of cyanobacteria (blue-green algae) produce secondary metabolites with potent biotoxic or cytotoxic properties. These metabolites differ from the intermediates and cofactor compounds that are essential for cell structural synthesis and energy transduction. The mass growth of cyanobacteria which develop in fresh, brackish and, marine waters commonly contain potent toxins. Cyanobacterial toxins or cyanotoxins are responsible for or implicated in animal poisoning, human gastroenteritis, dermal contact irritations and primary liver cancer in humans. These toxins (microcystins, nodularins, saxitoxins, anatoxin-a, anatoxin-a(s), cylindrospermopsin) are structurally diverse and their effects range from liver damage, including liver cancer to neurotoxicity. Several incidents of human illness and more recently, the death of 60 haemodialysis patients in Caruaru, Brazil, have been linked to the presence of microcystins in water. In response to the growing concern about the non-lethal acute and chronic effects of microcystins, World Health Organization has recently set a new provisional guideline value for microcystin-LR of 1.0 microg/L in drinking water. Cyanobacteria including microcystin-producing strains produce a large number of peptide compounds, e.g. micropeptins, cyanopeptolins, microviridin, circinamide, aeruginosin, with varying bioactivities and potential pharmacological application. This article discusses briefly cyanobacterial toxins and their implications on human health.     

Fresh water blue green algae from three agro-climatic zones of Uttar Pradesh, India: distribution pattern with seasonal variation

The paper deals with 45 species of 21 genera of fresh water blue green algae (BGA) from three different agro-climatic zones of Uttar Pradesh. Samples were collected from different habitats varying in physico-chemical properties. Out of 45 species, 13 species belonged to order Chroococcales, 31 to order Nostocales, while only 1 species belonged to order Stigonimatales i.e. Fischerella mucicola. The physico-chemical parameters like pH, temperature, dissolved oxygen, electrical conductivity, nitrate, nitrite and rainfall play an important role in the periodicity of BGA. A positive correlation was found between dissolved oxygen (DO) of different ponds and species diversity, except in the case of western region of Uttar Pradesh (Farukhabad and Mahoba districts) where a positive correlation was found in electrical conductivity and total dissolved solids.     

Investigation of some basic water quality parameters of the north Bengal Terai river Kaljani--a tributary of river Torsa, and comparison thereof with the mainstream

Some physico-chemical parameters of Kaljani River were studied in and around Alipurduar municipality. The principal characteristics of Kaljani River are high TSS, Mg-hardness, COD, and Phosphate 'P' Comparison of water quality parameters of the two rivers demonstrated higher range of alkalinity, ammonia 'N' content and chloride content in Torsa than Kaljani. River Kaljani showed higher COD range than Torsa. Mean BOD value of both these rivers ranged between 0.93-1.65 mg/l. Overall TDS content of Kaljani was found to be lower than Torsa. Maximum phosphate 'P' content was observed at the downstream of both the rivers.     

Comparative studies on accumulation of Cr from metal solution and tannery effluent under repeated metal exposure by aquatic plants: its toxic effects

The present study demonstrates comparison of Cr accumulatingpotential by the plants of Najas indica Cham. (submerged),Vallisneria spiralis L. (rooted submerged) and Alternanthera sessilis R. Br. (rooted emergent) under repeatedmetal exposure and its effect on chlorophyll and protein concentrations. These plants were treated with different concentrations of Cr under repeated exposure in controlled laboratory conditions to assess the maximum metal accumulationpotential. The plants of V. spiralis accumulated significantly high amount of Cr under laboratory conditions incomparison to N. indica and A. sessilis. The maximumaccumulation of 1378, 458 and 201 g g^-1 dw Cr was found in the leaves of V. spiralis, N. indica and A. sessilis, respectively at 8 mg L^-1 after 9 day of Cr exposure. These plants have shown a decrease in chlorophyll andprotein concentrations with increase in Cr concentrations. In view of high accumulation of Cr in V. spiralis, the plantswere treated with different concentrations of tannery effluent collected from Common Effluent Treatment Plant, Unnao (UP). Theplants of V. spiralis treated with 100% tannery wastewatershowed the maximum accumulation (57.5 g g^-1 dw) of Cr in the roots after 10 days of exposure. The plants were foundeffective in removing Cr from solution and tannery effluent.     

SIMULATING SOIL WATER RECESSION COEFFICIENTS FOR AGRICULTURAL WATERSHEDS1

ABSTRACT: The antecedent precipitation index (API) has been a useful indicator of soil moisture conditions for watershed runoff calculations, and recent attempts to correlate this index with spaceborne microwave observations have been fairly successful. The prognostic equation for soil moisture used in some of the atmospheric general circulation models (GCM) together with Thomthwaite-Mather parameterization of actual evapotranspiration leads to API equations. The recession coefficient for API is found to depend on climatic factors as contained in potential evapotranspiration and to depend on soil texture as reflected by field capacity and permanent wilting point. A recently developed model for global insolation is used with climatological data for Wisconsin to simulate the annual trend of the recession coefficient. Good quantitative agreement is shown with the observed trends at Fennimore and Colby watersheds in Wisconsin. This study suggests that API could be a unifying concept for watershed and atmospheric general circulation modeling.     

Pollution abatement in the indian pulp and paper industry

Summary In this paper, pollutants in air, water and as solids which stem from the paper industry are discussed, and pollution abatement measures are suggested. The Pulp and Paper Industry is highly capital, material and energy intensive and return on investment is very low. This paper reviews some emerging international principles which are effective in reducing both effluent treatment costs per tonne of paper and the mill discharges, to levels where their environmental impacts become far less significant than at present.Mr Avijit Dey is a graduate in Chemical Engineering from Jadavpur University and at present is Design Engineer in the Paper and Process Cell of Development Consultants Ltd, 24-B Park Street, Calcutta 70016, India. Dr B. Sen Gupta is Reader in the Chemical Engineering Department of Jadavpur University, Calcutta. He obtained his BChE and PhD in Chemical Engineering from Jadavpur University and an ME in Chemical Engineering from the Indian Institute of Science, Bangalore. His research interests involve pulp and paper technology, water conservation and management, and pollution control.     

Using satellite imagery to locate innovative forest management practices in Nepal

There is a critical need to locate innovative forest management institutions that significantly impact forest cover change. This research presents an initial "proof of concept" methodology which combines deforestation theory with satellite image change analysis to identify forested areas that, theoretically, should probably not be there. Ten such "forest anomalies" are identified using temporal analysis of Landsat TM imagery of the Chitwan district in Nepal, linked with a GIS database on roads and a visual estimation of topography. A rapid field reconnaissance is undertaken to determine which of these anomalies exhibit interesting forest management innovations. Based on this information, one case is selected for detailed field study: this turns out to be a major case of community forestry and a premier ecotourism initiative that we were not aware of until we undertook this analysis. The utility and limitations of the method are described for monitoring trends in forest cover change.